Abstract
Previous theoretical calculations and experimental measurements of the surface energies or enthalpies of the alkali halides are reviewed briefly. A new attempt to determine the surface enthalpy associated with the {100} face of sodium chloride from a calorimetric study of the effect of particle size on the heat of solution is described. The result (305 ergs/cm.2 at 25 °C.) appears to be larger than might be predicted on the basis of the classical Born-Mayer theory.
References
14
Referenced
20
{'key': 'p_1/p_1_1', 'first-page': '901', 'volume': '48', 'author': 'BORN M', 'year': '1919', 'journal-title': 'Akad. Wiss. Physik.-math. I<I.'}
/ Akad. Wiss. Physik.-math. I<I. by BORN M (1919)10.1021/ja01257a054
/ J. Am. Chem. Soc. by BOYD G. E. (1942){'key': 'p_3/p_3_1', 'first-page': '530', 'volume': '8', 'author': 'DENT B. M.', 'year': '1929', 'journal-title': 'Mag.'}
/ Mag. by DENT B. M. (1929)-
EMERSLEBEN, 0. Z. physik. Chem. 200: 1. 1952.
(
10.1515/zpch-1952-20002
) 10.1063/1.1740093
/ J. Chem. Phys. by VAN DER HOW B. M. (1954)10.1021/ja01143a062
/ J. Am. Chem. Soc. by JURA G. (1952)-
LENNARD-JONES, J. E. and TAYLOR,P. A. Proc. Roy. Soc. (London), A, 109: 476. 1925.
(
10.1098/rspa.1925.0139
) 10.1021/ja01403a005
/ and MAASS,0. J. Am. Chem. Soc. by LIPSETT S. G. (1927)10.1021/ja01407a013
/ and MAASS,0. J . Am. Chem. Soc. by LIPSETT S. G. (1927){'key': 'p_10/p_10_1', 'first-page': '240', 'volume': '33', 'author': 'PATTERSON D.', 'year': '1955', 'journal-title': 'J. Chem.'}
/ J. Chem. by PATTERSON D. (1955)-
SHUTTLEWORTH, R. Proc. Phys. Soc. (London), 62, A: 167. 1949.
(
10.1088/0370-1298/62/3/303
) {'key': 'p_12/p_12_1', 'first-page': '268', 'volume': '14', 'author': 'SUTHERLAND K. L.', 'year': '1947', 'journal-title': 'J. & Proc.'}
/ J. & Proc. by SUTHERLAND K. L. (1947)-
W i j s ,J. and LANGE,E. Z. physik. Chem. 116: 161. 1925.
(
10.1038/116161a0
) 10.1088/0950-7671/31/3/307
/ J. Sci. Instr. by YOUXG D. M. (1954)
Dates
Type | When |
---|---|
Created | 19 years, 3 months ago (May 2, 2006, 4:15 p.m.) |
Deposited | 1 month, 2 weeks ago (July 2, 2025, 1:55 p.m.) |
Indexed | 1 month, 2 weeks ago (July 2, 2025, 2:10 p.m.) |
Issued | 70 years, 6 months ago (Feb. 1, 1955) |
Published | 70 years, 6 months ago (Feb. 1, 1955) |
Published Print | 70 years, 6 months ago (Feb. 1, 1955) |
@article{Benson_1955, title={SURFACE ENERGIES OF THE ALKALI HALIDES}, volume={33}, ISSN={1480-3291}, url={http://dx.doi.org/10.1139/v55-026}, DOI={10.1139/v55-026}, number={2}, journal={Canadian Journal of Chemistry}, publisher={Canadian Science Publishing}, author={Benson, G. C. and Benson, G. W.}, year={1955}, month=feb, pages={232–239} }