Abstract
The Hamiltonian describing the rotation and vibration of a homonuclear diatomic molecule in the field of a point charge at a fixed distance from its centre-of-mass is given. Numerical results for the Stark shift of the molecular levels due to a point charge of either sign are listed for H2, D2, and T2 as a function of the separation of the point charge from the molecule. The intensity associated with transitions between perturbed levels is discussed briefly.
Dates
Type | When |
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Created | 14 years, 4 months ago (April 23, 2011, 4:20 p.m.) |
Deposited | 2 months ago (July 2, 2025, 3:29 p.m.) |
Indexed | 1 month, 4 weeks ago (July 8, 2025, 7:31 a.m.) |
Issued | 40 years, 8 months ago (Jan. 1, 1985) |
Published | 40 years, 8 months ago (Jan. 1, 1985) |
Published Print | 40 years, 8 months ago (Jan. 1, 1985) |
@article{Poll_1985, title={On the theory of the Stark shifts of the rotational–vibrational levels of the hydrogen molecule and its isotopes produced by a point charge. I: H2, D2, and T2}, volume={63}, ISSN={1208-6045}, url={http://dx.doi.org/10.1139/p85-014}, DOI={10.1139/p85-014}, number={1}, journal={Canadian Journal of Physics}, publisher={Canadian Science Publishing}, author={Poll, J. D. and Hunt, J. L.}, year={1985}, month=jan, pages={84–93} }