DOI: 10.1139/p70-204. Fundamental infrared absorption of H<sub>2</sub> in solid Kr and of D<sub>2</sub> in solid argon

Fundamental infrared absorption of H2 in solid Kr and of D2 in solid argon

10.1139/p70-204

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Physics (155)

Abstract

The fundamental infrared absorption band of H2(D2) has been studied in the dilute solid solutions H2–Kr and D2–Ar, and the results are compared with previous data for H2–Ar. The spectrum consists of combination tones of molecular and lattice transitions; the lattice transition frequencies are (112, 22), (106, 16), and (79, 22) cm−1 for H2–Ar, H2–Kr, and D2–Ar, respectively. The previous assignment of the intense higher-frequency transition to the localized vibration of the impurity molecule on a substitutional lattice site is confirmed. The weaker lower-frequency transition is evidently due to an impurity-induced phonon transition of the host lattice.

Bibliography

Remigis, J. D., & Welsh, H. L. (1970). Fundamental infrared absorption of H2 in solid Kr and of D2 in solid argon. Canadian Journal of Physics, 48(13), 1622â1627.

Authors 2

J. De Remigis (first)
H. L. Welsh (additional)

References 0 Referenced 27

None

Dates

Type	When
Created	14 years, 4 months ago (April 23, 2011, 3:55 p.m.)
Deposited	1 month, 3 weeks ago (July 2, 2025, 10:02 a.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 10:40 a.m.)
Issued	55 years, 1 month ago (July 1, 1970)
Published	55 years, 1 month ago (July 1, 1970)
Published Print	55 years, 1 month ago (July 1, 1970)

Funders 0

None

BibTeX

@article{Remigis_1970, title={Fundamental infrared absorption of H2 in solid Kr and of D2 in solid argon}, volume={48}, ISSN={1208-6045}, url={http://dx.doi.org/10.1139/p70-204}, DOI={10.1139/p70-204}, number={13}, journal={Canadian Journal of Physics}, publisher={Canadian Science Publishing}, author={Remigis, J. De and Welsh, H. L.}, year={1970}, month=jul, pages={1622–1627} }

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  "abstract": "<jats:p> The fundamental infrared absorption band of H<jats:sub>2</jats:sub>(D<jats:sub>2</jats:sub>) has been studied in the dilute solid solutions H<jats:sub>2</jats:sub>\u2013Kr and D<jats:sub>2</jats:sub>\u2013Ar, and the results are compared with previous data for H<jats:sub>2</jats:sub>\u2013Ar. The spectrum consists of combination tones of molecular and lattice transitions; the lattice transition frequencies are (112, 22), (106, 16), and (79, 22)\u2002cm<jats:sup>\u22121</jats:sup> for H<jats:sub>2</jats:sub>\u2013Ar, H<jats:sub>2</jats:sub>\u2013Kr, and D<jats:sub>2</jats:sub>\u2013Ar, respectively. The previous assignment of the intense higher-frequency transition to the localized vibration of the impurity molecule on a substitutional lattice site is confirmed. The weaker lower-frequency transition is evidently due to an impurity-induced phonon transition of the host lattice. </jats:p>",
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