Abstract
Self-broadening of the rotational Raman lines of O2, N2, CO2, and CO, and foreign-gas broadening of O2 and N2 by He and Ar were measured in the pressure range from 7 to 43 atm at room temperature. Spectrograms were obtained with Hg 2 537 Å as exciting line and a reciprocal linear dispersion of 11.2 cm−1 per mm. In each case the broadening was found to be proportional to the pressure so that a broadening coefficient [Formula: see text] could be defined. The broadening coefficient shows a monotonie decrease with increasing rotational quantum number J. The values of [Formula: see text] for N2 and their variation with J are in good agreement with the values calculated theoretically by Van Kranendonk on the basis of quadrupolar interaction in the impact approximation.
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Dates
Type | When |
---|---|
Created | 14 years, 4 months ago (April 24, 2011, 3:43 a.m.) |
Deposited | 2 months ago (July 2, 2025, 10:10 a.m.) |
Indexed | 2 months ago (July 3, 2025, 12:07 a.m.) |
Issued | 59 years, 5 months ago (April 1, 1966) |
Published | 59 years, 5 months ago (April 1, 1966) |
Published Print | 59 years, 5 months ago (April 1, 1966) |
@article{Jammu_1966, title={PRESSURE BROADENING OF THE ROTATIONAL RAMAN LINES OF SOME SIMPLE GASES}, volume={44}, ISSN={1208-6045}, url={http://dx.doi.org/10.1139/p66-068}, DOI={10.1139/p66-068}, number={4}, journal={Canadian Journal of Physics}, publisher={Canadian Science Publishing}, author={Jammu, K. S. and John, G. E. St. and Welsh, H. L.}, year={1966}, month=apr, pages={797–814} }