DOI: 10.1139/p60-024. THEORY OF THE INFRARED AND RAMAN SPECTRA OF SOLID PARAHYDROGEN

THEORY OF THE INFRARED AND RAMAN SPECTRA OF SOLID PARAHYDROGEN

10.1139/p60-024

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Physics (155)

Abstract

The theory of the rotational and vibrational energy bands in solid hydrogen, developed previously, is applied to the interpretation of the infrared and Raman spectra of solid parahydrogen. A comparison of the theory with the experimental results yields information about the nature of the rotational and vibrational motions of the molecules in the solid, and about the anisotropic intermolecular forces. A calculation of the intensity of the infrared rotational and vibrational lines is given, which is based on the induction mechanisms introduced previously to explain the induced absorption in gaseous hydrogen. Satisfactory agreement with the experimental values is obtained. The importance of the interaction between other than nearest neighboring molecules, and of the interference effects affecting the single transitions, is pointed out. A frequency analysis is given of the infrared and Raman rotational and vibrational lines in the solid, and a consistent theory of the shifts and splittings of the various lines is obtained. Empirical values of the rotational and vibrational coupling constants are derived and compared with the theoretical values.

Bibliography

Kranendonk, J. V. (1960). THEORY OF THE INFRARED AND RAMAN SPECTRA OF SOLID PARAHYDROGEN. Canadian Journal of Physics, 38(2), 240â261.

Authors 1

J. Van Kranendonk (first)

References 14 Referenced 85

10.1103/PhysRev.106.1101 / Phys. Rev. by ALLIN E. J. (1957)
{'key': 'p_3/p_3_1', 'first-page': '721', 'volume': '41', 'author': 'DUNHAM J. L.', 'year': '1932', 'journal-title': 'Iiev.'} / Iiev. by DUNHAM J. L. (1932)
{'key': 'p_4/p_4_1', 'first-page': '176', 'volume': '38', 'author': 'GUSH H. P.', 'year': '1960', 'journal-title': 'J. Phys.'} / J. Phys. by GUSH H. P. (1960)
HUNT,L. J . 1959. P11.D. Thesis, University of Toronto, Toronto, Ontario.
KISS,Z. J. 1959. P11.D. Thesis, Uiversity 1935. Commun. I<amerlinrrhOnlcsLab.
NYBOER,B. R. A. and DE VETTE,F. 1957. Physica, 23, 309. (10.1016/S0031-8914(57)92124-9)
P A U L G, L. and WILSON,E. B. 1935. Iltroductionto quantum mechanics (McGraw-Hill Booli Co., New York).
ROSE,M. E. 1957. Elementary theory of angular momentum (John Wiley & Sons, Inc., New Yorl;). (10.1063/1.3060162)
{'key': 'p_13/p_13_1', 'first-page': '730', 'volume': '35', 'author': 'STOICHEFF R.', 'year': '1957', 'journal-title': 'Phys.'} / Phys. by STOICHEFF R. (1957)
10.1016/0022-2852(59)90016-5 / Mol. Spectroscopy by TERHUNE W. (1959)
10.1016/S0031-8914(57)94898-X / Physica by VANCIIANENDONK J. (1955)
10.1016/S0031-8914(58)95223-6 / Physica by VANCIIANENDONK J. (1958)
VANCIIANENDONK, J. 1959b. I'hysica, 25. To be pblished.
{'key': 'p_18/p_18_1', 'first-page': '1187', 'volume': '37', 'author': 'VAN I C', 'year': '1959', 'journal-title': "J. I'hys."} / J. I'hys. by VAN I C (1959)

Dates

Type	When
Created	14 years, 4 months ago (April 24, 2011, 3:30 a.m.)
Deposited	2 months ago (July 2, 2025, 10:10 a.m.)
Indexed	1 month, 4 weeks ago (July 3, 2025, 12:07 a.m.)
Issued	65 years, 7 months ago (Feb. 1, 1960)
Published	65 years, 7 months ago (Feb. 1, 1960)
Published Print	65 years, 7 months ago (Feb. 1, 1960)

Funders 0

None

BibTeX

@article{Kranendonk_1960, title={THEORY OF THE INFRARED AND RAMAN SPECTRA OF SOLID PARAHYDROGEN}, volume={38}, ISSN={1208-6045}, url={http://dx.doi.org/10.1139/p60-024}, DOI={10.1139/p60-024}, number={2}, journal={Canadian Journal of Physics}, publisher={Canadian Science Publishing}, author={Kranendonk, J. Van}, year={1960}, month=feb, pages={240–261} }

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