DOI: 10.1139/p57-079. HIGH RESOLUTION RAMAN SPECTROSCOPY OF GASES: IX. SPECTRA OF H<sub>2</sub>, HD, AND D<sub>2</sub>

HIGH RESOLUTION RAMAN SPECTROSCOPY OF GASES: IX. SPECTRA OF H2, HD, AND D2

10.1139/p57-079

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Physics (155)

Abstract

The pure rotational lines and the Q branch lines of the 1–0 vibrational bands of H2, HD, and D2 have been photographed with a 21 ft. grating spectrograph. From these spectra, a complete set of constants for the ν = 0 and 1 levels of all three molecules have been determined. When these constants are combined with Herzberg's results of the forbidden infrared spectra of H2 and HD they lead to improved values of the electronic ground state constants of H2 and HD. The leading terms in the Dunham power series expansion of the potential are calculated for H2 and HD and are found to be mutually consistent. The isotopic relations are obeyed within experimental accuracy, and the small constants De, Be, and He, are in agreement with values given by theoretical formulae.

Bibliography

Stoicheff, B. P. (1957). HIGH RESOLUTION RAMAN SPECTROSCOPY OF GASES: IX. SPECTRA OF H2, HD, AND D2. Canadian Journal of Physics, 35(6), 730â741.

Authors 1

B. P. Stoicheff (first)

References 5 Referenced 437

10.1103/PhysRev.94.893 / Phys. Rev. by BARNES R. G. (1954)
{'key': 'p_2/p_2_1', 'first-page': '107', 'volume': '7', 'author': 'BHAGAVANTAM S.', 'year': '1932', 'journal-title': 'Phys.'} / Phys. by BHAGAVANTAM S. (1932)
10.1364/JOSA.40.000339 / Opt. Soc. Amer. by BURNS K. (1950)
COHEN,E. R., D u \ / o N D . 1. \v. w1.LAYTON.T. W. and ROLLETT,1. S. 1955. Revs. Mod. Phys. 27, 363. (10.1103/RevModPhys.27.363)
10.1103/PhysRev.41.721 / Phvs. Rev. by DUNHAM I. L. (1932)

Dates

Type	When
Created	14 years, 3 months ago (April 24, 2011, 3:24 a.m.)
Deposited	1 month, 2 weeks ago (July 2, 2025, 10:29 a.m.)
Indexed	2 weeks, 1 day ago (Aug. 6, 2025, 8:07 a.m.)
Issued	68 years, 2 months ago (June 1, 1957)
Published	68 years, 2 months ago (June 1, 1957)
Published Print	68 years, 2 months ago (June 1, 1957)

Funders 0

None

BibTeX

@article{Stoicheff_1957, title={HIGH RESOLUTION RAMAN SPECTROSCOPY OF GASES: IX. SPECTRA OF H2, HD, AND D2}, volume={35}, ISSN={1208-6045}, url={http://dx.doi.org/10.1139/p57-079}, DOI={10.1139/p57-079}, number={6}, journal={Canadian Journal of Physics}, publisher={Canadian Science Publishing}, author={Stoicheff, B. P.}, year={1957}, month=jun, pages={730–741} }

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