DOI: 10.1139/p56-152. THE CHEMICAL BOND IN SEMICONDUCTORS: THE GROUP V B TO VII B ELEMENTS AND COMPOUNDS FORMED BETWEEN THEM

THE CHEMICAL BOND IN SEMICONDUCTORS: THE GROUP V B TO VII B ELEMENTS AND COMPOUNDS FORMED BETWEEN THEM

10.1139/p56-152

Crossref journal-article

Canadian Science Publishing

Canadian Journal of Physics (155)

Abstract

A brief review is first given of the developments which led to an understanding of the important role played by chemical bonding in semiconductors. The properties of the Group V B to VII B elements and of some compounds formed between these elements are then considered according to the valence bond model of Pauling. This leads to the conclusion that the band scheme in these substances is somewhat different to that which has been generally accepted, and we discuss the new model in relation to their electrical and optical properties.

Bibliography

Mooser, E., & Pearson, W. B. (1956). THE CHEMICAL BOND IN SEMICONDUCTORS: THE GROUP V B TO VII B ELEMENTS AND COMPOUNDS FORMED BETWEEN THEM. Canadian Journal of Physics, 34(12A), 1369â1376.

Authors 2

E. Mooser (first)
W. B. Pearson (additional)

References 25 Referenced 27

BERLINCOURT, T. G. 1055. Phys. Rev. 99, 1716. (10.1103/PhysRev.99.1716)
B R U X K E, F. 1955. Halbleiterprobleme, Vol. 11 (Friedr. Vieweg and Sohn, Braunschwcig), p. 59.
GIBSON, A. F. and hiIoss, T. S. 1050. Proc. Phys. Soc. A, 63, 176. (10.1088/0370-1298/63/2/112)
GOLDSMID, H. J. 1056. Proc. Phys. Soc. B, 69, 203. (10.1088/0370-1301/69/2/310)
10.1063/1.1721437 / J. Appl. Phys. (1953)
{'key': 'p_11/p_11_1', 'first-page': '1', 'volume': '25', 'year': '1954', 'journal-title': 'Phps.'} / Phps. (1954)
HILSCH,R. and BARTH,N. 1955. ConfCrence de P h y s i q e des basses tempCratures, Paris.
10.1063/1.1746893 / J. Chem. Phys. by VON HIPPEL A. (1948)
HUME-ROTHERY, W. 1948. London). Electrons, atoms, metals and alloys (Iliffe and Sons, Ltd.
{'key': 'p_16/p_16_1', 'first-page': '477', 'volume': '15', 'author': 'F.', 'year': '1951', 'journal-title': 'Ser. Fiz.'} / Ser. Fiz. by F. (1951)
{'key': 'p_17/p_17_1', 'first-page': '193', 'volume': '29', 'author': 'JUNOD P.', 'year': '1956', 'journal-title': 'Helv. Phys. Acta'} / Helv. Phys. Acta by JUNOD P. (1956)
{'key': 'p_19/p_19_1', 'first-page': '177', 'volume': '282', 'author': 'REBS H.', 'year': '1955', 'journal-title': 'Chem.'} / Chem. by REBS H. (1955)
{'key': 'p_20/p_20_1', 'first-page': '263', 'volume': '283', 'author': 'REBS H', 'year': '1956', 'journal-title': 'Chem.'} / Chem. by REBS H (1956)
I<RONMULLER, H., JAUMANN, J., and SEILER,I< 1956. 2. Naturforsch. Ila,243. (10.1515/zna-1956-0313)
10.1103/PhysRev.101.1608 / Phys. Rev. by MOOSER E. (1956)
10.1103/PhysRev.101.492 / Phys. Rev. by MOOSER E. (1956)
h/Ioss, T. S. 1952. Photoconductivity in the elements (Butterworth Scientific Publications, London).
{'key': 'p_25/p_25_1', 'first-page': '11', 'volume': '3', 'author': 'NOGUCHI S.', 'year': '1954', 'journal-title': 'Oita Univ.'} / Oita Univ. by NOGUCHI S. (1954)
{'key': 'p_26/p_26_1', 'first-page': '343', 'volume': '196', 'author': 'PAULING L.', 'year': '1949', 'journal-title': 'SOC. A'} / SOC. A by PAULING L. (1949)
10.1088/0370-1301/64/8/308 / Proc. Phys. Soc. B by PLESSNER W. (1951)
SCHOTTKY, W. 1955. Halbleiterprobleme, 1'01. 11 (Friedr. Vieweg aud Sohn, Braunschweig), p. 282.
SCHWEICKERT, H. 1955. Halbleiterprobleme, Vol. 11 (Friedr. Vieweg and Sohn, Braunschweig), p. 66. (10.1007/BFb0119000)
SERAPHIN, B. 1954. 2. Naturforsch. 9a,450. (10.1515/zna-1954-0511)
10.1103/PhysRev.99.1751 / Phys. Rev. by STEELE M. C. (1955)
WELKER,H. 1952. 2. Naturforsch. 7a,744. (10.1515/zna-1952-1110)

Dates

Type	When
Created	16 years ago (Aug. 12, 2009, 9:55 a.m.)
Deposited	1 month, 2 weeks ago (July 2, 2025, 10:20 a.m.)
Indexed	1 month, 2 weeks ago (July 3, 2025, 12:08 a.m.)
Issued	68 years, 8 months ago (Dec. 1, 1956)
Published	68 years, 8 months ago (Dec. 1, 1956)
Published Print	68 years, 8 months ago (Dec. 1, 1956)

Funders 0

None

BibTeX

@article{Mooser_1956, title={THE CHEMICAL BOND IN SEMICONDUCTORS: THE GROUP V B TO VII B ELEMENTS AND COMPOUNDS FORMED BETWEEN THEM}, volume={34}, ISSN={1208-6045}, url={http://dx.doi.org/10.1139/p56-152}, DOI={10.1139/p56-152}, number={12A}, journal={Canadian Journal of Physics}, publisher={Canadian Science Publishing}, author={Mooser, E. and Pearson, W. B.}, year={1956}, month=dec, pages={1369–1376} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        3
      ]
    ],
    "date-time": "2025-07-03T04:08:03Z",
    "timestamp": 1751515683155,
    "version": "3.41.0"
  },
  "reference-count": 25,
  "publisher": "Canadian Science Publishing",
  "issue": "12A",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1956,
            12,
            1
          ]
        ],
        "date-time": "1956-12-01T00:00:00Z",
        "timestamp": -412905600000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "http://www.nrcresearchpress.com/page/about/CorporateTextAndDataMining"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1956,
        12,
        1
      ]
    ]
  },
  "abstract": "<jats:p> A brief review is first given of the developments which led to an understanding of the important role played by chemical bonding in semiconductors. The properties of the Group V B to VII B elements and of some compounds formed between these elements are then considered according to the valence bond model of Pauling. This leads to the conclusion that the band scheme in these substances is somewhat different to that which has been generally accepted, and we discuss the new model in relation to their electrical and optical properties. </jats:p>",
  "DOI": "10.1139/p56-152",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2009,
        8,
        12
      ]
    ],
    "date-time": "2009-08-12T13:55:38Z",
    "timestamp": 1250085338000
  },
  "page": "1369-1376",
  "source": "Crossref",
  "is-referenced-by-count": 27,
  "title": "THE CHEMICAL BOND IN SEMICONDUCTORS: THE GROUP V B TO VII B ELEMENTS AND COMPOUNDS FORMED BETWEEN THEM",
  "prefix": "10.1139",
  "volume": "34",
  "author": [
    {
      "given": "E.",
      "family": "Mooser",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "W. B.",
      "family": "Pearson",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "155",
  "reference": [
    {
      "key": "p_1/p_1_1",
      "doi-asserted-by": "crossref",
      "unstructured": "BERLINCOURT, T. G. 1055. Phys. Rev. 99, 1716.",
      "DOI": "10.1103/PhysRev.99.1716"
    },
    {
      "key": "p_2/p_2_1",
      "unstructured": "B R U X K E, F. 1955. Halbleiterprobleme, Vol. 11 (Friedr. Vieweg and Sohn, Braunschwcig), p. 59."
    },
    {
      "key": "p_6/p_6_1",
      "doi-asserted-by": "crossref",
      "unstructured": "GIBSON, A. F. and hiIoss, T. S. 1050. Proc. Phys. Soc. A, 63, 176.",
      "DOI": "10.1088/0370-1298/63/2/112"
    },
    {
      "key": "p_7/p_7_1",
      "doi-asserted-by": "crossref",
      "unstructured": "GOLDSMID, H. J. 1056. Proc. Phys. Soc. B, 69, 203.",
      "DOI": "10.1088/0370-1301/69/2/310"
    },
    {
      "key": "p_10/p_10_1",
      "doi-asserted-by": "crossref",
      "first-page": "1056",
      "DOI": "10.1063/1.1721437",
      "volume": "24",
      "year": "1953",
      "journal-title": "J. Appl. Phys."
    },
    {
      "key": "p_11/p_11_1",
      "first-page": "1",
      "volume": "25",
      "year": "1954",
      "journal-title": "Phps."
    },
    {
      "key": "p_13/p_13_1",
      "unstructured": "HILSCH,R. and BARTH,N. 1955. ConfCrence de P h y s i q e des basses tempCratures, Paris."
    },
    {
      "key": "p_14/p_14_1",
      "doi-asserted-by": "crossref",
      "first-page": "372",
      "DOI": "10.1063/1.1746893",
      "volume": "16",
      "author": "VON HIPPEL A.",
      "year": "1948",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "p_15/p_15_1",
      "unstructured": "HUME-ROTHERY, W. 1948. London). Electrons, atoms, metals and alloys (Iliffe and Sons, Ltd."
    },
    {
      "key": "p_16/p_16_1",
      "first-page": "477",
      "volume": "15",
      "author": "F.",
      "year": "1951",
      "journal-title": "Ser. Fiz."
    },
    {
      "key": "p_17/p_17_1",
      "first-page": "193",
      "volume": "29",
      "author": "JUNOD P.",
      "year": "1956",
      "journal-title": "Helv. Phys. Acta"
    },
    {
      "key": "p_19/p_19_1",
      "first-page": "177",
      "volume": "282",
      "author": "REBS H.",
      "year": "1955",
      "journal-title": "Chem."
    },
    {
      "key": "p_20/p_20_1",
      "first-page": "263",
      "volume": "283",
      "author": "REBS H",
      "year": "1956",
      "journal-title": "Chem."
    },
    {
      "key": "p_21/p_21_1",
      "doi-asserted-by": "crossref",
      "unstructured": "I<RONMULLER, H., JAUMANN, J., and SEILER,I< 1956. 2. Naturforsch. Ila,243.",
      "DOI": "10.1515/zna-1956-0313"
    },
    {
      "key": "p_22/p_22_1",
      "doi-asserted-by": "crossref",
      "first-page": "1608",
      "DOI": "10.1103/PhysRev.101.1608",
      "volume": "101",
      "author": "MOOSER E.",
      "year": "1956",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "p_23/p_23_1",
      "doi-asserted-by": "crossref",
      "first-page": "492",
      "DOI": "10.1103/PhysRev.101.492",
      "volume": "101",
      "author": "MOOSER E.",
      "year": "1956",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "p_24/p_24_1",
      "unstructured": "h/Ioss, T. S. 1952. Photoconductivity in the elements (Butterworth Scientific Publications, London)."
    },
    {
      "key": "p_25/p_25_1",
      "first-page": "11",
      "volume": "3",
      "author": "NOGUCHI S.",
      "year": "1954",
      "journal-title": "Oita Univ."
    },
    {
      "key": "p_26/p_26_1",
      "first-page": "343",
      "volume": "196",
      "author": "PAULING L.",
      "year": "1949",
      "journal-title": "SOC. A"
    },
    {
      "key": "p_27/p_27_1",
      "doi-asserted-by": "crossref",
      "first-page": "681",
      "DOI": "10.1088/0370-1301/64/8/308",
      "volume": "64",
      "author": "PLESSNER W.",
      "year": "1951",
      "journal-title": "Proc. Phys. Soc. B"
    },
    {
      "key": "p_28/p_28_1",
      "unstructured": "SCHOTTKY, W. 1955. Halbleiterprobleme, 1'01. 11 (Friedr. Vieweg aud Sohn, Braunschweig), p. 282."
    },
    {
      "key": "p_29/p_29_1",
      "doi-asserted-by": "crossref",
      "unstructured": "SCHWEICKERT, H. 1955. Halbleiterprobleme, Vol. 11 (Friedr. Vieweg and Sohn, Braunschweig), p. 66.",
      "DOI": "10.1007/BFb0119000"
    },
    {
      "key": "p_30/p_30_1",
      "doi-asserted-by": "crossref",
      "unstructured": "SERAPHIN, B. 1954. 2. Naturforsch. 9a,450.",
      "DOI": "10.1515/zna-1954-0511"
    },
    {
      "key": "p_31/p_31_1",
      "doi-asserted-by": "crossref",
      "first-page": "1751",
      "DOI": "10.1103/PhysRev.99.1751",
      "volume": "99",
      "author": "STEELE M. C.",
      "year": "1955",
      "journal-title": "Phys. Rev."
    },
    {
      "key": "p_32/p_32_1",
      "doi-asserted-by": "crossref",
      "unstructured": "WELKER,H. 1952. 2. Naturforsch. 7a,744.",
      "DOI": "10.1515/zna-1952-1110"
    }
  ],
  "container-title": "Canadian Journal of Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://cdnsciencepub.com/doi/pdf/10.1139/p56-152",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2025,
        7,
        2
      ]
    ],
    "date-time": "2025-07-02T14:20:32Z",
    "timestamp": 1751466032000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://cdnsciencepub.com/doi/10.1139/p56-152"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1956,
        12,
        1
      ]
    ]
  },
  "references-count": 25,
  "journal-issue": {
    "issue": "12A",
    "published-print": {
      "date-parts": [
        [
          1956,
          12,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1139/p56-152"
  ],
  "URL": "http://dx.doi.org/10.1139/p56-152",
  "relation": {},
  "ISSN": [
    "0008-4204",
    "1208-6045"
  ],
  "subject": [],
  "container-title-short": "Can. J. Phys.",
  "published": {
    "date-parts": [
      [
        1956,
        12,
        1
      ]
    ]
  }
}