Abstract
Poking a semiconductor Noncentrosymmetric crystal structure can lead to a peculiar kind of charge separation under illumination called the bulk photovoltaic (BPV) effect. Solar cells made of such materials, however, typically have low efficiency. Yang et al. expanded the class of materials capable of exhibiting the BPV effect by making ordinarily centrosymmetric materials, such as SrTiO 3 and TiO 2 , lose their inversion symmetry. The authors accomplished this by applying a point force on the surface of the material. This induced a strain gradient and the loss of inversion symmetry, resulting in large photovoltaic currents under illumination. The mechanism, dubbed the flexo-photovoltaic effect, is expected to apply to most semiconductors. Science , this issue p. 904
Authors
3
- Ming-Min Yang (first)
- Dong Jik Kim (additional)
- Marin Alexe (additional)
References
42
Referenced
360
10.1080/14786448508627681
10.1038/nmat4676
10.1126/science.aad4424
- A. Fahrenbruch R. Bube Fundamentals of Solar Cells: Photovoltaic Solar Energy Conversion (Elsevier 2012).
10.1063/1.1736034
10.1103/PhysRev.102.705
- B. I. Sturman V. M. Fridkin The Photovoltaic and Photorefractive Effects in Noncentrosymmetric Materials (Gordon and Breach Science Publishers 1992).
10.1038/nphoton.2016.143
10.1038/ncomms3835
10.1103/PhysRevB.34.5883
10.1146/annurev-matsci-071312-121634
10.1016/S0167-577X(99)00020-8
10.1371/journal.pone.0005201
10.1038/nnano.2015.260
10.1103/PhysRevB.77.033403
10.1103/PhysRevB.92.035417
10.1126/science.1218693
10.1038/srep43070
10.1103/PhysRevLett.99.167601
10.1134/1.1387133
- A. C. Fischer-Cripps Introduction to Contact Mechanics (Springer 2000).
- V. M. Fridkin Photoferroelectrics vol. 9 (Springer 2012).
10.1021/jz5015746
10.1103/PhysRevB.81.054115
10.1038/nphoton.2012.285
10.1021/nn4062353
10.1063/1.4871458
10.1063/1.4971798
10.1063/1.331987
10.1103/PhysRevLett.107.057602
10.1038/nmat1057
10.1038/ncomms7948
10.1002/smll.201001217
10.1016/S0009-2614(02)00820-5
- J. F. Nye Physical Properties of Crystals: Their Representation by Tensors and Matrices (Oxford Univ. Press 1985).
10.1063/1.4983032
- R. H. Bube Photoconductivity of Solids (Wiley 1960).
10.1063/1.1655453
10.1080/00150197808237365
10.1103/PhysRevLett.118.096601
10.1038/ncomms1261
10.1103/PhysRevB.90.161409
Dates
Type | When |
---|---|
Created | 7 years, 4 months ago (April 19, 2018, 2:05 p.m.) |
Deposited | 1 year, 7 months ago (Jan. 15, 2024, 12:12 p.m.) |
Indexed | 35 minutes ago (Aug. 27, 2025, 11:14 a.m.) |
Issued | 7 years, 3 months ago (May 25, 2018) |
Published | 7 years, 3 months ago (May 25, 2018) |
Published Print | 7 years, 3 months ago (May 25, 2018) |
Funders
4
Engineering and Physical Sciences Research Council
10.13039/501100000266
Region: Europe
gov (National government)
Labels
4
- UKRI Engineering and Physical Sciences Research Council
- Engineering and Physical Sciences Research Council - UKRI
- Engineering & Physical Sciences Research Council
- EPSRC
Awards
1
- EP/M022706/1
Engineering and Physical Sciences Research Council
10.13039/501100000266
Region: Europe
gov (National government)
Labels
4
- UKRI Engineering and Physical Sciences Research Council
- Engineering and Physical Sciences Research Council - UKRI
- Engineering & Physical Sciences Research Council
- EPSRC
Awards
1
- EP/P025803/1
Royal Society
10.13039/501100000288
Region: Europe
pri (Associations and societies (private and public))
Labels
1
- The Royal Society
Awards
1
- Wolfson Research Merit Award
Royal Society
10.13039/501100000288
Region: Europe
pri (Associations and societies (private and public))
Labels
1
- The Royal Society
Awards
1
- Theo Murphy Blue-Sky Award
@article{Yang_2018, title={Flexo-photovoltaic effect}, volume={360}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.aan3256}, DOI={10.1126/science.aan3256}, number={6391}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Yang, Ming-Min and Kim, Dong Jik and Alexe, Marin}, year={2018}, month=may, pages={904–907} }