DOI: 10.1126/science.282.5390.916. Spinodal Dewetting in Liquid Crystal and Liquid Metal Films

Spinodal Dewetting in Liquid Crystal and Liquid Metal Films

10.1126/science.282.5390.916

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

Theory predicts that dewetting of a homogeneous liquid film from a solid surface may proceed via unstable surface waves on the liquid. This phenomenon, usually termed spinodal dewetting, has been sought after in many systems. Observations in liquid crystal and liquid metal films showed that, as expected, the emerging structures were similar to those found for spinodal decomposition in mixtures. Certain differences, however, could be attributed to peculiarities of the wetting forces in these two dissimilar systems, thereby demonstrating the role of nonlinearities inherent in the wetting forces.

Bibliography

Herminghaus, S., Jacobs, K., Mecke, K., Bischof, J., Fery, A., Ibn-Elhaj, M., & Schlagowski, S. (1998). Spinodal Dewetting in Liquid Crystal and Liquid Metal Films. Science, 282(5390), 916â919.

Authors 7

Stephan Herminghaus (first)
Karin Jacobs (additional)
Klaus Mecke (additional)
Jörg Bischof (additional)
Andreas Fery (additional)
Mohammed Ibn-Elhaj (additional)
Stefan Schlagowski (additional)

References 36 Referenced 518

Reiter G., Phys. Rev. Lett. 68, 75 (1992). (10.1103/PhysRevLett.68.75) / Phys. Rev. Lett. by Reiter G. (1992)
Sharma A., Jameel A. T., J. Colloid Interface Sci. 161, 190 (1993). (10.1006/jcis.1993.1458) / J. Colloid Interface Sci. by Sharma A. (1993)
Elbaum M., Lipson S. G., Phys. Rev. Lett. 72, 3562 (1994). (10.1103/PhysRevLett.72.3562) / Phys. Rev. Lett. by Elbaum M. (1994)
Henn G., Bucknall D. G., Stamm M., Vanhoorne P., Jerome R., Macromolecules 29, 4305 (1996). (10.1021/ma9500392) / Macromolecules by Henn G. (1996)
Stange T. G., Evans D. F., Hendrickson W. A., Langmuir 13, 4459 (1997). (10.1021/la962090k) / Langmuir by Stange T. G. (1997)
Jacobs K., Herminghaus S., Mecke K. R., ibid. 14, 965 (1998). / ibid. by Jacobs K. (1998)
Xie R., Karim A., Douglas J. F., Han C. C., Weiss R. A., Phys. Rev. Lett. 81, 1251 (1998). (10.1103/PhysRevLett.81.1251) / Phys. Rev. Lett. by Xie R. (1998)
We discuss only films with a thickness within the range of the dispersion forces that is not thicker than ∼100 nm.
Vrij A., Discuss. Faraday Soc. 42, 23 (1966). (10.1039/df9664200023) / Discuss. Faraday Soc. by Vrij A. (1966)
Ruckenstein E., Jain R. K., Faraday Trans. II 70, 132 (1974). (10.1039/f29747000132) / Faraday Trans. II by Ruckenstein E. (1974)
Brochard-Wyart F., Daillant J., Can. J. Phys. 68, 1084 (1990). (10.1139/p90-151) / Can. J. Phys. by Brochard-Wyart F. (1990)
S. Dietrich in Phase Transitions and Critical Phenomena C. Domb and J. L. Lebowitz Eds. (Academic Press London 1988) vol. 12 pp. 1–218.
M. Schick in Les Houches Session XLVIII 1988: Liquids at Interfaces J. Charvolin et al. Eds. (Elsevier Science Amsterdam 1989) pp. 415–497.
Cahn J. W., J. Chem. Phys. 42, 93 (1965). (10.1063/1.1695731) / J. Chem. Phys. by Cahn J. W. (1965)
Mitlin V. S., J. Colloid Interface Sci. 156, 491 (1993). (10.1006/jcis.1993.1142) / J. Colloid Interface Sci. by Mitlin V. S. (1993)
Bischof J., Scherer D., Herminghaus S., Leiderer P., Phys. Rev. Lett. 77, 1536 (1996). (10.1103/PhysRevLett.77.1536) / Phys. Rev. Lett. by Bischof J. (1996)
Ibn-Elhaj M., Möhwald H., Cherkaoui M. Z., Zniber R., Langmuir 14, 504 (1998). (10.1021/la970761o) / Langmuir by Ibn-Elhaj M. (1998)
Riegler R., Engel M., Ber. Bunsenges. Phys. Chem. 95, 1424 (1991). (10.1002/bbpc.19910951121) / Ber. Bunsenges. Phys. Chem. by Riegler R. (1991)
The influence of the dipolar polarizability of the subphase on long-range wetting forces has been shown in studies on the wetting of pentane on water [
Ragil K., Meunier J., Broseta D., Indekeu J., Bonn D., Phys. Rev. Lett. 77, 1532 (1996); (10.1103/PhysRevLett.77.1532) / Phys. Rev. Lett. by Ragil K. (1996)
] among others.
Ripening of these structures was too slow to be observed on experimental time scales.
The possibility of imaging polar liquids has recently been demonstrated [
Fery A., Herminghaus S., Ultramicroscopy 69, 211 (1997)]. (10.1016/S0304-3991(97)00049-1) / Ultramicroscopy by Fery A. (1997)
The system thus relaxes toward a film of finite thickness that is incomplete wetting. This justifies the well-established term “dewetting ” even though the process does not leave a perfectly dry surface.
Ocko B. M., Braslau A., Pershan P. S., Als-Nielsen J., Deutsch M., Phys. Rev. Lett. 57, 94 (1986). (10.1103/PhysRevLett.57.94) / Phys. Rev. Lett. by Ocko B. M. (1986)
DeGennes P.-G., Langmuir 6, 1448 (1990). (10.1021/la00099a003) / Langmuir by DeGennes P.-G. (1990)
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Srolovitz D. J., Goldiner M. G., J. Met. 3, 31 (1995). / J. Met. by Srolovitz D. J. (1995)
An intermediate layer of a few monolayers of chromium (thickness <2 nm) was deposited to improve the adhesion of the films.
T. Iida and R. I. L. Guthrie The Physical Properties of Liquid Metals (Oxford Univ. Press Oxford 1987).
For simple monatomic liquids such as gold the liquid is not expected to slip along the substrate. In the absence of slippage the holes grow linear with time [
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Stimulating discussions with G. Reiter A. Sharma and P. Leiderer are gratefully acknowledged.

Dates

Type	When
Created	23 years, 1 month ago (July 27, 2002, 5:35 a.m.)
Deposited	1 year, 7 months ago (Jan. 13, 2024, 12:16 a.m.)
Indexed	3 weeks, 5 days ago (Aug. 6, 2025, 9:32 a.m.)
Issued	26 years, 10 months ago (Oct. 30, 1998)
Published	26 years, 10 months ago (Oct. 30, 1998)
Published Print	26 years, 10 months ago (Oct. 30, 1998)

Funders 0

None

BibTeX

@article{Herminghaus_1998, title={Spinodal Dewetting in Liquid Crystal and Liquid Metal Films}, volume={282}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.282.5390.916}, DOI={10.1126/science.282.5390.916}, number={5390}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Herminghaus, Stephan and Jacobs, Karin and Mecke, Klaus and Bischof, Jörg and Fery, Andreas and Ibn-Elhaj, Mohammed and Schlagowski, Stefan}, year={1998}, month=oct, pages={916–919} }

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