DOI: 10.1126/science.282.5389.720. Pressure-Induced Landau-Type Transition in Stishovite

Pressure-Induced Landau-Type Transition in Stishovite

10.1126/science.282.5389.720

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

A Rietveld structural analysis of stishovite, with angle-dispersive x-ray diffraction synchrotron source at the European Synchrotron Radiation Facility, confirmed a CaCl 2 form of stishovite distortion at 54 ± 1 gigapascals but confirmed no further phase transformation up to 120 gigapascals. The deviatoric stress that is usually encountered at such pressures was relaxed after yttrium-aluminum-garnet–laser heating. A single Birch-Murnaghan equation of state fits volumes of stishovite and a CaCl 2 form, showing that the tetragonal distortion occurs without a substantial change in volume. At the 54-gigapascal transition, the pressure-induced lattice modifications were similar to those found in a Landau-type temperature-induced transition. It is proposed that, above the transition pressure, the critical temperature increases above 300 kelvin, so that the lower entropy form becomes stable.

Bibliography

Andrault, D., Fiquet, G., Guyot, F., & Hanfland, M. (1998). Pressure-Induced Landau-Type Transition in Stishovite. Science, 282(5389), 720â724.

Authors 4

Denis Andrault (first)
Guillaume Fiquet (additional)
François Guyot (additional)
Michael Hanfland (additional)

References 29 Referenced 194

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We thank T. Charpin P. Richet N. L. Ross and two anonymous referees for their help and comments. D.A. thanks M. Kunz and L. W. Finger for their help with the GSAS code. This work was supported by the CNRS Institut National des Sciences de l'Univers Institut de Physique du Globe and ESRF programs.

Dates

Type	When
Created	23 years, 1 month ago (July 27, 2002, 5:50 a.m.)
Deposited	1 year, 7 months ago (Jan. 13, 2024, 12:12 a.m.)
Indexed	1 week, 1 day ago (Aug. 19, 2025, 6:20 a.m.)
Issued	26 years, 10 months ago (Oct. 23, 1998)
Published	26 years, 10 months ago (Oct. 23, 1998)
Published Print	26 years, 10 months ago (Oct. 23, 1998)

Funders 0

None

BibTeX

@article{Andrault_1998, title={Pressure-Induced Landau-Type Transition in Stishovite}, volume={282}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.282.5389.720}, DOI={10.1126/science.282.5389.720}, number={5389}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Andrault, Denis and Fiquet, Guillaume and Guyot, François and Hanfland, Michael}, year={1998}, month=oct, pages={720–724} }

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