Crossref journal-article
American Association for the Advancement of Science (AAAS)
Science (221)
Abstract

A previously unknown solid phase of H 2 O has been identified by its peculiar growth patterns, distinct pressure-temperature melting relations, and vibrational Raman spectra. Morphologies of ice crystals and their pressure-temperature melting relations were directly observed in a hydrothermal diamond-anvil cell for H 2 O bulk densities between 1203 and 1257 kilograms per cubic meter at temperatures between –10° and 50°C. Under these conditions, four different ice forms were observed to melt: two stable phases, ice V and ice VI, and two metastable phases, ice IV and the new ice phase. The Raman spectra and crystal morphology are consistent with a disordered anisotropic structure with some similarities to ice VI.

Bibliography

Chou, I.-M., Blank, J. G., Goncharov, A. F., Mao, H., & Hemley, R. J. (1998). In Situ Observations of a High-Pressure Phase of H 2 O Ice. Science, 281(5378), 809–812.

Authors 5
  1. I-Ming Chou (first)
  2. Jennifer G. Blank (additional)
  3. Alexander F. Goncharov (additional)
  4. Ho-kwang Mao (additional)
  5. Russell J. Hemley (additional)
References 37 Referenced 95
  1. Tammann G., Ann. Phys. 2, 1 (1900). (10.1002/andp.19003070502) / Ann. Phys. by Tammann G. (1900)
  2. Bridgman P. W., Proc. Am. Acad. Art Sci. 47, 441 (1912). (10.2307/20022754) / Proc. Am. Acad. Art Sci. by Bridgman P. W. (1912)
  3. 10.1038/310393a0
  4. ; ibid. 314 76 (1985); (10.1038/314076a0)
  5. Mishima O., ibid. 384, 546 (1996). / ibid. by Mishima O. (1996)
  6. 10.1038/360324a0
  7. Harrington S., Zhang R., Poole P. H., Sciortino F., Stanley H. E., Phys. Rev. Lett. 78, 2409 (1997). (10.1103/PhysRevLett.78.2409) / Phys. Rev. Lett. by Harrington S. (1997)
  8. 10.1126/science.273.5272.218
  9. Aoki K., Yamawaki H., Sakashita M., Fujihisa H., Phys. Rev. B 54, 15673 (1996). (10.1103/PhysRevB.54.15673) / Phys. Rev. B by Aoki K. (1996)
  10. Hemley R. J., Chen L. C., Mao H. K., Nature 338, 638 (1989). (10.1038/338638a0) / Nature by Hemley R. J. (1989)
  11. Englehardt H., Whalley E., J. Chem. Phys. 56, 2678 (1972). (10.1063/1.1677596) / J. Chem. Phys. by Englehardt H. (1972)
  12. Bridgman P. W., ibid. 3, 597 (1935). / ibid. by Bridgman P. W. (1935)
  13. Bizhigitov T. B., Sirota N. N., JETP Lett. 44, 417 (1986). / JETP Lett. by Bizhigitov T. B. (1986)
  14. Evans L. F., J. Appl. Phys. 38, 4930 (1967). (10.1063/1.1709255) / J. Appl. Phys. by Evans L. F. (1967)
  15. P. V. Hobbs Ice Physics (Clarendon Press Oxford 1974). See for example figure 1.19.
  16. Chou I. M., Haselton H. T., Rev. High Press. Sci. Tech. 7, 1132 (1998). (10.4131/jshpreview.7.1132) / Rev. High Press. Sci. Tech. by Chou I. M. (1998)
  17. B. Kamb in Physics and Chemistry of Ice E. Whalley S. J. Jones L. W. Gold Eds. (Royal Society of Canada Ottawa 1973) pp. 28–41.
  18. Lobban C., Finney J. L., Kuhs W. F., Nature 391, 268 (1998). (10.1038/34622) / Nature by Lobban C. (1998)
  19. Mishima O., Stanley H. E., Rev. High Press. Sci. Tech. 7, 1103 (1998). (10.4131/jshpreview.7.1103) / Rev. High Press. Sci. Tech. by Mishima O. (1998)
  20. Bassett W. A., Shen A. H., Bucknum M., Chou I. M., Rev. Sci. Instr. 64, 2340 (1993). (10.1063/1.1143931) / Rev. Sci. Instr. by Bassett W. A. (1993)
  21. The sample was cooled by a stream of cold nitrogen and heated by two individual heaters and the sample temperatures were detected by two K-type thermocouples in direct contact with the diamonds; for the reported temperatures the precision is ±0.1°C and accuracy is ±0.5°C. The images of the sample under a microscope together with the temperature and time information were recorded continuously on videotape.
  22. Wagner W., Saul A., Pruss A., J. Phys. Chem. Ref. Data 23, 515 (1994). (10.1063/1.555947) / J. Phys. Chem. Ref. Data by Wagner W. (1994)
  23. Saul A., Wagner W., ibid. 18, 1537 (1989). / ibid. by Saul A. (1989)
  24. For example for experiment 10 (Table 1) observations were made at a fixed bulk water density and the new phase ice V and ice VI were observed to melt at 8.1° 6.5° and 13.0°C respectively. The bulk water density calculated from T m of ice VI is 1212 kg/m 3 which yielded a pressure of 775 MPa at T m = 8.1°C; a pressure of 779 MPa was obtained when we assumed that the bulk water density was 1213 kg/m 3 (on the basis of the melting point of ice V). The two calculated pressures for the melting of the new phase at 8.1°C agree. Similar results were also obtained for other melting temperatures (Fig. 3) even under more extreme P-T conditions where uncertainties are involved in extrapolating both the melting curve of ice V (18) and the equation of state of water (19).
  25. A quantitative determination of the birefringence cannot be made because samples were viewed between the two diamonds the tips of which become birefringent under stress.
  26. Sivakumar T. C., Rice S. A., J. Chem. Phys. 69, 3468 (1978); (10.1063/1.437079) / J. Chem. Phys. by Sivakumar T. C. (1978)
  27. Klug D. D., Mishima O., Whalley E., ibid. 86, 5323 (1987); / ibid. by Klug D. D. (1987)
  28. . These amorphous forms are reportedly stable only at lower temperatures.
  29. The lowest frequency band sharpened somewhat with decreasing temperature but no new peaks appeared. This observation together with weak frequency shifts indicates that the phase did not become significantly more ordered with cooling. The 192 cm −1 band and the structure of spectrum in the O–H stretching region are also similar to that measured for ice III; however the latter also has a characteristic band at 95 cm −1 which was not observed for the new phase.
  30. Kamb (13) proposed that pressure-quenched ice VI is partially ordered with space group Pmmn. In its stability field the phase is proton-disordered (space group P 4 2 / nmc ) and a fully ordered form (space group Pn ) was also predicted (13). Subsequent study by W. L. Kuhs J. L. Finney C. Vettier and D. V. Bliss [ J. Chem. Phys. 81 3612 (1984)] confirmed that the space group of ice VI is P 4 2 / nmc. Our results indicate that the new phase is more extensively disordered. Because of the lack of data it is difficult to speculate the relation if any between the new phase and the one recently found at lower pressures by Lobban et al. (14) .
  31. I. M. Chou in Workshop on Hydrogen Bonds at High Pressure (Japan Science and Technology Corporation Gifu Japan 21 to 23 August 1997) p. 11.
  32. 10.2138/am-1995-11-1220
  33. G. D'Arrigo
  34. Maisano G., Mallemace F., Migliardo P., Wanderlingh F., J. Chem. Phys. 75, 4264 (1981). (10.1063/1.442629) / J. Chem. Phys. by Maisano G. (1981)
  35. Bansil R., Wiafe-Akenten J., Taaffe J. L., ibid. 76, 2221 (1982); / ibid. by Bansil R. (1982)
  36. ; Y. Yeh J. H. Bilgram W. Kanzig ibid. 77 2317 (1982). (10.1063/1.444142)
  37. We thank W. A. Bassett H. T. Haselton Jr. E. Karmon and V. V. Struzhkin for assistance with experiments and P. B. Barton Jr. and R. R. Seal for reviews. Supported by the U.S. Geological Survey (Deep Continental Studies Program) NSF (D.M.R. and E.A.R.) and NASA.
Dates
Type When
Created 23 years, 1 month ago (July 27, 2002, 5:43 a.m.)
Deposited 1 year, 7 months ago (Jan. 12, 2024, 10 p.m.)
Indexed 13 hours, 8 minutes ago (Sept. 1, 2025, 6:32 a.m.)
Issued 27 years ago (Aug. 7, 1998)
Published 27 years ago (Aug. 7, 1998)
Published Print 27 years ago (Aug. 7, 1998)
Funders 0

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@article{Chou_1998, title={In Situ Observations of a High-Pressure Phase of H 2 O Ice}, volume={281}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.281.5378.809}, DOI={10.1126/science.281.5378.809}, number={5378}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Chou, I-Ming and Blank, Jennifer G. and Goncharov, Alexander F. and Mao, Ho-kwang and Hemley, Russell J.}, year={1998}, month=aug, pages={809–812} }