Crossref journal-article
American Association for the Advancement of Science (AAAS)
Science (221)
Abstract

Indirect evidence for life on Mars has been reported from the study of meteorite ALH84001. The formation temperature of the carbonates is controversial; some estimates suggest 20° to 80°C, whereas others exceed 650°C. Paleomagnetism can be used to distinguish between these possibilities because heating can remagnetize ferrimagnetic minerals. Study of two adjacent pyroxene grains from the crushed zone of ALH84001 shows that each possesses a stable natural remanent magnetization (NRM), implying that Mars had a substantial magnetic field when the grains cooled. However, NRM directions from these particles differ, implying that the meteorite has not been heated significantly since the formation of the internal crushed zone about 4 billion years ago. The carbonate globules postdate this brecciation, and thus formed at low temperatures.

Bibliography

Kirschvink, J. L., Maine, A. T., & Vali, H. (1997). Paleomagnetic Evidence of a Low-Temperature Origin of Carbonate in the Martian Meteorite ALH84001. Science, 275(5306), 1629–1633.

Authors 3
  1. Joseph L. Kirschvink (first)
  2. Altair T. Maine (additional)
  3. Hojatollah Vali (additional)
References 34 Referenced 102
  1. 10.1126/science.273.5277.924
  2. Jagoutz E., et al.., Meteoritics 294781994. / Meteoritics by Jagoutz E. (1994)
  3. Nyquist L. E., Bansal B., Wiesmann H., Shih C.-Y., Lunar Planet. Sci. XXVI10651995. / Lunar Planet. Sci. by Nyquist L. E. (1995)
  4. Ash R. D., Knott S. F., Turner G., Nature 380571996. (10.1038/380057a0) / Nature by Ash R. D. (1996)
  5. 10.1111/j.1945-5100.1995.tb01127.x
  6. Griffith L. L., Shock E. L., Nature 3774061995. (10.1038/377406a0) / Nature by Griffith L. L. (1995)
  7. Wadhwa M., Lugmair G. W., Meteoritics Planet. Sci. 31(suppl.)A1451996. / Meteoritics Planet. Sci. by Wadhwa M. (1996)
  8. 10.1016/0016-7037(94)00359-T
  9. 10.1038/372655a0
  10. 10.1111/j.1945-5100.1994.tb00673.x
  11. 10.1038/382049a0
  12. Bradley J. P., Harvey R. P., McSween H. Y., Geochim. Cosmochim. Acta 6051491996. (10.1016/S0016-7037(96)00383-3) / Geochim. Cosmochim. Acta by Bradley J. P. (1996)
  13. Vali H., Kirschvink J. L., Iron Biomineralization, Frankel R. P., Blakemore R. P., Eds. (PlenumNew York199197115. (10.1007/978-1-4615-3810-3_7) / Iron Biomineralization by Vali H. (1991)
  14. Mann S., et al.., J. Exp. Biology 140351988. (10.1242/jeb.140.1.35) / J. Exp. Biology by Mann S. (1988)
  15. Several possibilities exist. First if the crushed material in ALH84001 was heated either during or after carbonate precipitation all of the pyroxene grains would be left magnetized in the same direction. Second if the crushed zone cooled before the carbonates were precipitated the pyroxene grains would have a uniform direction but might differ from that of the carbonate. Third if the crushed zone formed after the pyroxene had cooled particles within it should have a dispersion of magnetic directions resulting from their physical rotation. This is a simple variation of the conglomerate test (26). Fourth low to intermediate levels of heating after formation of the crushed zone should remagnetize only the lower portion of the blocking temperature spectrum of the meteorite and the directionally consistent component could be recognized.
  16. Collinson D. W., Earth Planet. Sci. Lett. 71591986. (10.1016/0012-821X(86)90157-3) / Earth Planet. Sci. Lett. by Collinson D. W. (1986)
  17. Cisowski S. M., Geochim. Cosmochim. Acta 5010431986. (10.1016/0016-7037(86)90386-8) / Geochim. Cosmochim. Acta by Cisowski S. M. (1986)
  18. Tanaka H., et al.., Geophys. J. Int. 120971995. (10.1111/j.1365-246X.1995.tb05913.x) / Geophys. J. Int. by Tanaka H. (1995)
  19. Runcorn S. K., Geochim. Cosmochim. Acta 6012051996. (10.1016/0016-7037(96)00024-5) / Geochim. Cosmochim. Acta by Runcorn S. K. (1996)
  20. O'Reilly W., Rock and Mineral Magnetism(BlackieLondon1984. (10.1007/978-1-4684-8468-7) / Rock and Mineral Magnetism by O'Reilly W. (1984)
  21. Dekkers M. J., Phys. Earth Planet. Inter. 572661989. Note that K. L. Thomas et al. [Lunar Planet. Sci.XXVII, 1327 {1996)] have imaged inclusions of magnetite within the pyroxene; however, these appear to have been formed on the fracture surfaces at the same time as the magnetite and Fe-sulfide phases associated with the carbonate globule. (10.1016/0031-9201(89)90116-7) / Phys. Earth Planet. Inter. by Dekkers M. J. (1989)
  22. Kirschvink J. L., Biomagnetism: An Interdisciplinary Approach, Williamson S., Ed. (PlenumNew York1983501532. (10.1007/978-1-4757-1785-3_14) / Biomagnetism: An Interdisciplinary Approach by Kirschvink J. L. (1983)
  23. The intact sample was mounted at one end of a quartz-glass fiber 15 cm long and 1 mm in diameter which had been cleaned in concentrated HCl. It was attached to this fiber using cyanoacrylate cement that had been passed through a 0.2-μm syringe filter to remove ferromagnetic impurities (Fig. 1A). The opposite end of the fiber was attached to the vertex of a flat quartz-glass triangle such that the open face of the carbonate layer on the fracture surface was aligned parallel to the triangle's surface. The edge of the triangle opposite from the fiber attachment was fused to an elongate hook allowing the assembly to be suspended vertically on a thin (∼200-g test) nylon fishing line U-loop. This loop was wound on a Teflon spool attached to a small computer-controlled stepping motor mounted on the ceiling of the clean-lab facility and held directly above the room-temperature access port of the superconducting magnetometer. With this assembly the sample could be raised and lowered smoothly from the sample loading position to a pair of computer-controlled solenoids for the demagnetization and rock magnetic experiments and to the center of a three-axis superconducting moment magnetometer (a 2G Enterprises® model 570 with DC-biased SQuIDs). A horizontal arrow marked on the quartz triangle was aligned with the + X direction of the superconducting moment magnetometer; vertical down was + Z and the + Y direction formed the third axis of a right-handed orthogonal coordinate system. We were able to obtain replicate measurements to better than 1% intensity and 0.5° in direction on magnetic moments as weak as 10 −12 A m −2 equivalent to the saturation remanence produced by ∼20 picograms of single-domain (SD) magnetite.
  24. This separation was done using a 150-μm-thick diamond-impregnated copper wafering saw. The flat surface of the carbonate-bearing grain was first glued to a thin Pyrex cover slip such that it was parallel to the surface of the quartz-glass triangle. The magnetic moment of this new assembly was indistinguishable from that measured prior to addition of the cover slip and the additional cement confirming that they were both nonmagnetic. The other surface of the Pyrex cover slip was then bound to the surface of a cylindrical brass stub with a temperature-sensitive adhesive that had been filtered in acetone to remove ferromagnetic contaminants. The orientation of the quartz fiber was marked on the brass surface. Shortly after we began our first cut the bond between the cyanoacrylic cement and the cover slip gave way. This left a small notch in the sample at the boundary between the pyroxene grains (Fig. 1A). By remeasuring the NRM of the sample after this step we were able to calculate by difference the NRM vector that had been held by the material removed in the cut. Next we fixed the flat surface of the carbonate-bearing layer directly to the brass stub with the adhesive which held properly during the remainder of the wafering process. This last cut was adjusted slightly so that most material was removed from the larger grain leaving a 2.2-mg fragment of the small pyroxene grain on the brass stub (Fig. 1D). While it was still bound to the stub we then used the cyanoacrylate to cement a second quartz-glass triangle and fiber assembly to the this new fragment with a relative orientation identical to that of the first sample. It was then freed from the brass stub by heating briefly to 110°C and washed with filtered acetone to dissolve traces of the adhesive. The sawing procedure left a 1.6-mg fragment of the carbonate-bearing grain attached to the larger pyroxene grain. After measurement of the NRM we were able to break this free with a nonmagnetic ceramic scalpel blade and by re-measuring the NRM vector were able to recover by difference the NRM vector of this small chip. The final weight of the pyroxene grain was 12.7 mg implying that a total of 3.4 mg of the sample was lost in both sawing operations.
  25. Gooding J. L., Icarus 99281992. (10.1016/0019-1035(92)90168-7) / Icarus by Gooding J. L. (1992)
  26. Butler R. F., Paleomagnetism: Magnetic Domains to Geologic Terranes (BlackwellBoston1992). / Paleomagnetism: Magnetic Domains to Geologic Terranes by Butler R. F. (1992)
  27. AF demagnetization was not continued to higher levels for the small pyroxene grain because the intensity became weak and it had a linear decay toward the origin. Thermal demagnetization experiments were not done because of the possibility of irreversible mineralogical changes on some of the Fe-S minerals such as the iron monosulfides reported by McKay et al. (1).
  28. 10.1111/j.1365-246X.1980.tb02601.x
  29. Mcfadden P. L., McElhinny M. W., Earth Planet. Sci. Lett. 871611988. (10.1016/0012-821X(88)90072-6) / Earth Planet. Sci. Lett. by Mcfadden P. L. (1988)
  30. Shearer C. K., et al.., Geochim. Cosmochim. Acta 6029211996. (10.1016/0016-7037(96)00165-2) / Geochim. Cosmochim. Acta by Shearer C. K. (1996)
  31. Dekkers M. J., Phys. Earth Planet. Inter. 523761988. (10.1016/0031-9201(88)90129-X) / Phys. Earth Planet. Inter. by Dekkers M. J. (1988)
  32. Johnson H. P., et al.., Geophys. J. R. Astron. Soc. 4111975. (10.1111/j.1365-246X.1975.tb05480.x) / Geophys. J. R. Astron. Soc. by Johnson H. P. (1975)
  33. Cisowski S., Phys. Earth Planet. Inter. 26561981. (10.1016/0031-9201(81)90097-2) / Phys. Earth Planet. Inter. by Cisowski S. (1981)
  34. We thank D. McKay and E. K. Gibson for our sample of ALH84001 P. Carpenter for assistance with the SEM and G. R. Rossman for help with the delicate sawing operation. H.V. acknowledges financial support from the U.S. National Research Council. We made extensive use of the software provided by C. Jones (cjones@mantle.colorado.edu) for the analysis and presentation of paleomagnetic data. B. C. Murray J. Eiler and D. A. Evans made helpful suggestions on the manuscript. This is contribution no. 5897 from the Division of Geological and Planetary Sciences of the California Institute of Technology.
Dates
Type When
Created 23 years ago (July 27, 2002, 5:45 a.m.)
Deposited 1 year, 7 months ago (Jan. 12, 2024, 10:58 p.m.)
Indexed 2 weeks, 6 days ago (Aug. 6, 2025, 8:49 a.m.)
Issued 28 years, 5 months ago (March 14, 1997)
Published 28 years, 5 months ago (March 14, 1997)
Published Print 28 years, 5 months ago (March 14, 1997)
Funders 0

None

@article{Kirschvink_1997, title={Paleomagnetic Evidence of a Low-Temperature Origin of Carbonate in the Martian Meteorite ALH84001}, volume={275}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.275.5306.1629}, DOI={10.1126/science.275.5306.1629}, number={5306}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Kirschvink, Joseph L. and Maine, Altair T. and Vali, Hojatollah}, year={1997}, month=mar, pages={1629–1633} }