DOI: 10.1126/science.272.5262.704. Photoinduced Magnetization of a Cobalt-Iron Cyanide

Photoinduced Magnetization of a Cobalt-Iron Cyanide

10.1126/science.272.5262.704

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

Photoinduced magnetization was observed in a Prussian blue analog, K 0.2 Co 1.4 - [Fe(CN) 6 ]⋅6.9H 2 O. An increase in the critical temperature from 16 to 19 kelvin was observed as a result of red light illumination. Moreover, the magnetization in the ferrimagnetic region below 16 kelvin was substantially increased after illumination and could be restored almost to its original level by thermal treatment. These effects are thought to be caused by an internal photochemical redox reaction. Furthermore, blue light illumination could be used to partly remove the enhancement of the magnetization. Such control over magnetic properties by optical stimuli may have application in magneto-optical devices.

Bibliography

Sato, O., Iyoda, T., Fujishima, A., & Hashimoto, K. (1996). Photoinduced Magnetization of a Cobalt-Iron Cyanide. Science, 272(5262), 704â705.

Authors 4

O. Sato (first)
T. Iyoda (additional)
A. Fujishima (additional)
K. Hashimoto (additional)

References 19 Referenced 1,675

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DECURTINS S, LIGHT-INDUCED EXCITED SPIN STATE TRAPPING IN A TRANSITION-METAL COMPLEX - THE HEXA-1-PROPYLTETRAZOLE-IRON (II) TETRAFLUOROBORATE SPIN-CROSSOVER SYSTEM, CHEMICAL PHYSICS LETTERS 105, 1 (1984). (10.1016/0009-2614(84)80403-0) / CHEMICAL PHYSICS LETTERS / LIGHT-INDUCED EXCITED SPIN STATE TRAPPING IN A TRANSITION-METAL COMPLEX - THE HEXA-1-PROPYLTETRAZOLE-IRON (II) TETRAFLUOROBORATE SPIN-CROSSOVER SYSTEM by DECURTINS S (1984)
ENTLEY W.R., NEW 3-DIMENSIONAL FERRIMAGNETIC MATERIALS - K2MN[MN(CN)(6)], MN-3[MN(CN)(6)]CENTER-DOT(2)12H2O, AND CSMN[MN(CN)(6)]CENTER-DOT-1/2H2O, INORGANIC CHEMISTRY 33, 5165 (1994). (10.1021/ic00101a003) / INORGANIC CHEMISTRY / NEW 3-DIMENSIONAL FERRIMAGNETIC MATERIALS - K2MN[MN(CN)(6)], MN-3[MN(CN)(6)]CENTER-DOT(2)12H2O, AND CSMN[MN(CN)(6)]CENTER-DOT-1/2H2O by ENTLEY W.R. (1994)
ENTLEY W.R., HIGH-TEMPERATURE MOLECULAR MAGNETS BASED ON CYANOVANADATE BUILDING-BLOCKS - SPONTANEOUS MAGNETIZATION AT 230-K, SCIENCE 268, 397 (1995). (10.1126/science.268.5209.397) / SCIENCE / HIGH-TEMPERATURE MOLECULAR MAGNETS BASED ON CYANOVANADATE BUILDING-BLOCKS - SPONTANEOUS MAGNETIZATION AT 230-K by ENTLEY W.R. (1995)
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GATTESCHI D, MOLECULAR MAGNETISM - A BASIS FOR NEW MATERIALS, ADVANCED MATERIALS 6, 635 (1994). (10.1002/adma.19940060903) / ADVANCED MATERIALS / MOLECULAR MAGNETISM - A BASIS FOR NEW MATERIALS by GATTESCHI D (1994)
GRIEBLER W.D., X-RAY AND MAGNETIC STUDIES OF PEROVSKITE-RELATED CYANO COMPOUNDS CSMIIMIII(CN)6, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 37, 832 (1982). (10.1515/znb-1982-0709) / ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES / X-RAY AND MAGNETIC STUDIES OF PEROVSKITE-RELATED CYANO COMPOUNDS CSMIIMIII(CN)6 by GRIEBLER W.D. (1982)
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JUSZCZYK S, FERROMAGNETISM OF THE ME3[FE(CN)6]2-CENTER-DOT-H2O COMPOUNDS, WHERE ME=NI AND CO, JOURNAL OF PHYSICS-CONDENSED MATTER 6, 5697 (1994). (10.1088/0953-8984/6/29/012) / JOURNAL OF PHYSICS-CONDENSED MATTER / FERROMAGNETISM OF THE ME3[FE(CN)6]2-CENTER-DOT-H2O COMPOUNDS, WHERE ME=NI AND CO by JUSZCZYK S (1994)
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10.1126/science.262.5139.1554
MILLER J.S., ORGANIC AND ORGANOMETALLIC MOLECULAR MAGNETIC-MATERIALS - DESIGNER MAGNETS, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 33, 385 (1994). (10.1002/anie.199403851) / ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH / ORGANIC AND ORGANOMETALLIC MOLECULAR MAGNETIC-MATERIALS - DESIGNER MAGNETS by MILLER J.S. (1994)
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SATO O, Electrochemically tunable magnetic phase transition in a high-T-c chromium cyanide thin film, SCIENCE 271, 49 (1996). (10.1126/science.271.5245.49) / SCIENCE / Electrochemically tunable magnetic phase transition in a high-T-c chromium cyanide thin film by SATO O (1996)
VERDAGUER M, CONTRIBUTIONS DEV CO (1993). / CONTRIBUTIONS DEV CO by VERDAGUER M (1993)
WOJTOWICZ T, MAGNETIZATION OF BOUND MAGNETIC POLARONS - DIRECT DETERMINATION VIA PHOTOMEMORY EFFECT, PHYSICAL REVIEW LETTERS 70, 2317 (1993). (10.1103/PhysRevLett.70.2317) / PHYSICAL REVIEW LETTERS / MAGNETIZATION OF BOUND MAGNETIC POLARONS - DIRECT DETERMINATION VIA PHOTOMEMORY EFFECT by WOJTOWICZ T (1993)

Dates

Type	When
Created	18 years, 9 months ago (Oct. 27, 2006, 2:30 p.m.)
Deposited	1 year, 7 months ago (Jan. 12, 2024, 4:44 p.m.)
Indexed	2 days ago (Aug. 23, 2025, 9:18 p.m.)
Issued	29 years, 3 months ago (May 3, 1996)
Published	29 years, 3 months ago (May 3, 1996)
Published Print	29 years, 3 months ago (May 3, 1996)

Funders 0

None

BibTeX

@article{Sato_1996, title={Photoinduced Magnetization of a Cobalt-Iron Cyanide}, volume={272}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.272.5262.704}, DOI={10.1126/science.272.5262.704}, number={5262}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Sato, O. and Iyoda, T. and Fujishima, A. and Hashimoto, K.}, year={1996}, month=may, pages={704–705} }

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      ]
    ]
  },
  "references-count": 19,
  "journal-issue": {
    "issue": "5262",
    "published-print": {
      "date-parts": [
        [
          1996,
          5,
          3
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1126/science.272.5262.704"
  ],
  "URL": "http://dx.doi.org/10.1126/science.272.5262.704",
  "relation": {},
  "ISSN": [
    "0036-8075",
    "1095-9203"
  ],
  "subject": [],
  "container-title-short": "Science",
  "published": {
    "date-parts": [
      [
        1996,
        5,
        3
      ]
    ]
  }
}