Abstract
Materials with nanoscopic dimensions not only have potential technological applications in areas such as device technology and drug delivery but also are of fundamental interest in that the properties of a material can change in this regime of transition between the bulk and molecular scales. In this article, a relatively new method for preparing nanomaterials, membrane-based synthesis, is reviewed. This method entails synthesis of the desired material within the pores of a nanoporous membrane. Because the membranes used contain cylindrical pores of uniform diameter, monodisperse nanocylinders of the desired material, whose dimensions can be carefully controlled, are obtained. This "template" method has been used to prepare polymers, metals, semiconductors, and other materials on a nanoscopic scale.
References
65
Referenced
3,740
10.1126/science.254.5036.1300
- Asada T. Japanese patent 310 401 (1960).
-
ALMAWLAWI, D, MAGNETIC-PROPERTIES OF FE DEPOSITED INTO ANODIC ALUMINUM-OXIDE PORES AS A FUNCTION OF PARTICLE-SIZE, JOURNAL OF APPLIED PHYSICS 70: 4421 (1991).
(
10.1063/1.349125
) / JOURNAL OF APPLIED PHYSICS (1991) - BATE, R.T., THE QUANTUM-EFFECT DEVICE - TOMORROWS TRANSISTOR, SCIENTIFIC AMERICAN 258: 96 (1988). / SCIENTIFIC AMERICAN (1988)
-
BECK, J.S., A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 114: 10834 (1992).
(
10.1021/ja00053a020
) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1992) 10.1021/ar00118a005
-
BRUMLIK, C.J., MICROHOLE ARRAY ELECTRODES BASED ON MICROPOROUS ALUMINA MEMBRANES, ANALYTICAL CHEMISTRY 64: 1201 (1992).
(
10.1021/ac00034a022
) / ANALYTICAL CHEMISTRY (1992) -
BRUMLIK, C.J., TEMPLATE SYNTHESIS OF METAL MICROTUBULES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 113: 3174 (1991).
(
10.1021/ja00008a057
) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1991) -
BRUMLIK, C.J., TEMPLATE SYNTHESIS OF METAL MICROTUBULE ENSEMBLES UTILIZING CHEMICAL, ELECTROCHEMICAL, AND VACUUM DEPOSITION TECHNIQUES, JOURNAL OF MATERIALS RESEARCH 9: 1174 (1994).
(
10.1557/JMR.1994.1174
) / JOURNAL OF MATERIALS RESEARCH (1994) - BURFORD, R.P., J MATER SCI 26: 3264 (1993). / J MATER SCI (1993)
-
CAHALANE, W, CHEM MATER 1: 519 (1989).
(
10.1021/cm00005a011
) / CHEM MATER (1989) -
CAI, Z.H., MOLECULAR AND SUPERMOLECULAR ORIGINS OF ENHANCED ELECTRONIC CONDUCTIVITY IN TEMPLATE-SYNTHESIZED POLYHETEROCYCLIC FIBRILS .1. SUPERMOLECULAR EFFECTS, CHEMISTRY OF MATERIALS 3: 960 (1991).
(
10.1021/cm00017a036
) / CHEMISTRY OF MATERIALS (1991) -
CAI, Z.H., ELECTRONICALLY CONDUCTIVE POLYMER FIBERS WITH MESOSCOPIC DIAMETERS SHOW ENHANCED ELECTRONIC CONDUCTIVITIES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 111: 4138 (1989).
(
10.1021/ja00193a077
) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1989) -
CAI, Z.H., ELECTROCHEMICAL INVESTIGATIONS OF ELECTRONICALLY CONDUCTIVE POLYMERS .6. MECHANISM OF THE REDOX REACTIONS FOR THE ELECTRONICALLY CONDUCTIVE FORM OF POLYPYRROLE, JOURNAL OF ELECTROANALYTICAL CHEMISTRY 300: 35 (1991).
(
10.1016/0022-0728(91)85382-Y
) / JOURNAL OF ELECTROANALYTICAL CHEMISTRY (1991) -
Chakarvarti, S. K., Journal of Micromechanics and Microengineering 3: 57 (1993).
(
10.1088/0960-1317/3/2/004
) / Journal of Micromechanics and Microengineering (1993) - CHAKARVARTI, S.K., MORPHOLOGY OF ETCHED PORES AND MICROSTRUCTURES FABRICATED FROM NUCLEAR TRACK FILTERS, NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS 62: 109 (1991). / NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS (1991)
-
CHENG, I.F., ULTRAMICROELECTRODE ENSEMBLES - COMPARISON OF EXPERIMENTAL AND THEORETICAL RESPONSES AND EVALUATION OF ELECTROANALYTICAL DETECTION LIMITS, ANALYTICAL CHEMISTRY 61: 762 (1989).
(
10.1021/ac00182a024
) / ANALYTICAL CHEMISTRY (1989) - Despic, A., Modern Aspects of Electrochemistry 20: CH6 (1989). / Modern Aspects of Electrochemistry (1989)
-
DEVORET, M.H., SINGLE-ELECTRON TRANSFER IN METALLIC NANOSTRUCTURES, NATURE 360: 547 (1992).
(
10.1038/360547a0
) / NATURE (1992) 10.1126/science.257.5070.642
-
Fleischer R. L. Nuclear Tracks in Solids (1975).
(
10.1525/9780520320239
) - Fosong, W., Molecular Crystals and Liquid Crystals 160: 175 (1988). / Molecular Crystals and Liquid Crystals (1988)
-
FOSS, C.A., OPTICAL-PROPERTIES OF COMPOSITE MEMBRANES CONTAINING ARRAYS OF NANOSCOPIC GOLD CYLINDERS, JOURNAL OF PHYSICAL CHEMISTRY 96: 7497 (1992).
(
10.1021/j100198a004
) / JOURNAL OF PHYSICAL CHEMISTRY (1992) -
FOSS, C.A., TEMPLATE-SYNTHESIZED NANOSCOPIC GOLD PARTICLES - OPTICAL-SPECTRA AND THE EFFECTS OF PARTICLE-SIZE AND SHAPE, JOURNAL OF PHYSICAL CHEMISTRY 98: 2963 (1994).
(
10.1021/j100062a037
) / JOURNAL OF PHYSICAL CHEMISTRY (1994) -
GRANSTROM, M, STUDIES OF STRUCTURE AND CONDUCTIVITY IN POLY(PYRROLE) AND POLY(THIOPHENE-OCTYLTHIOPHENE) GROWN IN MICROPOROUS MEMBRANES, SYNTHETIC METALS 55: 460 (1993).
(
10.1016/0379-6779(93)90975-3
) / SYNTHETIC METALS (1993) 10.1126/science.8128245
10.1126/science.263.5148.800
- Jewell, J. L., Scientific American 265:86 (1991). / Scientific American (1991)
- KAWAI, S, J ELECTROCHEM SOC 112: 32 (1975). / J ELECTROCHEM SOC (1975)
-
KIVELSON, S, INTRINSIC CONDUCTIVITY OF CONDUCTING POLYMERS, SYNTHETIC METALS 22: 371 (1988).
(
10.1016/0379-6779(88)90108-7
) / SYNTHETIC METALS (1988) -
KLEIN, J.D., ELECTROCHEMICAL FABRICATION OF CADMIUM CHALCOGENIDE MICRODIODE ARRAYS, CHEMISTRY OF MATERIALS 5: 902 (1993).
(
10.1021/cm00031a002
) / CHEMISTRY OF MATERIALS (1993) - KOOPAL, C. G. J., JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS: 1691 (1991). / JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (1991)
-
Kressin, A. M., Chemistry of Materials 3: 1015 (1991).
(
10.1021/cm00018a014
) / Chemistry of Materials (1991) -
Lei, J., Polymers for Advanced Technologies 4: 124 (1993).
(
10.1002/pat.1993.220040211
) / Polymers for Advanced Technologies (1993) -
LEI, J.T., EFFECT OF REAGENT CONCENTRATIONS USED TO SYNTHESIZE POLYPYRROLE ON THE CHEMICAL CHARACTERISTICS AND OPTICAL AND ELECTRONIC-PROPERTIES OF THE RESULTING POLYMER, SYNTHETIC METALS 46: 53 (1992).
(
10.1016/0379-6779(92)90318-D
) / SYNTHETIC METALS (1992) -
LIANG, W.B., TEMPLATE-SYNTHESIZED POLYACETYLENE FIBRILS SHOW ENHANCED SUPERMOLECULAR ORDER, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 112: 9666 (1990).
(
10.1021/ja00182a051
) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1990) - MacDiarmid, A. G., Conjugated Polymers and Related Materials: 73 (1993). / Conjugated Polymers and Related Materials (1993)
-
MARTIN, C.R., TEMPLATE SYNTHESIS OF POLYMERIC AND METAL MICROTUBULES, ADVANCED MATERIALS 3: 457 (1991).
(
10.1002/adma.19910030914
) / ADVANCED MATERIALS (1991) -
Martin, C. R., Accounts of Chemical Research 28: 61 (1995).
(
10.1021/ar00050a002
) / Accounts of Chemical Research (1995) -
MARTIN, C.R., TEMPLATE SYNTHESIS OF ORGANIC MICROTUBULES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 112: 8976 (1990).
(
10.1021/ja00180a050
) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1990) -
MARTIN, C.R., TEMPLATE SYNTHESIS OF ELECTRONICALLY CONDUCTIVE POLYMERS - A NEW ROUTE FOR ACHIEVING HIGHER ELECTRONIC CONDUCTIVITIES, SYNTHETIC METALS 55: 1165 (1993).
(
10.1016/0379-6779(93)90218-L
) / SYNTHETIC METALS (1993) -
MASDEN, J.T., FINITE-SIZE EFFECTS IN THE ELECTRICAL-CONDUCTION OF THIN WIRES, PHYSICAL REVIEW B 36: 4197 (1987).
(
10.1103/PhysRevB.36.4197
) / PHYSICAL REVIEW B (1987) - MENON V.P. unpublished data.
- MENON V.P. unpublished data.
-
MILLER, C.J., MICROPOROUS ALUMINUM-OXIDE FILMS AT ELECTRODES .4. LATERAL CHARGE TRANSPORT IN SELF-ORGANIZED BILAYER ASSEMBLIES, JOURNAL OF PHYSICAL CHEMISTRY 92: 1928 (1988).
(
10.1021/j100318a044
) / JOURNAL OF PHYSICAL CHEMISTRY (1988) -
OLDHAM, K.B., COMPARISON OF VOLTAMMETRIC STEADY-STATES AT HEMISPHERICAL AND DISK MICROELECTRODES, JOURNAL OF ELECTROANALYTICAL CHEMISTRY 256: 11 (1988).
(
10.1016/0022-0728(88)85002-2
) / JOURNAL OF ELECTROANALYTICAL CHEMISTRY (1988) -
OZIN, G.A., NANOCHEMISTRY - SYNTHESIS IN DIMINISHING DIMENSIONS, ADVANCED MATERIALS 4: 612 (1992).
(
10.1002/adma.19920041003
) / ADVANCED MATERIALS (1992) -
PARTHASARATHY, R.V., TEMPLATE-SYNTHESIZED POLYANILINE MICROTUBULES, CHEMISTRY OF MATERIALS 6: 1627 (1994).
(
10.1021/cm00046a011
) / CHEMISTRY OF MATERIALS (1994) -
PARTHASARATHY, R.V., SYNTHESIS OF POLYMERIC MICROCAPSULE ARRAYS AND THEIR USE FOR ENZYME IMMOBILIZATION, NATURE 369: 298 (1994).
(
10.1038/369298a0
) / NATURE (1994) -
PATEL, R.D., STRUCTURED SELECTIVE COATINGS, THIN SOLID FILMS 115: 169 (1984).
(
10.1016/0040-6090(84)90178-0
) / THIN SOLID FILMS (1984) -
PENNER, R.M., PREPARATION AND ELECTROCHEMICAL CHARACTERIZATION OF ULTRAMICROELECTRODE ENSEMBLES, ANALYTICAL CHEMISTRY 59: 2625 (1987).
(
10.1021/ac00148a020
) / ANALYTICAL CHEMISTRY (1987) -
PENNER, R.M., CONTROLLING THE MORPHOLOGY OF ELECTRONICALLY CONDUCTIVE POLYMERS, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 133: 2206 (1986).
(
10.1149/1.2108371
) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1986) 10.1126/science.247.4949.1410
-
POSSIN, G.E., A METHOD FOR FORMING VERY SMALL DIAMETER WIRES, REVIEW OF SCIENTIFIC INSTRUMENTS 41: 772 (1970).
(
10.1063/1.1684640
) / REVIEW OF SCIENTIFIC INSTRUMENTS (1970) -
PRESTON, C.K., OPTICAL CHARACTERIZATION OF ANODIC ALUMINUM-OXIDE FILMS CONTAINING ELECTROCHEMICALLY DEPOSITED METAL PARTICLES .1. GOLD IN PHOSPHORIC-ACID ANODIC ALUMINUM-OXIDE FILMS, JOURNAL OF PHYSICAL CHEMISTRY 97: 8495 (1993).
(
10.1021/j100134a019
) / JOURNAL OF PHYSICAL CHEMISTRY (1993) - Skotheim T. A. Handbook of Conducting Polymers (1986).
10.1126/science.254.5036.1326
10.1126/science.258.5083.783
-
UOSAKI, K, PREPARATIVE METHOD FOR FABRICATING A MICROELECTRODE ENSEMBLE - ELECTROCHEMICAL RESPONSE OF MICROPOROUS ALUMINUM ANODIC OXIDE FILM MODIFIED GOLD ELECTRODE, ANALYTICAL CHEMISTRY 62: 652 (1990).
(
10.1021/ac00205a023
) / ANALYTICAL CHEMISTRY (1990) - van de Hulst H. C. Light Scattering by Small Particles (1981).
-
VANDYKE, L.S., LANGMUIR 6: 1123 (1990).
(
10.1021/la00096a017
) / LANGMUIR (1990) 10.1126/science.261.5126.1316
-
WITTMANN, J.C., HIGHLY ORIENTED THIN-FILMS OF POLY(TETRAFLUOROETHYLENE) AS A SUBSTRATE FOR ORIENTED GROWTH OF MATERIALS, NATURE 352: 414 (1991).
(
10.1038/352414a0
) / NATURE (1991) 10.1126/science.264.5166.1757
10.1126/science.263.5154.1744
Dates
Type | When |
---|---|
Created | 18 years, 10 months ago (Oct. 5, 2006, 8:01 p.m.) |
Deposited | 1 year, 7 months ago (Jan. 12, 2024, 5:55 p.m.) |
Indexed | 3 days, 16 hours ago (Aug. 23, 2025, 9:51 p.m.) |
Issued | 30 years, 8 months ago (Dec. 23, 1994) |
Published | 30 years, 8 months ago (Dec. 23, 1994) |
Published Print | 30 years, 8 months ago (Dec. 23, 1994) |
@article{Martin_1994, title={Nanomaterials: A Membrane-Based Synthetic Approach}, volume={266}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.266.5193.1961}, DOI={10.1126/science.266.5193.1961}, number={5193}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Martin, Charles R.}, year={1994}, month=dec, pages={1961–1966} }