DOI: 10.1126/science.261.5126.1299. Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures

Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures

10.1126/science.261.5126.1299

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

A model is presented to explain the formation and morphologies of surfactant-silicate mesostructures. Three processes are identified: multidentate binding of silicate oligomers to the cationic surfactant, preferential silicate polymerization in the interface region, and charge density matching between the surfactant and the silicate. The model explains present experimental data, including the transformation between lamellar and hexagonal mesophases, and provides a guide for predicting conditions that favor the formation of lamellar, hexagonal, or cubic mesostructures. Model Q 230 proposed by Mariani and his co-workers satisfactorily fits the x-ray data collected on the cubic mesostructure material. This model suggests that the silicate polymer forms a unique infinite silicate sheet sitting on the gyroid minimal surface and separating the surfactant molecules into two disconnected volumes.

Bibliography

Monnier, A., SchÃ¼th, F., Huo, Q., Kumar, D., Margolese, D., Maxwell, R. S., Stucky, G. D., Krishnamurty, M., Petroff, P., Firouzi, A., Janicke, M., & Chmelka, B. F. (1993). Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures. Science, 261(5126), 1299â1303.

Authors 12

A. Monnier (first)
F. Schüth (additional)
Q. Huo (additional)
D. Kumar (additional)
D. Margolese (additional)
R. S. Maxwell (additional)
G. D. Stucky (additional)
M. Krishnamurty (additional)
P. Petroff (additional)
A. Firouzi (additional)
M. Janicke (additional)
B. F. Chmelka (additional)

References 17 Referenced 1,395

AUVRAY, X, JOURNAL OF PHYSICAL CHEMISTRY 93: 7458 (1989). (10.1021/j100358a040) / JOURNAL OF PHYSICAL CHEMISTRY (1989)
BECK, J.S., A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 114: 10834 (1992). (10.1021/ja00053a020) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1992)
Brinker, C. J., Sol-Gel Science: 100 (1990). / Sol-Gel Science (1990)
CHARVOLIN, J, PERIODIC-SYSTEMS OF FRUSTRATED FLUID FILMS AND BICONTINUOUS CUBIC STRUCTURES IN LIQUID-CRYSTALS, JOURNAL DE PHYSIQUE 48: 1559 (1987). (10.1051/jphys:019870048090155900) / JOURNAL DE PHYSIQUE (1987)
HAGAKAWA, K, SURFACTANT SCIENCE 37: 189 (1991). / SURFACTANT SCIENCE (1991)
HARRIS, R.K., NMR-STUDIES OF THE CHEMICAL-STRUCTURE OF SILICATES IN SOLUTION, ACS SYMPOSIUM SERIES 194: 79 (1982). (10.1021/bk-1982-0194.ch006) / ACS SYMPOSIUM SERIES (1982)
Iler, R. K., The Chemistry of Silica: 182 (1979). / The Chemistry of Silica (1979)
Israelachvili, J., Surfactants in Solution 4: 3 (1987). / Surfactants in Solution (1987)
KNIGHT, C. T. G., JOURNAL OF MAGNETIC RESONANCE 78: 31 (1988). / JOURNAL OF MAGNETIC RESONANCE (1988)
10.1038/359710a0
LAUGHLIN, R.G., SURFACTANT SCIENCE 37: 1 (1991). / SURFACTANT SCIENCE (1991)
MARIANI, P, CUBIC PHASES OF LIPID-CONTAINING SYSTEMS - STRUCTURE-ANALYSIS AND BIOLOGICAL IMPLICATIONS, JOURNAL OF MOLECULAR BIOLOGY 204: 165 (1988). (10.1016/0022-2836(88)90607-9) / JOURNAL OF MOLECULAR BIOLOGY (1988)
MCCORMICK, A. V., CATALYSIS REVIEWS. SCIENCE AND ENGINEERING 31: 97 (1989). (10.1080/01614948909351349) / CATALYSIS REVIEWS. SCIENCE AND ENGINEERING (1989)
MONNIER A unpublished data.
WEISS, A, REPLICATION AND EVOLUTION IN INORGANIC SYSTEMS, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 20: 850 (1981). (10.1002/anie.198108501) / ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH (1981)
WEISS, A, CLAYS CLAY MINERALS 10: 191 (1963). / CLAYS CLAY MINERALS (1963)
YANAGISAWA, T, THE PREPARATION OF ALKYLTRIMETHYLAMMONIUM-KANEMITE COMPLEXES AND THEIR CONVERSION TO MICROPOROUS MATERIALS, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 63: 988 (1990). (10.1246/bcsj.63.988) / BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (1990)

Dates

Type	When
Created	18 years, 10 months ago (Oct. 5, 2006, 7:05 p.m.)
Deposited	1 year, 7 months ago (Jan. 12, 2024, 5:24 p.m.)
Indexed	5 hours, 30 minutes ago (Aug. 23, 2025, 1:02 a.m.)
Issued	31 years, 11 months ago (Sept. 3, 1993)
Published	31 years, 11 months ago (Sept. 3, 1993)
Published Print	31 years, 11 months ago (Sept. 3, 1993)

Funders 0

None

BibTeX

@article{Monnier_1993, title={Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures}, volume={261}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.261.5126.1299}, DOI={10.1126/science.261.5126.1299}, number={5126}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Monnier, A. and Schüth, F. and Huo, Q. and Kumar, D. and Margolese, D. and Maxwell, R. S. and Stucky, G. D. and Krishnamurty, M. and Petroff, P. and Firouzi, A. and Janicke, M. and Chmelka, B. F.}, year={1993}, month=sep, pages={1299–1303} }

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