Abstract
Compressibilities of five silicate spinels, including γ-Mg 2 SiO 4 , γ-Fe 2 SiO 4 , Ni 2 SiO 4 , and two ferromagnesian compositions, were determined on crystals positioned in the same high-pressure mount. Subjection of all crystals simultaneously to the same pressure revealed differences in compressibility that resulted from compositional differences. Ferromagnesian silicate spinels showed an anomalous 13 percent increase in bulk modulus with increasing iron content, from Mg 2 SiO 4 (184 gigapascals) to Fe 2 SiO 4 (207 gigapascals). This result suggests that ferrous iron and magnesium, which behave similarly under crustal conditions, are chemically more distinct at high pressures characteristic of the transition zone and lower mantle.
References
49
Referenced
55
-
AIKAWA, N, TEMPERATURE-DEPENDENCE OF INTERSITE DISTRIBUTION OF MG AND FE IN OLIVINE AND THE ASSOCIATED CHANGE OF LATTICE-PARAMETERS, PHYSICS AND CHEMISTRY OF MINERALS 12: 1 (1985).
(
10.1007/BF00348738
) / PHYSICS AND CHEMISTRY OF MINERALS (1985) -
ANDERSON, D. L., JOURNAL OF GEOPHYSICAL RESEARCH 75: 3494 (1970).
(
10.1029/JB075i017p03494
) / JOURNAL OF GEOPHYSICAL RESEARCH (1970) -
ANDERSON, D.L., TRANSITION REGION OF THE EARTHS UPPER MANTLE, NATURE 320: 321 (1986).
(
10.1038/320321a0
) / NATURE (1986) -
ANDERSON, O. L., JOURNAL OF GEOPHYSICAL RESEARCH 70: 3951 (1965).
(
10.1029/JZ070i016p03951
) / JOURNAL OF GEOPHYSICAL RESEARCH (1965) -
ANGEL, R.J., COMPARATIVE COMPRESSIBILITY OF END-MEMBER FELDSPARS, PHYSICS AND CHEMISTRY OF MINERALS 15: 313 (1988).
(
10.1007/BF00311034
) / PHYSICS AND CHEMISTRY OF MINERALS (1988) - BASS, J.D., EOS 70: 474 (1989). / EOS (1989)
-
BASS, J. D., JOURNAL OF GEOPHYSICAL RESEARCH 89: 4359 (1984).
(
10.1029/JB089iB06p04359
) / JOURNAL OF GEOPHYSICAL RESEARCH (1984) -
BASS, J. D., JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH AND PLANETS 94: 7621 (1989).
(
10.1029/JB094iB06p07621
) / JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH AND PLANETS (1989) -
BASS, J.D., ELASTICITY OF THE OLIVINE AND SPINEL POLYMORPHS OF NI2SIO4, PHYSICS AND CHEMISTRY OF MINERALS 10: 261 (1984).
(
10.1007/BF00311951
) / PHYSICS AND CHEMISTRY OF MINERALS (1984) -
BRIDGMAN, P.W., The compressibility of thirty metals as a function of pressure and temperature, PROCEEDINGS OF THE AMERICAN ACADEMY OF ARTS AND SCIENCES 58: 165 (1923).
(
10.2307/20025987
) / PROCEEDINGS OF THE AMERICAN ACADEMY OF ARTS AND SCIENCES (1923) - BROWN, G. E., Olivines and Silicate Spinels, REVIEWS IN MINERALOGY 5: 275 (1982). / REVIEWS IN MINERALOGY / Olivines and Silicate Spinels (1982)
-
BUKOWINSKI, M. S. T., JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH AND PLANETS 95: 12583 (1990).
(
10.1029/JB095iB08p12583
) / JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH AND PLANETS (1990) -
CHANG, Z. P., JOURNAL OF GEOPHYSICAL RESEARCH 78: 2418 (1973).
(
10.1029/JB078i014p02418
) / JOURNAL OF GEOPHYSICAL RESEARCH (1973) - Hamilton W. C. International Tables for X-Ray Crystallography 4 (1974).
-
Fei, Y., Journal of Geophysical Research 96: 2157 (1991).
(
10.1029/90JB02164
) / Journal of Geophysical Research (1991) - FINGER, L.W., CRYSTAL-STRUCTURES AND ELECTRON-DENSITIES OF NICKEL AND IRON SILICATE SPINELS AT ELEVATED-TEMPERATURE OR PRESSURE, AMERICAN MINERALOGIST 64: 1002 (1979). / AMERICAN MINERALOGIST (1979)
- Finger, L. W., Physics and Chemistry of Minerals 19: 361 (1993). / Physics and Chemistry of Minerals (1993)
-
GRAHAM, E. K., JOURNAL OF GEOPHYSICAL RESEARCH 74: 5949 (1969).
(
10.1029/JB074i025p05949
) / JOURNAL OF GEOPHYSICAL RESEARCH (1969) - HAZEN, R.M., CRYSTAL-CHEMISTRY OF FE-BEARING ANHYDROUS PHASE-B - IMPLICATIONS FOR TRANSITION ZONE MINERALOGY, AMERICAN MINERALOGIST 77: 217 (1992). / AMERICAN MINERALOGIST (1992)
- Hazen R. M. Comparative Crystal Chemistry (1982).
-
HAZEN, R. M., JOURNAL OF GEOPHYSICAL RESEARCH 84: 6723 (1979).
(
10.1029/JB084iB12p06723
) / JOURNAL OF GEOPHYSICAL RESEARCH (1979) - HAZEN, R.M., EFFECTS OF FE/MG ON THE COMPRESSIBILITY OF SYNTHETIC WADSLEYITE - BETA-(MG1-XFEX)2SIO4(X LESS-THAN-OR-EQUAL-TO 0.25), PHYSICS AND CHEMISTRY OF MINERALS 17: 416 (1990). / PHYSICS AND CHEMISTRY OF MINERALS (1990)
-
HAZEN, R.M., WUSTITE (FE1-XO) - A REVIEW OF ITS DEFECT STRUCTURE AND PHYSICAL-PROPERTIES, REVIEWS OF GEOPHYSICS 22: 37 (1984).
(
10.1029/RG022i001p00037
) / REVIEWS OF GEOPHYSICS (1984) - HAZEN, R. M., CARNEGIE INSTITUTE OF WASHININGTON YEARBOOK 80: 277 (1981). / CARNEGIE INSTITUTE OF WASHININGTON YEARBOOK (1981)
- ITA, J, EOS 72: 281 (1991). / EOS (1991)
- JEANLOZ, R, FINITE-STRAIN ANALYSIS OF RELATIVE COMPRESSIBILITIES - APPLICATION TO THE HIGH-PRESSURE WADSLEYITE PHASE AS AN ILLUSTRATION, AMERICAN MINERALOGIST 76: 1765 (1991). / AMERICAN MINERALOGIST (1991)
-
JEANLOZ, R, PHASE-TRANSITIONS AND MANTLE DISCONTINUITIES, REVIEWS OF GEOPHYSICS 21: 51 (1983).
(
10.1029/RG021i001p00051
) / REVIEWS OF GEOPHYSICS (1983) - KAMB, B, STRUCTURAL BASIS OF OLIVINE-SPINEL STABILITY RELATION, AMERICAN MINERALOGIST 53: 1439 (1968). / AMERICAN MINERALOGIST (1968)
-
KANDELIN, J, JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH AND PLANETS 93: 1063 (1988).
(
10.1029/JB093iB02p01063
) / JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH AND PLANETS (1988) -
KING, H.E., DIFFRACTED BEAM CRYSTAL CENTERING AND ITS APPLICATION TO HIGH-PRESSURE CRYSTALLOGRAPHY, JOURNAL OF APPLIED CRYSTALLOGRAPHY 12: 374 (1979).
(
10.1107/S0021889879012723
) / JOURNAL OF APPLIED CRYSTALLOGRAPHY (1979) -
KNITTLE, E, THERMAL-EXPANSION OF SILICATE PEROVSKITE AND STRATIFICATION OF THE EARTHS MANTLE, NATURE 319: 214 (1986).
(
10.1038/319214a0
) / NATURE (1986) -
KUMAZAWA, M, JOURNAL OF GEOPHYSICAL RESEARCH 74: 5961 (1969).
(
10.1029/JB074i025p05961
) / JOURNAL OF GEOPHYSICAL RESEARCH (1969) -
LEVIEN, L, ELASTICITY OF DIOPSIDE, PHYSICS AND CHEMISTRY OF MINERALS 4: 105 (1979).
(
10.1007/BF00307555
) / PHYSICS AND CHEMISTRY OF MINERALS (1979) - LINDSLEY, D. H., The Crystal Chemistry and Structure of Oxide Minerals as Exemplified by the Fe-Ti Oxides, REVIEWS IN MINERALOGY 3: L-1 (1976). / REVIEWS IN MINERALOGY / The Crystal Chemistry and Structure of Oxide Minerals as Exemplified by the Fe-Ti Oxides (1976)
- MCCORMICK, T.C., COMPRESSIBILITY OF OMPHACITE TO 60 KBAR - ROLE OF VACANCIES, AMERICAN MINERALOGIST 74: 1287 (1989). / AMERICAN MINERALOGIST (1989)
- MENG R.L. COMMUNICATION.
-
MERRILL, L, MINIATURE DIAMOND ANVIL PRESSURE CELL FOR SINGLE-CRYSTAL X-RAY-DIFFRACTION STUDIES, REVIEW OF SCIENTIFIC INSTRUMENTS 45: 290 (1974).
(
10.1063/1.1686607
) / REVIEW OF SCIENTIFIC INSTRUMENTS (1974) -
MOTOYAMA, T, MINERAL J 14: 338 (1989).
(
10.2465/minerj.14.338
) / MINERAL J (1989) - ROSS, C.R., CRYSTAL-STRUCTURE REFINEMENT OF A SPINELLOID IN THE SYSTEM FE3O4-FE2SIO4, AMERICAN MINERALOGIST 77: 507 (1992). / AMERICAN MINERALOGIST (1992)
- ROSS, N.L., HIGH-PRESSURE STRUCTURAL STUDY OF DOLOMITE AND ANKERITE, AMERICAN MINERALOGIST 77: 412 (1992). / AMERICAN MINERALOGIST (1992)
-
SHANNON, R.D., REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES, ACTA CRYSTALLOGRAPHICA SECTION A 32: 751 (1976).
(
10.1107/S0567739476001551
) / ACTA CRYSTALLOGRAPHICA SECTION A (1976) - Smyth J. R. Crystal Structures and Cation Sites of the Rock-Forming Minerals (1988).
- STANEK, J, LOCAL STATES OF FE-2+ AND MG-2+ IN MAGNESIUM-RICH OLIVINES, AMERICAN MINERALOGIST 71: 127 (1986). / AMERICAN MINERALOGIST (1986)
10.1126/science.257.5073.1099
-
WANG, H, JOURNAL OF GEOPHYSICAL RESEARCH 77: 4379 (1972).
(
10.1029/JB077i023p04379
) / JOURNAL OF GEOPHYSICAL RESEARCH (1972) -
WANG, Y, PHASE-TRANSITION AND THERMAL-EXPANSION OF MGSIO3 PEROVSKITE, SCIENCE 251: 410 (1991).
(
10.1126/science.251.4992.410
) / SCIENCE (1991) -
WEIDNER, D. J., JOURNAL OF GEOPHYSICAL RESEARCH 89: 7852 (1984).
(
10.1029/JB089iB09p07852
) / JOURNAL OF GEOPHYSICAL RESEARCH (1984) -
WEIDNER, D.J., ELASTICITY OF ORTHOENSTATITE, PHYSICS OF THE EARTH AND PLANETARY INTERIORS 17: P7 (1978).
(
10.1016/0031-9201(78)90043-2
) / PHYSICS OF THE EARTH AND PLANETARY INTERIORS (1978) -
YONEDA, A, PRESSURE DERIVATIVES OF ELASTIC-CONSTANTS OF SINGLE-CRYSTAL MGO AND MGAL2O4, JOURNAL OF PHYSICS OF THE EARTH 38: 19 (1990).
(
10.4294/jpe1952.38.19
) / JOURNAL OF PHYSICS OF THE EARTH (1990)
Dates
Type | When |
---|---|
Created | 18 years, 10 months ago (Oct. 5, 2006, 7:05 p.m.) |
Deposited | 1 year, 7 months ago (Jan. 12, 2024, 5:07 p.m.) |
Indexed | 1 year ago (Aug. 20, 2024, 3:10 a.m.) |
Issued | 32 years, 7 months ago (Jan. 8, 1993) |
Published | 32 years, 7 months ago (Jan. 8, 1993) |
Published Print | 32 years, 7 months ago (Jan. 8, 1993) |
@article{Hazen_1993, title={Comparative Compressibilities of Silicate Spinels: Anomalous Behavior of (Mg,Fe) 2 SiO 4}, volume={259}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.259.5092.206}, DOI={10.1126/science.259.5092.206}, number={5092}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Hazen, Robert M.}, year={1993}, month=jan, pages={206–209} }