DOI: 10.1126/science.255.5049.1230. Correlation Between Surface Free Energy and Surface Constitution

Correlation Between Surface Free Energy and Surface Constitution

10.1126/science.255.5049.1230

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

Self-assembled monolayers (SAMs) of alkylsiloxanes on elastomeric PDMS (polydimethylsiloxane) were used as model systems to study interactions between surfaces. Surface free energies (γsv) of these chemically modified surfaces were estimated by measuring the deformations that resulted from the contact between small semispherical lenses and flat sheets of the elastomer under controlled loads. The measured surface free energies correlated with the surface chemical compositions of the SAMs and were commensurate with the values estimated from the measurements of contact angles. This study provides direct experimental evidence for the validity of estimates of the surface free energies of low-energy solids obtained from contact angles.

Bibliography

Chaudhury, M. K., & Whitesides, G. M. (1992). Correlation Between Surface Free Energy and Surface Constitution. Science, 255(5049), 1230â1232.

Authors 2

Manoj K. Chaudhury (first)
George M. Whitesides (additional)

References 30 Referenced 282

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CHAUDHURY, M.K., DIRECT MEASUREMENT OF INTERFACIAL INTERACTIONS BETWEEN SEMISPHERICAL LENSES AND FLAT SHEETS OF POLY(DIMETHYLSILOXANE) AND THEIR CHEMICAL DERIVATIVES, LANGMUIR 7: 1013 (1991). (10.1021/la00053a033) / LANGMUIR (1991)
CHAUDHURY M.K. unpublished data.
DERJAGUIN, B.V., EFFECT OF CONTACT DEFORMATIONS ON ADHESION OF PARTICLES, JOURNAL OF COLLOID AND INTERFACE SCIENCE 53: 314 (1975). (10.1016/0021-9797(75)90018-1) / JOURNAL OF COLLOID AND INTERFACE SCIENCE (1975)
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FAKES, D.W., SURFACE MODIFICATION OF A CONTACT-LENS COPOLYMER BY PLASMA-DISCHARGE TREATMENTS, SURFACE AND INTERFACE ANALYSIS 10: 416 (1987). (10.1002/sia.740100807) / SURFACE AND INTERFACE ANALYSIS (1987)
FAKES, D.W., THE SURFACE-ANALYSIS OF A PLASMA MODIFIED CONTACT-LENS SURFACE BY SSIMS, SURFACE AND INTERFACE ANALYSIS 13: 233 (1988). (10.1002/sia.740130411) / SURFACE AND INTERFACE ANALYSIS (1988)
10.1126/science.253.5021.776
FOWKES, F. M., Dispersion Force Contributions to Surface and Interfacial Tensions, Contact Angles, and Heats of Immersion, ADVANCES IN CHEMISTRY 43: 99 (1964). (10.1021/ba-1964-0043.ch006) / ADVANCES IN CHEMISTRY / Dispersion Force Contributions to Surface and Interfacial Tensions, Contact Angles, and Heats of Immersion (1964)
FOWKES, F.M., ATTRACTIVE FORCES AT INTERFACES, INDUSTRIAL AND ENGINEERING CHEMISTRY 56: 40 (1964). / INDUSTRIAL AND ENGINEERING CHEMISTRY (1964)
GIRIFALCO, L.A., A THEORY FOR THE ESTIMATION OF SURFACE AND INTERFACIAL ENERGIES .1. DERIVATION AND APPLICATION TO INTERFACIAL TENSION, JOURNAL OF PHYSICAL CHEMISTRY 61: 904 (1957). (10.1021/j150553a013) / JOURNAL OF PHYSICAL CHEMISTRY (1957)
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Hilderbrand J. H. Solubility of Non-Electrolytes 3 (1950).
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JOHNSON, K.L., SURFACE ENERGY AND CONTACT OF ELASTIC SOLIDS, PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES 324: 301 (1971). / PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES (1971)
KENDALL, K, ADHESION PARADOX, JOURNAL OF ADHESION 5: 77 (1973). (10.1080/00218467308078440) / JOURNAL OF ADHESION (1973)
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LEE, A.E., ROLE OF ELASTIC DEFORMATION IN ADHESION OF SOLIDS, JOURNAL OF COLLOID AND INTERFACE SCIENCE 64: 577 (1978). (10.1016/0021-9797(78)90400-9) / JOURNAL OF COLLOID AND INTERFACE SCIENCE (1978)
MAOZ, R, ON THE FORMATION AND STRUCTURE OF SELF-ASSEMBLING MONOLAYERS .1. A COMPARATIVE ATR-WETABILITY STUDY OF LANGMUIR-BLODGETT AND ADSORBED FILMS ON FLAT SUBSTRATES AND GLASS MICROBEADS, JOURNAL OF COLLOID AND INTERFACE SCIENCE 100: 465 (1984). (10.1016/0021-9797(84)90452-1) / JOURNAL OF COLLOID AND INTERFACE SCIENCE (1984)
Maugis, D., Adhesion and Adsorption of Polymers: Polymer Science and Technology 12: 203 (1980). / Adhesion and Adsorption of Polymers: Polymer Science and Technology (1980)
MORRA, M, ON THE AGING OF OXYGEN PLASMA-TREATED POLYDIMETHYLSILOXANE SURFACES, JOURNAL OF COLLOID AND INTERFACE SCIENCE 137: 11 (1990). (10.1016/0021-9797(90)90038-P) / JOURNAL OF COLLOID AND INTERFACE SCIENCE (1990)
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TILLMAN, N, INCORPORATION OF PHENOXY GROUPS IN SELF-ASSEMBLED MONOLAYERS OF TRICHLOROSILANE DERIVATIVES - EFFECTS ON FILM THICKNESS, WETTABILITY, AND MOLECULAR-ORIENTATION, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 110: 6136 (1988). (10.1021/ja00226a031) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1988)
WASSERMAN, S.R., STRUCTURE AND REACTIVITY OF ALKYLSILOXANE MONOLAYERS FORMED BY REACTION OF ALKYLTRICHLOROSILANES ON SILICON SUBSTRATES, LANGMUIR 5: 1074 (1989). (10.1021/la00088a035) / LANGMUIR (1989)
Young, T., Miscellaneous Works: 1 (1855). / Miscellaneous Works (1855)
ZISMAN, W.A., ADV CHEM SER 43: 1 (1964). (10.1021/ba-1964-0043.ch001) / ADV CHEM SER (1964)

Dates

Type	When
Created	18 years, 10 months ago (Oct. 5, 2006, 7:03 p.m.)
Deposited	1 year, 7 months ago (Jan. 12, 2024, 4:49 p.m.)
Indexed	4 weeks, 1 day ago (July 25, 2025, 6:40 a.m.)
Issued	33 years, 5 months ago (March 6, 1992)
Published	33 years, 5 months ago (March 6, 1992)
Published Print	33 years, 5 months ago (March 6, 1992)

Funders 0

None

BibTeX

@article{Chaudhury_1992, title={Correlation Between Surface Free Energy and Surface Constitution}, volume={255}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.255.5049.1230}, DOI={10.1126/science.255.5049.1230}, number={5049}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Chaudhury, Manoj K. and Whitesides, George M.}, year={1992}, month=mar, pages={1230–1232} }

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