DOI: 10.1126/science.255.5042.315. Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex

Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex

10.1126/science.255.5042.315

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

The gas-phase irradiation of CpRh(CO) 2 (Cp = η 5 -C 5 H 5 ) was examined in order to study the rates of reaction of the 16-electron intermediates presumed to be involved in the C-H oxidative addition of alkanes. "Naked" (unsolvated) CpRh(CO) was detected, and direct measurements of the rates of reaction of this very short-lived complex with alkane C-H bonds were made. Activation of C-H bonds occurs on almost every collision for alkanes of moderate size, and intermediates in which the alkanes are bound to the metal centers, without their C-H bonds being fully broken, are implicated as intermediates in the overall reaction.

Bibliography

Wasserman, E. P., Moore, C. B., & Bergman, R. G. (1992). Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex. Science, 255(5042), 315â318.

Authors 3

Eric P. Wasserman (first)
C. Bradley Moore (additional)
Robert G. Bergman (additional)

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Dates

Type	When
Created	18 years, 10 months ago (Oct. 5, 2006, 7:03 p.m.)
Deposited	1 year, 7 months ago (Jan. 12, 2024, 5:50 p.m.)
Indexed	1 year, 3 months ago (June 3, 2024, 7:13 p.m.)
Issued	33 years, 7 months ago (Jan. 17, 1992)
Published	33 years, 7 months ago (Jan. 17, 1992)
Published Print	33 years, 7 months ago (Jan. 17, 1992)

Funders 0

None

BibTeX

@article{Wasserman_1992, title={Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex}, volume={255}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.255.5042.315}, DOI={10.1126/science.255.5042.315}, number={5042}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Wasserman, Eric P. and Moore, C. Bradley and Bergman, Robert G.}, year={1992}, month=jan, pages={315–318} }

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