DOI: 10.1126/science.252.5012.1532. Crystallinity of the Double Layer of Cadmium Arachidate Films at the Water Surface

Crystallinity of the Double Layer of Cadmium Arachidate Films at the Water Surface

10.1126/science.252.5012.1532

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

A crystalline counterionic layer at the interface between an electrolyte solution and a charged layer of insoluble amphiphilic molecules was observed with grazing incidence synchrotron x-ray diffraction. Uncompressed arachidic films spread over 10 -3 molar cadmium chloride solution (pH 8.8) spontaneously form crystalline clusters with coherence lengths of ∼1000 angstroms at 9°C. Ten distinct diffraction peaks were observed, seven of which were attributed to scattering only from a crystalline Cd 2+ layer and the other three to scattering primarily from the arachidate layer. The reflections from the Cd 2+ layer were indexed according to a 2 × 3 supercell of the arachidate lattice with three Cd 2+ ions per cadmium unit cell.

Bibliography

Leveiller, F., Jacquemain, D., Lahav, M., Leiserowitz, L., Deutsch, M., Kjaer, K., & Als-Nielsen, J. (1991). Crystallinity of the Double Layer of Cadmium Arachidate Films at the Water Surface. Science, 252(5012), 1532â1536.

Authors 7

F. Leveiller (first)
D. Jacquemain (additional)
M. Lahav (additional)
L. Leiserowitz (additional)
M. Deutsch (additional)
K. Kjaer (additional)
J. Als-Nielsen (additional)

References 28 Referenced 104

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10.1126/science.242.4883.1286

Dates

Type	When
Created	18 years, 10 months ago (Oct. 5, 2006, 6:10 p.m.)
Deposited	1 year, 7 months ago (Jan. 12, 2024, 9:39 a.m.)
Indexed	2 months, 1 week ago (June 24, 2025, 7:29 a.m.)
Issued	34 years, 2 months ago (June 14, 1991)
Published	34 years, 2 months ago (June 14, 1991)
Published Print	34 years, 2 months ago (June 14, 1991)

Funders 0

None

BibTeX

@article{Leveiller_1991, title={Crystallinity of the Double Layer of Cadmium Arachidate Films at the Water Surface}, volume={252}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.252.5012.1532}, DOI={10.1126/science.252.5012.1532}, number={5012}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Leveiller, F. and Jacquemain, D. and Lahav, M. and Leiserowitz, L. and Deutsch, M. and Kjaer, K. and Als-Nielsen, J.}, year={1991}, month=jun, pages={1532–1536} }

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