DOI: 10.1126/science.246.4935.1260. Preparation of Organometallic Compounds from Highly Reactive Metal Powders

Preparation of Organometallic Compounds from Highly Reactive Metal Powders

10.1126/science.246.4935.1260

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

The formation of novel organometallic compounds by the reaction of organic substrates with finely divided metal powders represents a powerful tool for the synthetic chemist. The direct reaction with a zerovalent metal is the only viable method of synthesis for many of these compounds. Accordingly, chemists have been actively developing new methods for increasing the reactivity of metal powders toward organic substrates. Three principal approaches have been developed in recent years: the metal vaporization method, sonochemistry, and the preparation of finely divided metal powders by the reduction of metal salts. A number of new methods of synthesis have resulted from these studies.

Bibliography

Rieke, R. D. (1989). Preparation of Organometallic Compounds from Highly Reactive Metal Powders. Science, 246(4935), 1260â1264.

Authors 1

Reuben D. Rieke (first)

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Dates

Type	When
Created	18 years, 10 months ago (Oct. 5, 2006, 5:21 p.m.)
Deposited	1 year, 7 months ago (Jan. 12, 2024, 9:52 a.m.)
Indexed	4 days, 7 hours ago (Aug. 29, 2025, 6:34 a.m.)
Issued	35 years, 8 months ago (Dec. 8, 1989)
Published	35 years, 8 months ago (Dec. 8, 1989)
Published Print	35 years, 8 months ago (Dec. 8, 1989)

Funders 0

None

BibTeX

@article{Rieke_1989, title={Preparation of Organometallic Compounds from Highly Reactive Metal Powders}, volume={246}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.246.4935.1260}, DOI={10.1126/science.246.4935.1260}, number={4935}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Rieke, Reuben D.}, year={1989}, month=dec, pages={1260–1264} }

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