DOI: 10.1126/science.241.4863.332. Design of a Monomeric Arsinogallane and Chemical Conversion to Gallium Arsenide

Design of a Monomeric Arsinogallane and Chemical Conversion to Gallium Arsenide

10.1126/science.241.4863.332

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

A monomeric arsinogallane containing a covalent gallium-arsenic bond has been prepared, and its molecular structure has been determined by x-ray crystallography. The compound reacted with tert -butanol at ambient temperature to yield the III-V semiconductor gallium arsenide as a finely divided amorphous solid. During the initial stages of the reaction small clusters of gallium arsenide were apparently present in solution. The band gaps of these particles, as observed by their absorption spectra, were larger than that of the bulk material. This work is a step toward the development of new molecular precursors for technologically important materials and the study of quantum size effects in small semiconductor particles.

Bibliography

Byrne, E. K., Parkanyi, L., & Theopold, K. H. (1988). Design of a Monomeric Arsinogallane and Chemical Conversion to Gallium Arsenide. Science, 241(4863), 332â334.

Authors 3

Erin K. Byrne (first)
Laszlo Parkanyi (additional)
Klaus H. Theopold (additional)

References 23 Referenced 77

Powder Ditraction File Joint Committee on Powder Diffraction Standards-International Centre for Diffraction Data File 32389 (1986).
ARIF, A.M., MONONUCLEAR AND DINUCLEAR PHOSPHIDO AND ARSENIDO COMPLEXES OF GALLIUM - GA(EBU-TERT-2)3, GA[PH(2,4,6-BU-TERT-3C6H2)]3 AND [GA(MU-EBU-TERT-2)R2]2, (E = P, AS, R = ME, BUN), JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS: 1543 (1986). / JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (1986)
BEACHLEY, O.T., SYNTHESES, CHARACTERIZATIONS, AND CRYSTAL AND MOLECULAR STRUCTURES OF (PENTAMETHYLCYCLOPENTADIENYL)GALLIUM CHLORINE COMPOUNDS GA(C5ME5)2CL AND GA(C5ME5)CL2, ORGANOMETALLICS 4: 1675 (1985). (10.1021/om00128a033) / ORGANOMETALLICS (1985)
BECKER, G, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 113: 462 (1980). / ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (1980)
BRUS, L, ELECTRONIC WAVE-FUNCTIONS IN SEMICONDUCTOR CLUSTERS - EXPERIMENT AND THEORY, JOURNAL OF PHYSICAL CHEMISTRY 90: 2555 (1986). (10.1021/j100403a003) / JOURNAL OF PHYSICAL CHEMISTRY (1986)
FOJTIK, A, PHOTO-CHEMISTRY OF COLLOIDAL METAL SULFIDES .8. PHOTO-PHYSICS OF EXTREMELY SMALL CDS PARTICLES - Q-STATE CDS AND MAGIC AGGLOMERATION NUMBERS, BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS 88: 969 (1984). (10.1002/bbpc.19840881010) / BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS (1984)
GLASS, A.M., OPTICAL-MATERIALS, SCIENCE 235: 1003 (1987). (10.1126/science.235.4792.1003) / SCIENCE (1987)
LEYS, M.R., CHEMTRONICS 2: 155 (1987). / CHEMTRONICS (1987)
MILLS, G, PHOTOCHEMISTRY AND SPECTROSCOPY OF COLLOIDAL AS2S3, JOURNAL OF PHYSICAL CHEMISTRY 92: 822 (1988). (10.1021/j100314a046) / JOURNAL OF PHYSICAL CHEMISTRY (1988)
10.1126/science.235.4792.1023
Pauling, L., The Nature of the Chemical Bond: 246 (1960). / The Nature of the Chemical Bond (1960)
PITT, C.G., INORG CHEM 25: 2484 (1986). (10.1021/ic00235a002) / INORG CHEM (1986)
PURDY, A.P., REACTIONS OF (ME3SICH2)2ASSIME3 WITH GALLIUM HALIDES - CRYSTAL-STRUCTURE AND DYNAMIC NMR-STUDY OF THE DIMER ([ME3SICH2)2AS]2GABR)2, ORGANOMETALLICS 6: 2099 (1987). (10.1021/om00153a012) / ORGANOMETALLICS (1987)
ROSSETTI, R, QUANTUM SIZE EFFECTS IN THE REDOX POTENTIALS, RESONANCE RAMAN-SPECTRA, AND ELECTRONIC-SPECTRA OF CDS CRYSTALLITES IN AQUEOUS-SOLUTION, JOURNAL OF CHEMICAL PHYSICS 79: 1086 (1983). (10.1063/1.445834) / JOURNAL OF CHEMICAL PHYSICS (1983)
Sandstroem J. Dynamic NMR Spectroscopy (1982).
SPANHEL, L, PHOTOCHEMISTRY OF COLLOIDAL SEMICONDUCTORS .20. SURFACE MODIFICATION AND STABILITY OF STRONG LUMINESCING CDS PARTICLES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 109: 5649 (1987). (10.1021/ja00253a015) / JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (1987)
STRINGFELLOW, G.B., EPITAXY, REPORTS ON PROGRESS IN PHYSICS 45: 469 (1982). (10.1088/0034-4885/45/5/001) / REPORTS ON PROGRESS IN PHYSICS (1982)
VARIANO, B.F., QUANTUM EFFECTS IN ANISOTROPIC SEMICONDUCTOR CLUSTERS - COLLOIDAL SUSPENSIONS OF BI2S3 AND SB2S3, JOURNAL OF PHYSICAL CHEMISTRY 91: 6455 (1987). (10.1021/j100310a006) / JOURNAL OF PHYSICAL CHEMISTRY (1987)
WELLER, H, PHOTOCHEMISTRY OF SEMICONDUCTOR COLLOIDS .14. PHOTOCHEMISTRY OF COLLOIDAL SEMICONDUCTORS - ONSET OF LIGHT-ABSORPTION AS A FUNCTION OF SIZE OF EXTREMELY SMALL CDS PARTICLES, CHEMICAL PHYSICS LETTERS 124: 557 (1986). (10.1016/0009-2614(86)85075-8) / CHEMICAL PHYSICS LETTERS (1986)
WELLS, R.L., ISOLATION AND CHARACTERIZATION OF AN ORGANOGALLIUM ARSENIC CLUSTER - CRYSTAL-STRUCTURE OF [(PHASH)(ME3SICH2GA)(PNAS)6(ME3SICH2GA)4], JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS: 487 (1986). / JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (1986)
WELLS, R.L., THE 1ST GALLIUM-ARSENIC COMPOUND CONTAINING A SINGLE GA3AS UNIT - ISOLATION AND CRYSTAL-STRUCTURE OF [(THF)BR2GA]3AS (THF = TETRAHYDROFURAN), JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS: 1823 (1987). / JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (1987)
WELLS, R.L., SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DIMER BIS([BIS(TRIMETHYLSILYLMETHYL)ARSINO]DIPHENYLGALLANE), JOURNAL OF ORGANOMETALLIC CHEMISTRY 308: 281 (1986). (10.1016/S0022-328X(00)99726-2) / JOURNAL OF ORGANOMETALLIC CHEMISTRY (1986)
WELLS, R.L., SYNTHESIS AND CHARACTERIZATION OF A DIMERIC TRIS(ARISONO)GALLANE CONTAINING A NONPLANAR (GA-AS)2 RING - CRYSTAL-STRUCTURE OF ([ME3SICH2)2AS]3GA)2, JOURNAL OF ORGANOMETALLIC CHEMISTRY 325: C7 (1987). (10.1016/0022-328X(87)80412-6) / JOURNAL OF ORGANOMETALLIC CHEMISTRY (1987)

Dates

Type	When
Created	18 years, 10 months ago (Oct. 5, 2006, 5:21 p.m.)
Deposited	1 year, 7 months ago (Jan. 12, 2024, 10:25 a.m.)
Indexed	1 month, 3 weeks ago (June 30, 2025, 7:27 a.m.)
Issued	37 years, 1 month ago (July 15, 1988)
Published	37 years, 1 month ago (July 15, 1988)
Published Print	37 years, 1 month ago (July 15, 1988)

Funders 0

None

BibTeX

@article{Byrne_1988, title={Design of a Monomeric Arsinogallane and Chemical Conversion to Gallium Arsenide}, volume={241}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.241.4863.332}, DOI={10.1126/science.241.4863.332}, number={4863}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Byrne, Erin K. and Parkanyi, Laszlo and Theopold, Klaus H.}, year={1988}, month=jul, pages={332–334} }

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