DOI: 10.1126/science.205.4407.651. Solid State Electrodes for High Energy Batteries

Solid State Electrodes for High Energy Batteries

10.1126/science.205.4407.651

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

A new class of electrode materials for high energy density, rechargeable batteries based on topochemical reactions of lithium and transition metal compounds is evolving. The physical and structural properties relevant to the ability of transition metal oxides with framework structures to topochemically incorporate lithium are discussed. Perovskite-related structures are particularly attractive hosts for lithium.

Bibliography

Murphy, D. W., & Christian, P. A. (1979). Solid State Electrodes for High Energy Batteries. Science, 205(4407), 651â656.

Authors 2

D. W. Murphy (first)
P. A. Christian (additional)

References 60 Referenced 324

Klemann L. P. U.S. Patent 4 060 674 (1977).
Whitney T. A. U.S. Patent 4 104 450 (1978).
Koch V. U.S. Patent 4 118 550 (1978).
ANDERSON, J.S., ON POSSIBLE ROLE OF DISLOCATIONS IN GENERATING ORDERED AND DISORDERED SHEAR STRUCTURES, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS 28: 1393 (1967). (10.1016/0022-3697(67)90268-5) / JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (1967)
ANDERSSON, S, NAXTI4O8, AN ALKALI METAL TITANIUM DIOXIDE BRONZE, ACTA CRYSTALLOGRAPHICA 15: 201 (1962). (10.1107/S0365110X62000523) / ACTA CRYSTALLOGRAPHICA (1962)
Armand, M. B., Fast Ion Transport in Solids: 665 (1973). / Fast Ion Transport in Solids (1973)
BACHMANN, H.G., ZEITSCHRIFT FUR KRISTALLOGRAPHIE 115: 110 (1961). (10.1524/zkri.1961.115.1-2.110) / ZEITSCHRIFT FUR KRISTALLOGRAPHIE (1961)
BESENHARD, J.O., CHROMIUM OXIDES AS CATHODES FOR SECONDARY HIGH-ENERGY DENSITY LITHIUM BATTERIES, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 124: 968 (1977). (10.1149/1.2133510) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1977)
BESENHARD, J.O., J POWER SOURCES 1: 267 (1976). (10.1016/0378-7753(76)81004-X) / J POWER SOURCES (1976)
Broadhead J. paper presented at the Electrochemical Society Meeting Chicago 13 to 18 May (1973).
Broadhead, J., Power Sources 4: 469 (1973). / Power Sources 4 (1973)
BYSTROM, A, VANADIUM PENTOXIDE - A COMPOUND WITH 5-COORDINATED VANADIUM ATOMS, ACTA CHEMICA SCANDINAVICA 4: 1119 (1950). (10.3891/acta.chem.scand.04-1119) / ACTA CHEMICA SCANDINAVICA (1950)
10.1126/science.164.3886.1347
CHIANELLI, R.R., REACTION OF NORMAL-BUTYLLITHIUM WITH TRANSITION-METAL TRICHALCOGENIDES, INORGANIC CHEMISTRY 14: 2417 (1975). (10.1021/ic50152a023) / INORGANIC CHEMISTRY (1975)
Clark, G. M., The Structures of Non-Molecular Solids: 148 (1972). / The Structures of Non-Molecular Solids (1972)
DANOT, M, BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE: 2670 (1969). / BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE (1969)
DINES, M.B., LITHIUM INTERCALATION VIA N-BUTYLLITHIUM OF LAYERED TRANSITION-METAL DICHALCOGENIDES, MATERIALS RESEARCH BULLETIN 10: 287 (1975). (10.1016/0025-5408(75)90115-4) / MATERIALS RESEARCH BULLETIN (1975)
DiPietro, B., Power Sources 6: 527 (1977). / Power Sources 6 (1977)
FARRINGTON, G.C., FAST IONIC TRANSPORT IN SOLIDS, SCIENCE 204: 1371 (1979). (10.1126/science.204.4400.1371) / SCIENCE (1979)
Gaines L. H. paper presented at the I Ith Intersociety Energy Conversion Engineering Conference Lake Tahoe September (1976).
Gamble, F. R., Treatise on Solid State Chemistry 3: 125 (1976). / Treatise on Solid State Chemistry (1976)
GOODENOUGH, J.B., FAST NA+-ION TRANSPORT IN SKELETON STRUCTURES, MATERIALS RESEARCH BULLETIN 11: 203 (1976). (10.1016/0025-5408(76)90077-5) / MATERIALS RESEARCH BULLETIN (1976)
GUERARD, D, INTERCALATION OF LITHIUM INTO GRAPHITE AND OTHER CARBONS, CARBON 13: 337 (1975). (10.1016/0008-6223(75)90040-8) / CARBON (1975)
HARDY, A, BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE: 1056 (1965). / BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE (1965)
Heyne, L., Fast Ion Transport in Solids: 123 (1973). / Fast Ion Transport in Solids (1973)
HOLLECK, G.L., TRANSITION-METAL SULFIDES AS CATHODES FOR SECONDARY LITHIUM BATTERIES .2. TITANIUM SULFIDES, ELECTROCHIMICA ACTA 22: 647 (1977). (10.1016/0013-4686(77)85134-7) / ELECTROCHIMICA ACTA (1977)
Hong H. Y.P. paper presented at the American Chemical Society Meeting Miami Beach Fla. September (1978).
Ikeda, H., Manganese Dioxide Symposium Proceedings 1: 384 (1975). / Manganese Dioxide Symposium Proceedings (1975)
JOHNSON, O.W., PHYS REV A 136: 284 (1964). (10.1103/PhysRev.136.A284) / PHYS REV A (1964)
KAWASHIMA, K, CHEMISTRY LETTERS: 1131 (1975). / CHEMISTRY LETTERS (1975)
Murphy, D. W., Inorganic Chemistry 18: 2800 (1979). (10.1021/ic50200a034) / Inorganic Chemistry (1979)
MURPHY, D.W., CONVENIENT PREPARATION AND PHYSICAL-PROPERTIES OF LITHIUM INTERCALATION COMPOUNDS OF GROUP-4B AND GROUP-5B LAYERED TRANSITION-METAL DICHALCOGENIDES, INORGANIC CHEMISTRY 15: 17 (1976). (10.1021/ic50155a005) / INORGANIC CHEMISTRY (1976)
MURPHY, D. W., JOURNAL OF CRYSTAL GROWTH 39: 185 (1977). (10.1016/0022-0248(77)90165-8) / JOURNAL OF CRYSTAL GROWTH (1977)
MURPHY, D.W., CHEMISTRY OF TIS3 AND NBSE3 CATHODES, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 123: 960 (1976). (10.1149/1.2133012) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1976)
MURPHY, D.W., VANADIUM-OXIDE CATHODE MATERIALS FOR SECONDARY LITHIUM CELLS, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 126: 497 (1979). (10.1149/1.2129070) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1979)
MURPHY, D.W., NEW NIOBIUM SELENIDE CATHODE FOR NON-AQUEOUS LITHIUM BATTERIES, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 124: 325 (1977). (10.1149/1.2133298) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1977)
MURPHY, D.W., CATHODES FOR NON-AQUEOUS LITHIUM BATTERIES BASED ON VS2, MATERIALS RESEARCH BULLETIN 12: 825 (1977). (10.1016/0025-5408(77)90011-3) / MATERIALS RESEARCH BULLETIN (1977)
MURPHY, D.W., TOPOCHEMICAL REACTIONS OF RUTILE RELATED STRUCTURES WITH LITHIUM, MATERIALS RESEARCH BULLETIN 13: 1395 (1978). (10.1016/0025-5408(78)90131-9) / MATERIALS RESEARCH BULLETIN (1978)
Murphy D. W. paper presented at the International Conference on Fast Ion Transport in Solids Lake Geneva Wis. 21 to 25 May (1979).
OMLOO, WPF, INTERCALATION COMPOUNDS OF ALKALI METALS WITH NIOBIUM AND TANTALUM DICHALCOGENIDES, JOURNAL OF THE LESS-COMMON METALS 20: 121 (1970). (10.1016/0022-5088(70)90096-2) / JOURNAL OF THE LESS-COMMON METALS (1970)
RAO, BML, LITHIUM-ALUMINUM ELECTRODE, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 124: 1490 (1977). (10.1149/1.2133098) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1977)
Rao B. M. L. paper presented at the Electrochemical Society Meeting Atlanta October (1977).
SATA, T, B TOKYO I TECHNOL 98: 1 (1970). / B TOKYO I TECHNOL (1970)
Steele, B. C. H., Fast Ion Transport in Solids: 103 (1973). / Fast Ion Transport in Solids (1973)
STEELE, B.C., SUPERIONIC CONDUCTOR: 47 (1976). / SUPERIONIC CONDUCTOR (1976)
THEOBALD, F, EXISTENCE AND STABILITY DOMAIN OF 2 VANADIUM OXIDES OF COMPOSITION NEAR VO2, COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C 268: 60 (1969). / COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C (1969)
THEOBALD, F, STRUCTURAL ELUCIDATION OF VO2(B), JOURNAL OF SOLID STATE CHEMISTRY 17: 431 (1976). (10.1016/S0022-4596(76)80013-8) / JOURNAL OF SOLID STATE CHEMISTRY (1976)
VISSERS, D.R., PRELIMINARY INVESTIGATION OF HIGH-TEMPERATURE LITHIUM-IRON SULFIDE SECONDARY CELLS, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 121: 665 (1974). (10.1149/1.2401882) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1974)
Walk C. R. paper presented at the Electrochemical Society Meeting Toronto 11 to 16 May (1975).
Weber, N., Advances in Energy Conversion Engineering: 913 (1967). / Advances in Energy Conversion Engineering (1967)
Whittingham, M. S., Fast Ion Transport in Solids: 645 (1973). / Fast Ion Transport in Solids (1973)
WHITTINGHAM, M.S., ROLE OF TERNARY PHASES IN CATHODE REACTIONS, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 123: 315 (1976). (10.1149/1.2132817) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1976)
WHITTINGHAM, M.S., NORMAL-BUTYLLITHIUM - EFFECTIVE, GENERAL CATHODE SCREENING AGENT, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 124: 1387 (1977). (10.1149/1.2133659) / JOURNAL OF THE ELECTROCHEMICAL SOCIETY (1977)
WHITTINGHAM, M.S., PROG SOLID STATE CHE 12: 1 (1978). (10.1016/0079-6786(78)90002-X) / PROG SOLID STATE CHE (1978)
10.1126/science.192.4244.1126
WHITTINGHAM, M.S., SOLID ELECTROLYTES: 93 (1977). / SOLID ELECTROLYTES (1977)
WILHELMI, K.A., REFINEMENT OF CRYSTAL STRUCTURE OF V6O13, ACTA CHEMICA SCANDINAVICA 25: 2675 (1971). (10.3891/acta.chem.scand.25-2675) / ACTA CHEMICA SCANDINAVICA (1971)
WINN, D.A., TITANIUM DISULFIDE - SOLID-SOLUTION ELECTRODE FOR SODIUM AND LITHIUM, MATERIALS RESEARCH BULLETIN 11: 559 (1976). (10.1016/0025-5408(76)90239-7) / MATERIALS RESEARCH BULLETIN (1976)
WISEMAN, P.J., NEUTRON-DIFFRACTION STUDIES OF CUBIC TUNGSTEN BRONZES, JOURNAL OF SOLID STATE CHEMISTRY 17: 91 (1976). (10.1016/0022-4596(76)90206-1) / JOURNAL OF SOLID STATE CHEMISTRY (1976)
WORRELL, W.L., P S WORKSHOP ADV BAT: B2 (1976). / P S WORKSHOP ADV BAT (1976)

Dates

Type	When
Created	18 years, 10 months ago (Oct. 5, 2006, 12:39 p.m.)
Deposited	1 year, 7 months ago (Jan. 11, 2024, 10:41 p.m.)
Indexed	3 days, 18 hours ago (Aug. 29, 2025, 6:49 a.m.)
Issued	46 years ago (Aug. 17, 1979)
Published	46 years ago (Aug. 17, 1979)
Published Print	46 years ago (Aug. 17, 1979)

Funders 0

None

BibTeX

@article{Murphy_1979, title={Solid State Electrodes for High Energy Batteries}, volume={205}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.205.4407.651}, DOI={10.1126/science.205.4407.651}, number={4407}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Murphy, D. W. and Christian, P. A.}, year={1979}, month=aug, pages={651–656} }

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