DOI: 10.1126/science.147.3661.1038.b. α-D-Glucose: Precise Determination of Crystal and Molecular Structure by Neutron-Diffraction Analysis

α-D-Glucose: Precise Determination of Crystal and Molecular Structure by Neutron-Diffraction Analysis

10.1126/science.147.3661.1038.b

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

This analysis provides the first precise crystal and molecular structural parameters for α-D-glucose. The C—C, C—H, and O—H bond lengths deviate only slightly from their means of 1.523 Å, 1.098 Å, and 0.968 Å. The C(1)—O(1) bond length, 1.389 Å, is significantly shorter than the mean value, 1.420 Å, of the other C—O bonds. The valence angle of the ring oxygen is 113.8 degrees.

Bibliography

Brown, G. M., & Levy, H. A. (1965). Î±-D-Glucose: Precise Determination of Crystal and Molecular Structure by Neutron-Diffraction Analysis. Science, 147(3661), 1038â1039.

Authors 2

George M. Brown (first)
Henri A. Levy (additional)

References 6 Referenced 17

10.1107/S0365110X52001787
10.1051/jphys:01964002505049500
10.1051/jphys:01964002505049700
Busing W. R. OR FLS A Fortran Crystallographic Least-Squares Program (1962). (10.2172/4772079)
Peerdemann, A. F., Koninkl. Ned. Akad. Wetenschap. Proc. Ser. B 54: 16 (1951). / Koninkl. Ned. Akad. Wetenschap. Proc. Ser. B (1951)
10.1126/science.141.3584.921

Dates

Type	When
Created	3 years, 10 months ago (Oct. 22, 2021, 2:17 a.m.)
Deposited	1 year, 7 months ago (Jan. 10, 2024, 10:30 p.m.)
Indexed	4 months, 3 weeks ago (April 4, 2025, 7:08 a.m.)
Issued	60 years, 6 months ago (Feb. 26, 1965)
Published	60 years, 6 months ago (Feb. 26, 1965)
Published Print	60 years, 6 months ago (Feb. 26, 1965)

Funders 0

None

BibTeX

@article{Brown_1965, title={α-D-Glucose: Precise Determination of Crystal and Molecular Structure by Neutron-Diffraction Analysis}, volume={147}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.147.3661.1038.b}, DOI={10.1126/science.147.3661.1038.b}, number={3661}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Brown, George M. and Levy, Henri A.}, year={1965}, month=feb, pages={1038–1039} }

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  "abstract": "<jats:p>This analysis provides the first precise crystal and molecular structural parameters for \u03b1-D-glucose. The C\u2014C, C\u2014H, and O\u2014H bond lengths deviate only slightly from their means of 1.523 \u00c5, 1.098 \u00c5, and 0.968 \u00c5. The C(1)\u2014O(1) bond length, 1.389 \u00c5, is significantly shorter than the mean value, 1.420 \u00c5, of the other C\u2014O bonds. The valence angle of the ring oxygen is 113.8 degrees.</jats:p>",
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