DOI: 10.1126/science.1253057. Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO <sub>2</sub>

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2

10.1126/science.1253057

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

Converting CO 2 into methanol by catalysis By hydrogenating CO 2 , scientists can transform a greenhouse gas into methanol, a desirable fuel. Graciani et al. cast copper in the role of the highly active catalyst for this reaction by putting copper particles on cerium oxide. The interface between the cerium oxide and the copper enables the reverse water-gas shift reaction that converts CO 2 into CO, which reacts more readily with hydrogen to make methanol. This result takes a step forward in innovating catalysts for this environmentally friendly process. Science , this issue p. 546

Bibliography

Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., & Rodriguez, J. A. (2014). Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2. Science, 345(6196), 546â550.

Authors 11

Jesús Graciani (first)
Kumudu Mudiyanselage (additional)
Fang Xu (additional)
Ashleigh E. Baber (additional)
Jaime Evans (additional)
Sanjaya D. Senanayake (additional)
Darío J. Stacchiola (additional)
Ping Liu (additional)
Jan Hrbek (additional)
Javier Fernández Sanz (additional)
José A. Rodriguez (additional)

References 37 Referenced 1,295

G. A. Olah A. Goeppert G. K. Surya Prakash Beyond Oil and Gas: The Methanol Economy (Wiley-VCH Weinheim Germany 2011)
10.1126/science.1219831
10.1016/S0166-9834(00)84123-8
10.1023/A:1019181715731
M. Aresta Ed. Carbon Dioxide as Chemical Feedstock (Wiley-VCH New York 2010). (10.1002/9783527629916)
10.1039/c001484b
10.1006/jcat.1996.0240
10.1016/0039-6028(94)90101-5
10.1021/jp208448c
10.1002/anie.201105481
10.1039/c0gc00951b
10.1021/jz300989e
10.1021/ar300231p
10.1002/anie.201210077
10.1002/anie.200903918
10.1021/ja408506y
10.1039/f19898500929
10.1016/S0039-6028(98)00857-7
10.1039/b913310k
10.1021/la8011052
10.1016/j.jcat.2012.10.028
10.1016/j.jcat.2011.04.012
10.1073/pnas.0812604106
10.1021/ja9087677
10.1063/1.3337918
10.1126/science.1207272
10.1038/nchem.1873
10.1063/1.3427218
10.1021/ja8081268
10.1021/ja1087979
10.1103/PhysRevB.45.13244
10.1103/PhysRevB.59.1758
10.1103/PhysRevB.47.558
10.1016/0927-0256(96)00008-0
10.1103/PhysRevB.57.1505
10.1103/PhysRevB.72.237102
10.1021/jp3125268

Dates

Type	When
Created	11 years, 1 month ago (July 31, 2014, 3:10 p.m.)
Deposited	1 year, 7 months ago (Jan. 10, 2024, 4:26 p.m.)
Indexed	1 day ago (Aug. 31, 2025, 7:16 p.m.)
Issued	11 years, 1 month ago (Aug. 1, 2014)
Published	11 years, 1 month ago (Aug. 1, 2014)
Published Print	11 years, 1 month ago (Aug. 1, 2014)

Funders 0

None

BibTeX

@article{Graciani_2014, title={Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2}, volume={345}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.1253057}, DOI={10.1126/science.1253057}, number={6196}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Graciani, Jesús and Mudiyanselage, Kumudu and Xu, Fang and Baber, Ashleigh E. and Evans, Jaime and Senanayake, Sanjaya D. and Stacchiola, Darío J. and Liu, Ping and Hrbek, Jan and Sanz, Javier Fernández and Rodriguez, José A.}, year={2014}, month=aug, pages={546–550} }

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