DOI: 10.1126/science.1234751. Galvanic Replacement Reactions in Metal Oxide Nanocrystals

Galvanic Replacement Reactions in Metal Oxide Nanocrystals

10.1126/science.1234751

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

Hollowing Out Metal Oxide Nanoparticles Corrosion is normally a problem, but it can be useful, for example, when you wish to create hollow metal nanoparticles, whereby the reduction of one metal species in solution drives the dissolution of the core of the particle. Oh et al. (p. 964 ; see the Perspective by Ibáñez and Cabot ) adapted this approach to metal oxide nanoparticles by placing Mn 3 O 4 nanocrystals in solution with Fe 2+ ions, which replaces the nanocrystal exterior with γ-Fe 2 O 3 . At sufficiently high Fe 2+ concentrations, hollow γ-Fe 2 O 3 nanocages formed. These hollow structures could be used as anode materials for lithium ion batteries.

Bibliography

Oh, M. H., Yu, T., Yu, S.-H., Lim, B., Ko, K.-T., Willinger, M.-G., Seo, D.-H., Kim, B. H., Cho, M. G., Park, J.-H., Kang, K., Sung, Y.-E., Pinna, N., & Hyeon, T. (2013). Galvanic Replacement Reactions in Metal Oxide Nanocrystals. Science, 340(6135), 964â968.

Authors 14

Myoung Hwan Oh (first)
Taekyung Yu (additional)
Seung-Ho Yu (additional)
Byungkwon Lim (additional)
Kyung-Tae Ko (additional)
Marc-Georg Willinger (additional)
Dong-Hwa Seo (additional)
Byung Hyo Kim (additional)
Min Gee Cho (additional)
Jae-Hoon Park (additional)
Kisuk Kang (additional)
Yung-Eun Sung (additional)
Nicola Pinna (additional)
Taeghwan Hyeon (additional)

References 42 Referenced 507

Dates

Type	When
Created	12 years, 2 months ago (May 23, 2013, 2:20 p.m.)
Deposited	1 year, 7 months ago (Jan. 10, 2024, 9:50 a.m.)
Indexed	2 days, 8 hours ago (Aug. 19, 2025, 6:34 a.m.)
Issued	12 years, 2 months ago (May 24, 2013)
Published	12 years, 2 months ago (May 24, 2013)
Published Print	12 years, 2 months ago (May 24, 2013)

Funders 0

None

BibTeX

@article{Oh_2013, title={Galvanic Replacement Reactions in Metal Oxide Nanocrystals}, volume={340}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.1234751}, DOI={10.1126/science.1234751}, number={6135}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Oh, Myoung Hwan and Yu, Taekyung and Yu, Seung-Ho and Lim, Byungkwon and Ko, Kyung-Tae and Willinger, Marc-Georg and Seo, Dong-Hwa and Kim, Byung Hyo and Cho, Min Gee and Park, Jae-Hoon and Kang, Kisuk and Sung, Yung-Eun and Pinna, Nicola and Hyeon, Taeghwan}, year={2013}, month=may, pages={964–968} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        19
      ]
    ],
    "date-time": "2025-08-19T10:34:28Z",
    "timestamp": 1755599668148
  },
  "reference-count": 42,
  "publisher": "American Association for the Advancement of Science (AAAS)",
  "issue": "6135",
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2013,
        5,
        24
      ]
    ]
  },
  "abstract": "<jats:title>Hollowing Out Metal Oxide Nanoparticles</jats:title>\n          <jats:p>\n            Corrosion is normally a problem, but it can be useful, for example, when you wish to create hollow metal nanoparticles, whereby the reduction of one metal species in solution drives the dissolution of the core of the particle.\n            <jats:bold>\n              Oh\n              <jats:italic>et al.</jats:italic>\n            </jats:bold>\n            (p.\n            <jats:related-article xmlns:xlink=\"http://www.w3.org/1999/xlink\" ext-link-type=\"doi\" issue=\"6135\" page=\"964\" related-article-type=\"in-this-issue\" vol=\"340\" xlink:href=\"10.1126/science.1234751\">964</jats:related-article>\n            ; see the Perspective by\n            <jats:related-article xmlns:xlink=\"http://www.w3.org/1999/xlink\" ext-link-type=\"doi\" issue=\"6135\" page=\"935\" related-article-type=\"in-this-issue\" vol=\"340\" xlink:href=\"10.1126/science.1239221\">\n              <jats:bold>Ib\u00e1\u00f1ez and Cabot</jats:bold>\n            </jats:related-article>\n            ) adapted this approach to metal oxide nanoparticles by placing Mn\n            <jats:sub>3</jats:sub>\n            O\n            <jats:sub>4</jats:sub>\n            nanocrystals in solution with Fe\n            <jats:sup>2+</jats:sup>\n            ions, which replaces the nanocrystal exterior with \u03b3-Fe\n            <jats:sub>2</jats:sub>\n            O\n            <jats:sub>3</jats:sub>\n            . At sufficiently high Fe\n            <jats:sup>2+</jats:sup>\n            concentrations, hollow \u03b3-Fe\n            <jats:sub>2</jats:sub>\n            O\n            <jats:sub>3</jats:sub>\n            nanocages formed. These hollow structures could be used as anode materials for lithium ion batteries.\n          </jats:p>",
  "DOI": "10.1126/science.1234751",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2013,
        5,
        23
      ]
    ],
    "date-time": "2013-05-23T18:20:19Z",
    "timestamp": 1369333219000
  },
  "page": "964-968",
  "source": "Crossref",
  "is-referenced-by-count": 507,
  "title": "Galvanic Replacement Reactions in Metal Oxide Nanocrystals",
  "prefix": "10.1126",
  "volume": "340",
  "author": [
    {
      "given": "Myoung Hwan",
      "family": "Oh",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Center for Nanoparticle Research, Institute for Basic Science (IBS), and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        },
        {
          "name": "World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    },
    {
      "given": "Taekyung",
      "family": "Yu",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemical Engineering, College of Engineering, Kyung Hee University, Yongin 446-701, Korea."
        }
      ]
    },
    {
      "given": "Seung-Ho",
      "family": "Yu",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Center for Nanoparticle Research, Institute for Basic Science (IBS), and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        },
        {
          "name": "World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    },
    {
      "given": "Byungkwon",
      "family": "Lim",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746, Korea."
        }
      ]
    },
    {
      "given": "Kyung-Tae",
      "family": "Ko",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Cross-Coupled Complex Materials Research and Department of Physics, Pohang University of Science and Technology, Pohang 790-784, Korea."
        }
      ]
    },
    {
      "given": "Marc-Georg",
      "family": "Willinger",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society, Berlin 14195, Germany."
        }
      ]
    },
    {
      "given": "Dong-Hwa",
      "family": "Seo",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    },
    {
      "given": "Byung Hyo",
      "family": "Kim",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Center for Nanoparticle Research, Institute for Basic Science (IBS), and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        },
        {
          "name": "World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    },
    {
      "given": "Min Gee",
      "family": "Cho",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Center for Nanoparticle Research, Institute for Basic Science (IBS), and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        },
        {
          "name": "World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    },
    {
      "given": "Jae-Hoon",
      "family": "Park",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Cross-Coupled Complex Materials Research and Department of Physics, Pohang University of Science and Technology, Pohang 790-784, Korea."
        },
        {
          "name": "Division of Advanced Materials Science, Pohang University of Science and Technology, Pohang 790-784, Korea."
        }
      ]
    },
    {
      "given": "Kisuk",
      "family": "Kang",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    },
    {
      "given": "Yung-Eun",
      "family": "Sung",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Center for Nanoparticle Research, Institute for Basic Science (IBS), and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        },
        {
          "name": "World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    },
    {
      "given": "Nicola",
      "family": "Pinna",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        },
        {
          "name": "Department of Chemistry and Centre for Research in Ceramics &amp; Composite Materials, University of Aveiro, Aveiro 3810-193, Portugal."
        },
        {
          "name": "Institut f\u00fcr Chemie, Humboldt-Universit\u00e4t zu Berlin, Berlin 12489, Germany."
        }
      ]
    },
    {
      "given": "Taeghwan",
      "family": "Hyeon",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Center for Nanoparticle Research, Institute for Basic Science (IBS), and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        },
        {
          "name": "World Class University (WCU) Program of Chemical Convergence for Energy and Environment and School of Chemical and Biological Engineering, Seoul National University, Seoul 151-742, Korea."
        }
      ]
    }
  ],
  "member": "221",
  "reference": [
    {
      "key": "e_1_3_2_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1077229"
    },
    {
      "key": "e_1_3_2_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl034097+"
    },
    {
      "key": "e_1_3_2_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja039734c"
    },
    {
      "key": "e_1_3_2_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar800018v"
    },
    {
      "key": "e_1_3_2_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nmat2848"
    },
    {
      "key": "e_1_3_2_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl100559y"
    },
    {
      "key": "e_1_3_2_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1212822"
    },
    {
      "key": "e_1_3_2_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja073032w"
    },
    {
      "key": "e_1_3_2_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.201200469"
    },
    {
      "key": "e_1_3_2_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nmat2118"
    },
    {
      "key": "e_1_3_2_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1096566"
    },
    {
      "key": "e_1_3_2_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1103755"
    },
    {
      "key": "e_1_3_2_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja905732q"
    },
    {
      "key": "e_1_3_2_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200700677"
    },
    {
      "key": "e_1_3_2_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja072574a"
    },
    {
      "key": "e_1_3_2_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja903751p"
    },
    {
      "key": "e_1_3_2_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.nantod.2009.10.008"
    },
    {
      "key": "e_1_3_2_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.nantod.2011.02.006"
    },
    {
      "key": "e_1_3_2_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cm900431b"
    },
    {
      "key": "e_1_3_2_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es001356d"
    },
    {
      "key": "e_1_3_2_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.77.035121"
    },
    {
      "key": "e_1_3_2_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201108098"
    },
    {
      "key": "e_1_3_2_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s10008-007-0269-5"
    },
    {
      "key": "e_1_3_2_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja105296a"
    },
    {
      "key": "e_1_3_2_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.elecom.2009.12.040"
    },
    {
      "key": "e_1_3_2_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nnano.2007.411"
    },
    {
      "key": "e_1_3_2_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl3004286"
    },
    {
      "key": "e_1_3_2_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c1cc15322f"
    },
    {
      "key": "e_1_3_2_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.electacta.2009.05.058"
    },
    {
      "key": "e_1_3_2_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.77.3865"
    },
    {
      "key": "e_1_3_2_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0927-0256(96)00008-0"
    },
    {
      "key": "e_1_3_2_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.57.1505"
    },
    {
      "key": "e_1_3_2_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.73.195107"
    },
    {
      "key": "e_1_3_2_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1329672"
    },
    {
      "key": "e_1_3_2_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.83.205127"
    },
    {
      "key": "e_1_3_2_38_2",
      "doi-asserted-by": "crossref",
      "unstructured": "Y. H. Li T. Kouh I.-B. Shim C. S. Kim Investigation of cation distribution in single crystalline Fe3\u2212xMnxO4 microspheres based on M\u00f6ssbauer spectroscopy. J. Appl. Phys. 111 07B544 (2012).",
      "DOI": "10.1063/1.3687007"
    },
    {
      "key": "e_1_3_2_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.1801451"
    },
    {
      "key": "e_1_3_2_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp203056n"
    },
    {
      "key": "e_1_3_2_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.84.045115"
    },
    {
      "key": "e_1_3_2_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/ncomms2185"
    },
    {
      "key": "e_1_3_2_43_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cm801105p"
    },
    {
      "key": "e_1_3_2_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja305539r"
    }
  ],
  "container-title": "Science",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://www.science.org/doi/pdf/10.1126/science.1234751",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        10
      ]
    ],
    "date-time": "2024-01-10T14:50:06Z",
    "timestamp": 1704898206000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://www.science.org/doi/10.1126/science.1234751"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2013,
        5,
        24
      ]
    ]
  },
  "references-count": 42,
  "journal-issue": {
    "issue": "6135",
    "published-print": {
      "date-parts": [
        [
          2013,
          5,
          24
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1126/science.1234751"
  ],
  "URL": "http://dx.doi.org/10.1126/science.1234751",
  "relation": {},
  "ISSN": [
    "0036-8075",
    "1095-9203"
  ],
  "subject": [],
  "container-title-short": "Science",
  "published": {
    "date-parts": [
      [
        2013,
        5,
        24
      ]
    ]
  }
}