Abstract
Approaching Lactate Inorganically Conversion of biomass to value-added chemical compounds currently relies in large part on fermentation. For full-scale displacement of petroleum as the chemical industry's primary feedstock, alternative conversion technologies will be necessary. Holm et al. (p. 602 ) have found that Lewis acidic zeolite derivatives suspended in methanol can catalyze the selective conversion of glucose, fructose, and sucrose sugars to methyl lactate, a versatile synthetic intermediate for commercial products. The catalysts were easily separated from product mixtures and proved robust over six reaction and regeneration cycles.
References
30
Referenced
863
10.1021/cr068360d
10.1039/a806968i
10.1021/cr050989d
-
Christensen C. H., Rass-Hansen J., Marsden C. C., Taarning E., Egeblad K., Chem. Sus. Chem. 1, 283 (2008).
(
10.1002/cssc.200700168
) / Chem. Sus. Chem. by Christensen C. H. (2008) 10.1126/science.1141199
10.1126/science.1126337
10.1039/b211468b
10.1126/science.1137016
10.1016/S0141-3910(97)00148-1
10.1016/S0141-3910(02)00372-5
10.1021/ie049963n
10.1002/jctb.1486
10.1080/01614940903048513
-
Serrano-Ruiz J. C., Dumesic J. A., Chem. Sus. Chem 2, 581 (2009).
(
10.1002/cssc.200900004
) / Chem. Sus. Chem by Serrano-Ruiz J. C. (2009) -
Taarning E., et al.., Chem. Sus. Chem 2, 625 (2009).
(
10.1002/cssc.200900099
) / Chem. Sus. Chem by Taarning E. (2009) 10.1016/j.jcat.2009.10.023
10.1039/b501964h
-
Aida T. M., et al.., J. Supercrit. Fluid. 42, 110 (2007).
(
10.1016/j.supflu.2006.12.017
) / J. Supercrit. Fluid. by Aida T. M. (2007) 10.1039/b203968k
10.1021/ie50521a600
10.1016/0008-6215(95)00233-2
- G. Braun U.S. patent 2 024 565 (1935).
10.1002/anie.200462473
10.1002/chem.200600478
10.1016/S0021-9517(02)00132-X
10.1016/0144-4565(87)90046-1
10.1016/0920-5861(95)00026-C
10.1002/1521-3765(20021018)8:20<4708::AID-CHEM4708>3.0.CO;2-U
10.1023/A:1019160827175
10.1021/ja012297m
Dates
Type | When |
---|---|
Created | 15 years, 3 months ago (April 29, 2010, 2:53 p.m.) |
Deposited | 1 year, 7 months ago (Jan. 10, 2024, 3:04 a.m.) |
Indexed | 37 minutes ago (Aug. 28, 2025, 8:35 p.m.) |
Issued | 15 years, 3 months ago (April 30, 2010) |
Published | 15 years, 3 months ago (April 30, 2010) |
Published Print | 15 years, 3 months ago (April 30, 2010) |
@article{Holm_2010, title={Conversion of Sugars to Lactic Acid Derivatives Using Heterogeneous Zeotype Catalysts}, volume={328}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.1183990}, DOI={10.1126/science.1183990}, number={5978}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Holm, Martin Spangsberg and Saravanamurugan, Shunmugavel and Taarning, Esben}, year={2010}, month=apr, pages={602–605} }