DOI: 10.1126/science.1116275. A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area

10.1126/science.1116275

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

We combined targeted chemistry and computational design to create a crystal structure for porous chromium terephthalate, MIL-101, withverylargeporesizes and surface area. Its zeotype cubic structure has a giant cell volume (∼702,000 cubic angstroms), a hierarchy of extra-large pore sizes (∼30 to 34 angstroms), and a Langmuir surface area for N 2 of ∼5900 ± 300 square meters per gram. Beside the usual properties of porous compounds, this solid has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.

Bibliography

FeÌrey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., SurbleÌ, S., & Margiolaki, I. (2005). A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area. Science, 309(5743), 2040â2042.

Authors 7

G. Férey (first)
C. Mellot-Draznieks (additional)
C. Serre (additional)
F. Millange (additional)
J. Dutour (additional)
S. Surblé (additional)
I. Margiolaki (additional)

References 26 Referenced 4,892

10.1038/35010088
F. Schüth et al., Handbook of Porous Solids (Wiley-VCH, Weinheim, Germany, 2002), vol. 3, p. 563. / Handbook of Porous Solids (2002)
10.1021/ja049408c
G. Férey et al., Chem. Commun.2003, 2276 (2003). / Chem. Commun. (2003)
10.1126/science.1062126
10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z
10.1038/352320a0
C. Serre et al., Angew. Chem. Int. Ed. Engl.43, 6286 (2004). / Angew. Chem. Int. Ed. Engl. (2004)
S. Girard et al., Stud. Surf. Sci. Catal.135, 254 (2001). / Stud. Surf. Sci. Catal. (2001)
10.1021/ja020999l
10.1002/1521-3765(20020916)8:18<4102::AID-CHEM4102>3.0.CO;2-3
C. Mellot-Draznieks et al., Angew. Chem. Int. Ed. Engl.39, 2271 (2000). / Angew. Chem. Int. Ed. Engl. (2000)
10.1002/anie.200454251
10.1002/zaac.200400416
10.1002/anie.200460592
10.1021/ar040163i
Materials and methods are available as supporting material on Science Online.
Available at www.iza-structure.org/databases.
10.1006/jssc.2000.8667
10.1038/nature02311
Materials and methods are available as supporting material on Science Online.
A. Muller et al., Angew. Chem. Int. Ed. Engl.39, 3414 (2000). / Angew. Chem. Int. Ed. Engl. (2000)
Initial hydrogen storage measurements were ∼0.45 and 3.75 weight percent at 293 K and 77 K respectively at 2 MPa. The values at 77 K seem to be the highest for MOFs after the contestation of previous results ( 3 ).
Initial introduction of semiconducting ZnS nanoparticles in the pores of MIL-101 was successfully achieved with a ZnS/Cr ratio close to 0.5.
Incorporation of ibuprofen within MIL-101 has been achieved in large amounts (∼1 g of drug per gram of MIL-101) with a total release of the drug within a few days.
We thank F. Taulelle and M. Haouas for collecting solid state NMR M. Latroche for hydrogen sorption measurements P. Mialane for providing the Keggin salt and for helpful discussions S. Floquet and E. Cadot for helpful discussion about the introduction of ZnS nanoparticles and P. Horcajada and M. Vallet-Regi for the drug incorporation study.

Dates

Type	When
Created	19 years, 10 months ago (Sept. 22, 2005, 4:58 p.m.)
Deposited	1 year, 7 months ago (Jan. 9, 2024, 9:50 p.m.)
Indexed	19 minutes ago (Aug. 21, 2025, 9:33 a.m.)
Issued	19 years, 10 months ago (Sept. 23, 2005)
Published	19 years, 10 months ago (Sept. 23, 2005)
Published Print	19 years, 10 months ago (Sept. 23, 2005)

Funders 0

None

BibTeX

@article{Fe_rey_2005, title={A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area}, volume={309}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.1116275}, DOI={10.1126/science.1116275}, number={5743}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Férey, G. and Mellot-Draznieks, C. and Serre, C. and Millange, F. and Dutour, J. and Surblé, S. and Margiolaki, I.}, year={2005}, month=sep, pages={2040–2042} }

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