DOI: 10.1126/science.1078481. Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid

Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid

10.1126/science.1078481

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

We report the direct observation of dioxygen molecules physisorbed in the nanochannels of a microporous copper coordination polymer by the MEM (maximum entropy method)/Rietveld method, using in situ high-resolution synchrotron x-ray powder diffraction measurements. The obtained MEM electron density revealed that van der Waals dimers of physisorbed O 2 locate in the middle of nanochannels and form a one-dimensional ladder structure aligned to the host channel structure. The observed O–O stretching Raman band and magnetic susceptibilities are characteristic of the confined O 2 molecules in one-dimensional nanochannels of CPL-1 (coordination polymer 1 with pillared layer structure).

Bibliography

Kitaura, R., Kitagawa, S., Kubota, Y., Kobayashi, T. C., Kindo, K., Mita, Y., Matsuo, A., Kobayashi, M., Chang, H.-C., Ozawa, T. C., Suzuki, M., Sakata, M., & Takata, M. (2002). Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid. Science, 298(5602), 2358â2361.

Authors 13

Ryo Kitaura (first)
Susumu Kitagawa (additional)
Yoshiki Kubota (additional)
Tatsuo C. Kobayashi (additional)
Koichi Kindo (additional)
Yoshimi Mita (additional)
Akira Matsuo (additional)
Michihiro Kobayashi (additional)
Ho-Chol Chang (additional)
Tadashi C. Ozawa (additional)
Megumi Suzuki (additional)
Makoto Sakata (additional)
Masaki Takata (additional)

References 22 Referenced 582

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The space group was assigned as P 2 1 / c and the lattice parameters were determined by Rietveld analysis as follows a = 4.71534(6) Å b = 19.8280(2) Å c = 10.7184(1) Å and β = 95.1031(10)°. R wp and R I were 2.6 and 3.3% respectively.
The MEM analysis was carried out by the computer program ENIGMA. The unit cell was divided into pixels (128 by 512 by 256) in calculation.
Tanaka H., et al., J. Appl. Crystallogr. 35, 282 (2002). (10.1107/S002188980200050X) / J. Appl. Crystallogr. by Tanaka H. (2002)
Miyahara M., Gubbins K. E., J. Chem. Phys. 106, 2865 (1997). (10.1063/1.473415) / J. Chem. Phys. by Miyahara M. (1997)
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Ueda C., Sugiyama K., Date M., J. Phys. Soc. Jpn. 54, 1107 (1985). (10.1143/JPSJ.54.1107) / J. Phys. Soc. Jpn. by Ueda C. (1985)
Bier K., Jodl H., J. Chem. Phys. 81, 1192 (1984). (10.1063/1.447794) / J. Chem. Phys. by Bier K. (1984)
The synchrotron radiation experiments were performed at the Spring-8 with the approval of the Japan Synchrotron Radiation Research Institute (JASRI). We thank H. Tanaka for the computer program ENIGMA for the MEM analysis K. Kato for his experimental help at Spring-8 and K. Miura for providing adsorption measurement apparatus. Supported by a grant-in-aid for Scientific Research from the Ministry of Education Culture Science Sports and Technology of Japan.

Dates

Type	When
Created	22 years, 8 months ago (Dec. 19, 2002, 7:05 p.m.)
Deposited	1 year, 7 months ago (Jan. 9, 2024, 10:52 p.m.)
Indexed	1 month, 2 weeks ago (July 11, 2025, 6:26 a.m.)
Issued	22 years, 8 months ago (Dec. 20, 2002)
Published	22 years, 8 months ago (Dec. 20, 2002)
Published Print	22 years, 8 months ago (Dec. 20, 2002)

Funders 0

None

BibTeX

@article{Kitaura_2002, title={Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid}, volume={298}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.1078481}, DOI={10.1126/science.1078481}, number={5602}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Kitaura, Ryo and Kitagawa, Susumu and Kubota, Yoshiki and Kobayashi, Tatsuo C. and Kindo, Koichi and Mita, Yoshimi and Matsuo, Akira and Kobayashi, Michihiro and Chang, Ho-Chol and Ozawa, Tadashi C. and Suzuki, Megumi and Sakata, Makoto and Takata, Masaki}, year={2002}, month=dec, pages={2358–2361} }

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