DOI: 10.1126/science.1058173. Variation of Crystal Dissolution Rate Based on a Dissolution Stepwave Model

Variation of Crystal Dissolution Rate Based on a Dissolution Stepwave Model

10.1126/science.1058173

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science (221)

Abstract

A formulation based on defect-generated dissolution stepwaves of the variation of dissolution rate with the degree of undersaturation is validated by near-atomic-scale observations of surfaces, Monte Carlo simulations, and experimental bulk dissolution rates. The dissolution stepwaves emanating from etch pits provide a train of steps similar to those of a spiral but with different behavior. Their role in accounting for the bulk dissolution rate of crystals provides a conceptual framework for mineral dissolution far from equilibrium. Furthermore, the law extends research to conditions closer to equilibrium and predicts a nonlinear decrease in the rate of dissolution as equilibrium is approached, which has implications for understanding artificial and natural processes involving solid-fluid reactions.

Bibliography

Lasaga, A. C., & Luttge, A. (2001). Variation of Crystal Dissolution Rate Based on a Dissolution Stepwave Model. Science, 291(5512), 2400â2404.

Authors 2

Antonio C. Lasaga (first)
Andreas Luttge (additional)

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We thank R. S. Arvidson and A. Seilacher for thoughtful discussions and M. Hochella and anonymous reviewers for their helpful comments. We also gratefully acknowledge support for this study from the Department of Energy (grant DE-FG02-90ER14153) the NSF (grants EAR-9628238 and EAR-9526794) and the Alexander von Humboldt Foundation.

Dates

Type	When
Created	23 years, 1 month ago (July 27, 2002, 5:52 a.m.)
Deposited	1 year, 7 months ago (Jan. 9, 2024, 4:38 p.m.)
Indexed	19 hours, 47 minutes ago (Aug. 31, 2025, 7:31 p.m.)
Issued	24 years, 5 months ago (March 23, 2001)
Published	24 years, 5 months ago (March 23, 2001)
Published Print	24 years, 5 months ago (March 23, 2001)

Funders 0

None

BibTeX

@article{Lasaga_2001, title={Variation of Crystal Dissolution Rate Based on a Dissolution Stepwave Model}, volume={291}, ISSN={1095-9203}, url={http://dx.doi.org/10.1126/science.1058173}, DOI={10.1126/science.1058173}, number={5512}, journal={Science}, publisher={American Association for the Advancement of Science (AAAS)}, author={Lasaga, Antonio C. and Luttge, Andreas}, year={2001}, month=mar, pages={2400–2404} }

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