DOI: 10.1126/sciadv.1500692. Nearly free electrons in a 5 <i>d</i> delafossite oxide metal

Nearly free electrons in a 5 d delafossite oxide metal

10.1126/sciadv.1500692

Crossref journal-article

American Association for the Advancement of Science (AAAS)

Science Advances (221)

Abstract

Transport and ARPES reveal extremely good metallicity arising from almost free-electron behavior in single-crystal PtCoO 2 .

Bibliography

Kushwaha, P., Sunko, V., Moll, P. J. W., Bawden, L., Riley, J. M., Nandi, N., Rosner, H., Schmidt, M. P., Arnold, F., Hassinger, E., Kim, T. K., Hoesch, M., Mackenzie, A. P., & King, P. D. C. (2015). Nearly free electrons in a 5 d delafossite oxide metal. Science Advances, 1(9).

Authors 14

Pallavi Kushwaha (first)
Veronika Sunko (additional)
Philip J. W. Moll (additional)
Lewis Bawden (additional)
Jonathon M. Riley (additional)
Nabhanila Nandi (additional)
Helge Rosner (additional)
Marcus P. Schmidt (additional)
Frank Arnold (additional)
Elena Hassinger (additional)
Timur K. Kim (additional)
Moritz Hoesch (additional)
Andrew P. Mackenzie (additional)
Phil D. C. King (additional)

References 49 Referenced 66

10.1021/ic50098a011
10.1021/ic50098a012
10.1021/ic50098a013
10.1016/j.tsf.2005.08.316
10.1103/PhysRevB.76.085110
10.1103/PhysRevLett.100.077201
10.1063/1.1355673
10.1103/PhysRevB.79.104424
10.1103/PhysRevLett.105.137201
10.1103/PhysRevLett.111.176405
10.1103/PhysRevB.89.104408
10.1103/PhysRevB.92.014425
10.1103/PhysRevB.90.020401
10.1021/cm703404e
10.1021/cm980079v
10.1103/PhysRevB.80.035116
10.1103/PhysRevB.80.073104
10.1103/PhysRevLett.109.116401
10.1103/PhysRevLett.111.056601
N. Kikugawa P. Goswami A. Kiswandhi E. S. Choi D. Graf R. E. Baumbach J. S. Brooks K. Sugii Y. Iida M. Nishio S. Uji T. Terashima P. M. C. Rourke N. E. Hussey H. Takatsu S. Yonezawa Y. Maeno L. Balicas Realization of the axial anomaly in a quasi-two-dimensional metal. arXiv:1412.5168
10.1103/PhysRevB.92.075205
R. D. Shannon Electrically conductive platinum cobalt oxides. U.S. Patent 3 514 414 (1970).
10.1016/S0022-0248(96)00847-0
10.1143/JPSJ.76.104701
P. Kushwaha C. Geibel M. P. Schmidt A. P. Mackenzie et al . to be published.
10.1038/nmat2795
10.1103/PhysRevB.10.2190
10.1016/0375-9601(68)90126-6
C. M. Hurd The Hall Effect in Metals and Alloys (Springer Boston MA 1972). (10.1007/978-1-4757-0465-5)
10.1038/nphys3105
10.1103/PhysRevLett.102.256404
10.1103/PhysRevLett.104.176601
F. Arnold E. Hassinger et al . to be published.
10.1103/PhysRevB.88.125109
10.1038/srep03680
10.1103/PhysRevLett.113.256402
10.1103/PhysRevLett.114.016401
10.1016/S0921-4526(97)00496-1
10.1103/PhysRevB.2.4813
10.1103/PhysRevLett.85.5194
10.1103/PhysRevLett.96.246402
10.1103/PhysRevLett.101.076402
10.1103/PhysRevB.87.241106
10.1103/PhysRevB.59.1743
10.1103/PhysRevB.60.14035
10.1103/PhysRevLett.77.3865
H. Eschrig M. Richter I. Opahle Relativistic solid state calculations in Relativistic Electronic Structure Theory ( Part II Applications) P. Schwerdtfeger Ed. (Elsevier Amsterdam 2004) pp. 723–776. (10.1016/S1380-7323(04)80039-6)
10.1016/S0022-4596(03)00274-3
10.1103/PhysRevB.43.193

Dates

Type	When
Created	9 years, 10 months ago (Oct. 24, 2015, 8:25 a.m.)
Deposited	1 year, 7 months ago (Jan. 9, 2024, 11:01 a.m.)
Indexed	1 month ago (Aug. 6, 2025, 8:19 a.m.)
Issued	9 years, 11 months ago (Oct. 2, 2015)
Published	9 years, 11 months ago (Oct. 2, 2015)
Published Print	9 years, 11 months ago (Oct. 2, 2015)

Funders 2

Engineering and Physical Sciences Research Council 10.13039/501100000266
Region: Europe
gov (National government)
Labels4
1. UKRI Engineering and Physical Sciences Research Council
2. Engineering and Physical Sciences Research Council - UKRI
3. Engineering & Physical Sciences Research Council
4. EPSRC
Awards2
1. ID0EAHCI2804
2. EP/I031014/1
Royal Society 10.13039/501100000288
Region: Europe
pri (Associations and societies (private and public))
Labels1
1. The Royal Society
Awards2
1. ID0E6NCI2805
2. UF120096

BibTeX

@article{Kushwaha_2015, title={Nearly free electrons in a 5 d delafossite oxide metal}, volume={1}, ISSN={2375-2548}, url={http://dx.doi.org/10.1126/sciadv.1500692}, DOI={10.1126/sciadv.1500692}, number={9}, journal={Science Advances}, publisher={American Association for the Advancement of Science (AAAS)}, author={Kushwaha, Pallavi and Sunko, Veronika and Moll, Philip J. W. and Bawden, Lewis and Riley, Jonathon M. and Nandi, Nabhanila and Rosner, Helge and Schmidt, Marcus P. and Arnold, Frank and Hassinger, Elena and Kim, Timur K. and Hoesch, Moritz and Mackenzie, Andrew P. and King, Phil D. C.}, year={2015}, month=oct }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        6
      ]
    ],
    "date-time": "2025-08-06T12:19:01Z",
    "timestamp": 1754482741681,
    "version": "3.41.2"
  },
  "reference-count": 49,
  "publisher": "American Association for the Advancement of Science (AAAS)",
  "issue": "9",
  "funder": [
    {
      "DOI": "10.13039/501100000266",
      "name": "Engineering and Physical Sciences Research Council",
      "doi-asserted-by": "publisher",
      "award": [
        "ID0EAHCI2804",
        "EP/I031014/1"
      ],
      "id": [
        {
          "id": "10.13039/501100000266",
          "id-type": "DOI",
          "asserted-by": "publisher"
        }
      ]
    },
    {
      "DOI": "10.13039/501100000288",
      "name": "Royal Society",
      "doi-asserted-by": "publisher",
      "award": [
        "ID0E6NCI2805",
        "UF120096"
      ],
      "id": [
        {
          "id": "10.13039/501100000288",
          "id-type": "DOI",
          "asserted-by": "publisher"
        }
      ]
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2015,
        10,
        2
      ]
    ]
  },
  "abstract": "<jats:p>\n            Transport and ARPES reveal extremely good metallicity arising from almost free-electron behavior in single-crystal PtCoO\n            <jats:sub>2</jats:sub>\n            .\n          </jats:p>",
  "DOI": "10.1126/sciadv.1500692",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2015,
        10,
        24
      ]
    ],
    "date-time": "2015-10-24T12:25:28Z",
    "timestamp": 1445689528000
  },
  "source": "Crossref",
  "is-referenced-by-count": 66,
  "title": "Nearly free electrons in a 5\n            <i>d</i>\n            delafossite oxide metal",
  "prefix": "10.1126",
  "volume": "1",
  "author": [
    {
      "ORCID": "https://orcid.org/0000-0002-6323-3384",
      "authenticated-orcid": false,
      "given": "Pallavi",
      "family": "Kushwaha",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        }
      ]
    },
    {
      "given": "Veronika",
      "family": "Sunko",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        },
        {
          "name": "Scottish Universities Physics Alliance, School of Physics and Astronomy, University of St. Andrews, St. Andrews, Fife KY16 9SS, UK."
        }
      ]
    },
    {
      "given": "Philip J. W.",
      "family": "Moll",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratory for Solid State Physics, ETH Zurich, CH-8093 Zurich,  Switzerland."
        }
      ]
    },
    {
      "ORCID": "https://orcid.org/0000-0002-4118-8041",
      "authenticated-orcid": false,
      "given": "Lewis",
      "family": "Bawden",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Scottish Universities Physics Alliance, School of Physics and Astronomy, University of St. Andrews, St. Andrews, Fife KY16 9SS, UK."
        }
      ]
    },
    {
      "given": "Jonathon M.",
      "family": "Riley",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Scottish Universities Physics Alliance, School of Physics and Astronomy, University of St. Andrews, St. Andrews, Fife KY16 9SS, UK."
        },
        {
          "name": "Diamond Light Source, Harwell Campus, Didcot, Oxfordshire OX11 0DE, UK."
        }
      ]
    },
    {
      "given": "Nabhanila",
      "family": "Nandi",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        }
      ]
    },
    {
      "given": "Helge",
      "family": "Rosner",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        }
      ]
    },
    {
      "given": "Marcus P.",
      "family": "Schmidt",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        }
      ]
    },
    {
      "given": "Frank",
      "family": "Arnold",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        }
      ]
    },
    {
      "given": "Elena",
      "family": "Hassinger",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        }
      ]
    },
    {
      "given": "Timur K.",
      "family": "Kim",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Diamond Light Source, Harwell Campus, Didcot, Oxfordshire OX11 0DE, UK."
        }
      ]
    },
    {
      "given": "Moritz",
      "family": "Hoesch",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Diamond Light Source, Harwell Campus, Didcot, Oxfordshire OX11 0DE, UK."
        }
      ]
    },
    {
      "ORCID": "https://orcid.org/0000-0001-8000-4949",
      "authenticated-orcid": false,
      "given": "Andrew P.",
      "family": "Mackenzie",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Max Planck Institute for Chemical Physics of Solids, N\u00f6thnitzer Stra\u00dfe 40, 01187 Dresden, Germany."
        },
        {
          "name": "Scottish Universities Physics Alliance, School of Physics and Astronomy, University of St. Andrews, St. Andrews, Fife KY16 9SS, UK."
        }
      ]
    },
    {
      "ORCID": "https://orcid.org/0000-0002-6523-9034",
      "authenticated-orcid": false,
      "given": "Phil D. C.",
      "family": "King",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Scottish Universities Physics Alliance, School of Physics and Astronomy, University of St. Andrews, St. Andrews, Fife KY16 9SS, UK."
        }
      ]
    }
  ],
  "member": "221",
  "reference": [
    {
      "key": "e_1_3_2_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50098a011"
    },
    {
      "key": "e_1_3_2_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50098a012"
    },
    {
      "key": "e_1_3_2_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic50098a013"
    },
    {
      "key": "e_1_3_2_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.tsf.2005.08.316"
    },
    {
      "key": "e_1_3_2_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.76.085110"
    },
    {
      "key": "e_1_3_2_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.100.077201"
    },
    {
      "key": "e_1_3_2_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1355673"
    },
    {
      "key": "e_1_3_2_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.79.104424"
    },
    {
      "key": "e_1_3_2_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.105.137201"
    },
    {
      "key": "e_1_3_2_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.111.176405"
    },
    {
      "key": "e_1_3_2_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.89.104408"
    },
    {
      "key": "e_1_3_2_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.92.014425"
    },
    {
      "key": "e_1_3_2_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.90.020401"
    },
    {
      "key": "e_1_3_2_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cm703404e"
    },
    {
      "key": "e_1_3_2_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cm980079v"
    },
    {
      "key": "e_1_3_2_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.80.035116"
    },
    {
      "key": "e_1_3_2_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.80.073104"
    },
    {
      "key": "e_1_3_2_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.109.116401"
    },
    {
      "key": "e_1_3_2_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.111.056601"
    },
    {
      "key": "e_1_3_2_21_2",
      "unstructured": "N. Kikugawa P. Goswami A. Kiswandhi E. S. Choi D. Graf R. E. Baumbach J. S. Brooks K. Sugii Y. Iida M. Nishio S. Uji T. Terashima P. M. C. Rourke N. E. Hussey H. Takatsu S. Yonezawa Y. Maeno L. Balicas Realization of the axial anomaly in a quasi-two-dimensional metal. arXiv:1412.5168"
    },
    {
      "key": "e_1_3_2_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.92.075205"
    },
    {
      "key": "e_1_3_2_23_2",
      "unstructured": "R. D. Shannon Electrically conductive platinum cobalt oxides. U.S. Patent 3 514 414 (1970)."
    },
    {
      "key": "e_1_3_2_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-0248(96)00847-0"
    },
    {
      "key": "e_1_3_2_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1143/JPSJ.76.104701"
    },
    {
      "key": "e_1_3_2_26_2",
      "unstructured": "P. Kushwaha C. Geibel M. P. Schmidt A. P. Mackenzie et al . to be published."
    },
    {
      "key": "e_1_3_2_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nmat2795"
    },
    {
      "key": "e_1_3_2_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.10.2190"
    },
    {
      "key": "e_1_3_2_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0375-9601(68)90126-6"
    },
    {
      "key": "e_1_3_2_30_2",
      "doi-asserted-by": "crossref",
      "unstructured": "C. M. Hurd The Hall Effect in Metals and Alloys (Springer Boston MA 1972).",
      "DOI": "10.1007/978-1-4757-0465-5"
    },
    {
      "key": "e_1_3_2_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nphys3105"
    },
    {
      "key": "e_1_3_2_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.102.256404"
    },
    {
      "key": "e_1_3_2_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.104.176601"
    },
    {
      "key": "e_1_3_2_34_2",
      "unstructured": "F. Arnold E. Hassinger et al . to be published."
    },
    {
      "key": "e_1_3_2_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.88.125109"
    },
    {
      "key": "e_1_3_2_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/srep03680"
    },
    {
      "key": "e_1_3_2_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.113.256402"
    },
    {
      "key": "e_1_3_2_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.114.016401"
    },
    {
      "key": "e_1_3_2_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0921-4526(97)00496-1"
    },
    {
      "key": "e_1_3_2_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.2.4813"
    },
    {
      "key": "e_1_3_2_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.85.5194"
    },
    {
      "key": "e_1_3_2_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.96.246402"
    },
    {
      "key": "e_1_3_2_43_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.101.076402"
    },
    {
      "key": "e_1_3_2_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.87.241106"
    },
    {
      "key": "e_1_3_2_45_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.59.1743"
    },
    {
      "key": "e_1_3_2_46_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.60.14035"
    },
    {
      "key": "e_1_3_2_47_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.77.3865"
    },
    {
      "key": "e_1_3_2_48_2",
      "doi-asserted-by": "crossref",
      "unstructured": "H. Eschrig M. Richter I. Opahle Relativistic solid state calculations in Relativistic Electronic Structure Theory ( Part II Applications) P. Schwerdtfeger Ed. (Elsevier Amsterdam 2004) pp. 723\u2013776.",
      "DOI": "10.1016/S1380-7323(04)80039-6"
    },
    {
      "key": "e_1_3_2_49_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-4596(03)00274-3"
    },
    {
      "key": "e_1_3_2_50_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.43.193"
    }
  ],
  "container-title": "Science Advances",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://www.science.org/doi/pdf/10.1126/sciadv.1500692",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        1,
        9
      ]
    ],
    "date-time": "2024-01-09T16:01:32Z",
    "timestamp": 1704816092000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://www.science.org/doi/10.1126/sciadv.1500692"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2015,
        10,
        2
      ]
    ]
  },
  "references-count": 49,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          2015,
          10,
          2
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1126/sciadv.1500692"
  ],
  "URL": "http://dx.doi.org/10.1126/sciadv.1500692",
  "relation": {},
  "ISSN": [
    "2375-2548"
  ],
  "subject": [],
  "container-title-short": "Sci. Adv.",
  "published": {
    "date-parts": [
      [
        2015,
        10,
        2
      ]
    ]
  },
  "article-number": "e1500692"
}