DOI: 10.1116/1.581241. Quantitative uses of the x-ray photoelectron spectroscopy valence band region in the analysis of polymer blends

Quantitative uses of the x-ray photoelectron spectroscopy valence band region in the analysis of polymer blends

10.1116/1.581241

Crossref journal-article

American Vacuum Society

Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films (20)

Abstract

Valence band spectra from similar polymers frequently show significant differences in appearance. Recent improvements in x-ray photoelectron spectroscopy instrumentation allow for valence band (VB) spectra with good signal to noise to be rapidly acquired. This study utilizes the VB region for the quantitative determination of the surface composition of several binary polymer systems using multiple linear regression. The systems evaluated include: poly(vinyl chloride)/poly(methylmethacrylate) blends which phase separate, chemically derivatized poly(vinyl methyl ketone), miscible polybutylmethacrylate isomers used in a study of liquid crystal alignment, and acrylate copolymers whose surface composition has been quantified using time-of-flight secondary ion mass spectrometry. For systems in which comparisons to core level spectra are possible, good agreement is found between quantification of core level and valence band spectra.

Bibliography

Thomas, E. A., & Fulghum, J. E. (1998). Quantitative uses of the x-ray photoelectron spectroscopy valence band region in the analysis of polymer blends. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 16(3), 1106â1111.

Authors 2

Elizabeth A. Thomas (first)
Julia E. Fulghum (additional)

References 15 Referenced 23

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{'key': '2023080823234441200_r2', 'first-page': '267', 'volume': '12', 'year': '1985', 'journal-title': 'CRC Crit. Rev. Solid State Mater. Sci.'} / CRC Crit. Rev. Solid State Mater. Sci. (1985)
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Dates

Type	When
Created	23 years ago (July 27, 2002, 5:17 a.m.)
Deposited	2 years ago (Aug. 8, 2023, 7:24 p.m.)
Indexed	1 year, 9 months ago (Nov. 19, 2023, 9:18 a.m.)
Issued	27 years, 3 months ago (May 1, 1998)
Published	27 years, 3 months ago (May 1, 1998)
Published Print	27 years, 3 months ago (May 1, 1998)

Funders 0

None

BibTeX

@article{Thomas_1998, title={Quantitative uses of the x-ray photoelectron spectroscopy valence band region in the analysis of polymer blends}, volume={16}, ISSN={1520-8559}, url={http://dx.doi.org/10.1116/1.581241}, DOI={10.1116/1.581241}, number={3}, journal={Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films}, publisher={American Vacuum Society}, author={Thomas, Elizabeth A. and Fulghum, Julia E.}, year={1998}, month=may, pages={1106–1111} }

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