DOI: 10.1111/j.1365-2818.1995.tb03652.x. Electron energy‐loss near‐edge structure of internal interfaces by spatial difference spectroscopy

Electron energy‐loss near‐edge structure of internal interfaces by spatial difference spectroscopy

10.1111/j.1365-2818.1995.tb03652.x

Crossref journal-article

Wiley

Journal of Microscopy (311)

Abstract

SUMMARYInternal interfaces determine the macroscopic mechanical and electronic properties of materials. Their investigation is therefore essential for an understanding of the relationship between microstructure and the materials properties. Besides the atomic structure, the bonding and electronic structure on an atomic scale are of interest. This information is contained in the interface‐sensitive component of the electron energy‐loss near‐edge structure (ELNES). It can be extracted by the spatial difference method. Such spectra have already been interpreted with respect to the bonding and the local atomic environment of the atoms at the interface. Here we assess critically the application of the spatial difference for the investigation of internal interfaces. The method is subjective because a suitable scaling factor has to be chosen. As a guideline we propose to minimize the number of turning points in the difference spectrum. With this hypothesis we successfully determine the ELNES arising from atoms at two internal interfaces between a metal and a ceramic. This reveals qualitatively which type of bonding is present at the interface and quantitatively how many atoms are involved in it.

Bibliography

MÃLLEJANS, H., & BRULEY, J. (1995). Electron energyâloss nearâedge structure of internal interfaces by spatial difference spectroscopy. Journal of Microscopy, 180(1), 12â21. Portico.

Authors 2

H. MÜLLEJANS (first)
J. BRULEY (additional)

References 40 Referenced 40

10.1038/366727a0
10.1103/PhysRevB.47.6898
10.1038/298635a0
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{'key': 'e_1_2_1_10_1', 'article-title': 'Modelling the bonding at metal‐ceramic interfaces using PEELS in the S/TEM', 'author': 'Brydson R.', 'year': '1994', 'journal-title': 'Ultramicroscopy'} / Ultramicroscopy / Modelling the bonding at metal‐ceramic interfaces using PEELS in the S/TEM by Brydson R. (1994)
{'key': 'e_1_2_1_11_1', 'first-page': '263', 'volume-title': 'Metal‐ceramic interface characterisation by parallel electron energy loss spectroscopy (PEELS) and high resolution electron microscopy (HREM)', 'author': 'Brydson R.', 'year': '1994'} / Metal‐ceramic interface characterisation by parallel electron energy loss spectroscopy (PEELS) and high resolution electron microscopy (HREM) by Brydson R. (1994)
10.1111/j.1365-2818.1995.tb03568.x
{'key': 'e_1_2_1_13_1', 'first-page': '131', 'volume-title': 'Transmission Electron Energy Loss Spectrometry in Materials Science', 'author': 'Brydson R.', 'year': '1992'} / Transmission Electron Energy Loss Spectrometry in Materials Science by Brydson R. (1992)
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{'key': 'e_1_2_1_17_1', 'article-title': 'Analysing line scan EELS data with neural pattern recognition', 'author': 'Gatts C.', 'year': '1994', 'journal-title': 'Ultramicroscopy'} / Ultramicroscopy / Analysing line scan EELS data with neural pattern recognition by Gatts C. (1994)
{'key': 'e_1_2_1_18_1', 'first-page': '491', 'volume-title': 'Using artificial neural networks for pattern recognition in HRTEM', 'author': 'Gatts C.', 'year': '1994'} / Using artificial neural networks for pattern recognition in HRTEM by Gatts C. (1994)
{'key': 'e_1_2_1_19_1', 'first-page': '745', 'volume-title': 'Analysis of near‐edge structure component at interfaces and grain boundaries through artificial neural networks', 'author': 'Gatts C.', 'year': '1994'} / Analysis of near‐edge structure component at interfaces and grain boundaries through artificial neural networks by Gatts C. (1994)
{'key': 'e_1_2_1_20_1', 'volume-title': 'Electron Microscopy of Thin Crystals.', 'author': 'Hirsch P.', 'year': '1977'} / Electron Microscopy of Thin Crystals. by Hirsch P. (1977)
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{'key': 'e_1_2_1_34_1', 'article-title': 'Strength and fracture toughness of aluminium/alumina composites with interpenetrating networks', 'author': 'Prielipp H.', 'year': '1994', 'journal-title': 'J. Mater. Sci. Eng.'} / J. Mater. Sci. Eng. / Strength and fracture toughness of aluminium/alumina composites with interpenetrating networks by Prielipp H. (1994)
{'key': 'e_1_2_1_35_1', 'first-page': '107', 'volume-title': 'Transmission Electron Energy Loss Spectrometry in Materials Science', 'author': 'Rez P.', 'year': '1992'} / Transmission Electron Energy Loss Spectrometry in Materials Science by Rez P. (1992)
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{'key': 'e_1_2_1_37_1', 'first-page': '672', 'volume-title': 'Proceedings of Fifty‐Second Annual Meeting of the Microscopy Society of America', 'author': 'Schumann E.', 'year': '1994'} / Proceedings of Fifty‐Second Annual Meeting of the Microscopy Society of America by Schumann E. (1994)
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{'key': 'e_1_2_1_41_1', 'first-page': '241', 'volume-title': 'Transmission Electron Energy Loss Spectrometry in Materials Science', 'author': 'Zaluzec N.J.', 'year': '1992'} / Transmission Electron Energy Loss Spectrometry in Materials Science by Zaluzec N.J. (1992)

Dates

Type	When
Created	14 years ago (Aug. 2, 2011, 10:23 a.m.)
Deposited	1 year, 9 months ago (Oct. 27, 2023, 12:59 a.m.)
Indexed	2 months, 4 weeks ago (May 27, 2025, 11:04 a.m.)
Issued	29 years, 10 months ago (Oct. 1, 1995)
Published	29 years, 10 months ago (Oct. 1, 1995)
Published Online	14 years ago (Aug. 2, 2011)
Published Print	29 years, 10 months ago (Oct. 1, 1995)

Funders 0

None

BibTeX

@article{M_LLEJANS_1995, title={Electron energy‐loss near‐edge structure of internal interfaces by spatial difference spectroscopy}, volume={180}, ISSN={1365-2818}, url={http://dx.doi.org/10.1111/j.1365-2818.1995.tb03652.x}, DOI={10.1111/j.1365-2818.1995.tb03652.x}, number={1}, journal={Journal of Microscopy}, publisher={Wiley}, author={MÜLLEJANS, H. and BRULEY, J.}, year={1995}, month=oct, pages={12–21} }

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