DOI: 10.1111/j.1151-2916.2001.tb00968.x. Chemical Expansivity of Electrochemical Ceramics

Chemical Expansivity of Electrochemical Ceramics

10.1111/j.1151-2916.2001.tb00968.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

To better understand thermal strain in electrochemical ceramics, the temperature and oxidation‐state dependence of lattice volume in La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) were measured. Large values in the apparent thermal expansion coefficient at high temperature (>50 ppm/°C) were caused by changes in oxygen content, not increases in thermal expansivity. This material can be described using an improved thermodynamic formalism that incorporates a new physical property, the chemical expansivity. Our approach opens new avenues for modeling stress and strain in materials, probing defect structure, and analyzing transport and kinetic properties.

Bibliography

Adler, S. B. (2001). Chemical Expansivity of Electrochemical Ceramics. Journal of the American Ceramic Society, 84(9), 2117â2119. Portico.

Authors 1

Stuart B. Adler (first)

References 22 Referenced 273

{'issue': '1', 'key': 'e_1_2_1_2_2', 'first-page': '1', 'article-title': 'Stress in Alkali Earth Doped Lanthanum Chromites from Oxygen Potential Gradients', 'volume': '95', 'author': 'Montross C. S.', 'year': '1996', 'journal-title': 'Br. Ceram. Trans.'} / Br. Ceram. Trans. / Stress in Alkali Earth Doped Lanthanum Chromites from Oxygen Potential Gradients by Montross C. S. (1996)
10.1016/S0167-2738(99)00331-8
10.1016/0167-2738(83)90122-4
10.1016/0167-2738(94)00245-N
10.1016/0167-2738(94)00244-M
10.1557/JMR.1993.3158
10.1016/S0167-2738(96)00440-7
10.1016/0022-4596(85)90243-9
10.1103/PhysRevLett.77.2989
M. H. R.Lankhorst “Thermodynamic and Transport Properties of Mixed Ionic and Electronically Conducting Perovskite‐Type Oxides”;Ph.D. Thesis. University of Twente Enschede the Netherlands 1997.
10.1149/1.1837531
10.1016/0167-2738(94)90145-7
10.1016/S0167-2738(97)00259-2
10.1002/aic.690431319
S. J.Benson D.Waller J. A.Lane andJ. A.Kilner Imperial College London U.K.;private communication.
{'key': 'e_1_2_1_17_2', 'first-page': '38', 'volume-title': 'Thermodynamics', 'author': 'Guggenheim E. A.', 'year': '1967'} / Thermodynamics by Guggenheim E. A. (1967)
{'key': 'e_1_2_1_18_2', 'first-page': '5', 'volume-title': 'Thermodynamics of Crystals', 'author': 'Wallace D. C.', 'year': '1972'} / Thermodynamics of Crystals by Wallace D. C. (1972)
10.2320/matertrans1989.30.789
J. E.Ten Elshof “Oxygen Separation with Mixed‐Conducting Perovskite Membranes”;Ph.D. Thesis. University of Twente Enschede The Netherlands 1997.
10.1107/S0567740870003576
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10.1021/ja00081a031

Dates

Type	When
Created	15 years, 1 month ago (July 24, 2010, 2:24 a.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 9:18 p.m.)
Indexed	2 weeks, 6 days ago (Aug. 5, 2025, 8:33 a.m.)
Issued	23 years, 11 months ago (Sept. 1, 2001)
Published	23 years, 11 months ago (Sept. 1, 2001)
Published Online	20 years, 8 months ago (Dec. 20, 2004)
Published Print	23 years, 11 months ago (Sept. 1, 2001)

Funders 0

None

BibTeX

@article{Adler_2001, title={Chemical Expansivity of Electrochemical Ceramics}, volume={84}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.2001.tb00968.x}, DOI={10.1111/j.1151-2916.2001.tb00968.x}, number={9}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Adler, Stuart B.}, year={2001}, month=sep, pages={2117–2119} }

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