DOI: 10.1111/j.1151-2916.2001.tb00826.x. Pressure‐Induced Phase Transformation of Controlled‐Porosity Pb(Zr0.95Ti0.05)O3 Ceramics

Pressure‐Induced Phase Transformation of Controlled‐Porosity Pb(Zr0.95Ti0.05)O3 Ceramics

10.1111/j.1151-2916.2001.tb00826.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

Chemically prepared Pb(Zr0.95Ti0.05)O3 (PZT 95/5) ceramics were fabricated with a range of different porosity levels, while grain size was held constant, by systematic additions of added organic pore former (Avicel). Use of Avicel in amounts ranging from 0 to 4.0 wt% resulted in fired ceramic densities that ranged from 97.3% to 82.3%. Hydrostatic‐pressure‐induced ferroelectric (FE) to antiferroelectric (AFE) phase transformations were substantially more diffuse and occurred at lower hydrostatic pressures with increasing porosity. An ∼12 MPa decrease in hydrostatic transformation pressure per volume percent added porosity was observed. The decrease in transformation pressure with decreasing density was quantitatively consistent with the calculated macroscopic stress required to achieve a specific volumetric macrostrain (0.40%). This strain was equivalent to experimentally measured macrostrain for FE‐to‐AFE transformation. The macroscopic stress levels were calculated using measured bulk modulus values that decreased from 84 to 46 GPa as density decreased from 97.3% to 82.3%. Good agreement between calculated and measured values of FE‐to‐AFE transformation stress was obtained for ceramics fired at 1275° and 1345°C.

Bibliography

Tuttle, B. A., Yang, P., Gieske, J. H., Voigt, J. A., Scofield, T. W., Zeuch, D. H., & Olson, W. R. (2001). PressureâInduced Phase Transformation of ControlledâPorosity Pb(Zr0.95Ti0.05)O3 Ceramics. Journal of the American Ceramic Society, 84(6), 1260â1264. Portico.

Authors 7

Bruce A. Tuttle (first)
Pin Yang (additional)
John H. Gieske (additional)
James A. Voigt (additional)
Timothy W. Scofield (additional)
David H. Zeuch (additional)
Walter R. Olson (additional)

References 13 Referenced 55

10.1016/0022-3697(78)90090-2
D. H.Zeuch S. T.Montgomery L. W.Carlson andJ. M.Grazier “Failure Surfaces and Related Mechanical Properties for Poled and Unpoled PZT 95/5–2Nb Ceramic “Sandia Report SAND99‐0635 Sandia National Laboratories Albuquerque NM 1999 p.29. (10.2172/5895)
D. H.Zeuch S. T.Montgomery andJ. D.Keck “Further Observations on the Effects of Nonhydrostatic Compression on the FR to AO Polymorphic Phase Transformation in Niobium‐Doped Lead Zirconate Titanate Ceramic “J. Mater. Res. 1322–27(1994). (10.1557/JMR.1994.1322)
10.1557/JMR.1999.0245
L. J.StorzandR. H.Dungan “A Study of the Electrical Mechanical and Microstructural Properties of 95/5 PZT as a Function of Pore Former Type and Concentration “Sandia Report SAND85‐1612 Sandia National Laboratories Albuquerque NM 1985.
10.1111/j.1151-2916.1985.tb11518.x
10.1111/j.1151-2916.1956.tb15608.x
10.1007/BF01184983
{'key': 'e_1_2_1_10_2', 'first-page': '55', 'volume-title': 'Proceedings of the 9th U.S. and Japan Seminar on Dielectric and Piezoelectric Ceramics', 'author': 'Tuttle B. A.', 'year': '1999'} / Proceedings of the 9th U.S. and Japan Seminar on Dielectric and Piezoelectric Ceramics by Tuttle B. A. (1999)
10.1080/00150199908016457
J. A.Voigt D. L.Sipola B. A.Tuttle andM.Anderson “Nonaqueous Solution Synthesis Process for Preparing Oxide Powders of Lead Zirconate Titanate and Related Materials “U.S. Pat. No. 5 908 802 June 1 1999.
{'key': 'e_1_2_1_13_2', 'first-page': '213', 'volume-title': 'Solid State Physics', 'author': 'Huntignton H. B.', 'year': '1958'} / Solid State Physics by Huntignton H. B. (1958)
10.1063/1.1661372

Dates

Type	When
Created	15 years, 1 month ago (July 24, 2010, 7:53 a.m.)
Deposited	1 year, 9 months ago (Nov. 23, 2023, 2:38 a.m.)
Indexed	1 year ago (Aug. 19, 2024, 1:48 p.m.)
Issued	24 years, 2 months ago (June 1, 2001)
Published	24 years, 2 months ago (June 1, 2001)
Published Online	20 years, 8 months ago (Dec. 20, 2004)
Published Print	24 years, 2 months ago (June 1, 2001)

Funders 0

None

BibTeX

@article{Tuttle_2001, title={Pressure‐Induced Phase Transformation of Controlled‐Porosity Pb(Zr0.95Ti0.05)O3 Ceramics}, volume={84}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.2001.tb00826.x}, DOI={10.1111/j.1151-2916.2001.tb00826.x}, number={6}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Tuttle, Bruce A. and Yang, Pin and Gieske, John H. and Voigt, James A. and Scofield, Timothy W. and Zeuch, David H. and Olson, Walter R.}, year={2001}, month=jun, pages={1260–1264} }

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