DOI: 10.1111/j.1151-2916.1998.tb02313.x. Nonisothermal Reaction Kinetics of SrNb2O6 and BaNb2O6 for the Formation of SrxBa1−xNb2O6

Nonisothermal Reaction Kinetics of SrNb2O6 and BaNb2O6 for the Formation of SrxBa1−xNb2O6

10.1111/j.1151-2916.1998.tb02313.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

The solid‐state reaction of SrNb2O6 and BaNb2O6 to form SrxBa1−xNb2O6(SBN) at different temperatures and heating rates was investigated. The reaction kinetics were analyzed by X‐ray diffractometry for quenched samples, and the internal‐standard method was applied to quantify the extent of the reaction. A nonisothermal kinetic empirical model was proposed to evaluate the activation energy and rate constant of SBN with different Sr:Ba ratios. It was found that the kinetic form would change above and below a transition at a reaction fraction of ∼60%, which might be due to the change of the frequency factor. It was also verified that the model that was presented was more favorable to describe the nonisothermal reaction kinetics of SBN.

Bibliography

Lee, W., & Fang, T. (1998). Nonisothermal Reaction Kinetics of SrNb2O6 and BaNb2O6 for the Formation of SrxBa1âxNb2O6. Journal of the American Ceramic Society, 81(1), 193â199. Portico.

Authors 2

Wen‐Jiung Lee (first)
Tsang‐Tse Fang (additional)

References 29 Referenced 23

10.1063/1.1668176
10.1063/1.1655759
10.1063/1.1657277
10.1063/1.1754944
10.1109/JQE.1987.1073272
10.1007/BF02666152
10.1016/0025-5408(80)90025-2
10.1063/1.1652971
10.1364/JOSAB.3.000274
10.1016/0025-5408(86)90126-1
10.1107/S0365110X60000285
10.1016/0022-0248(67)90038-3
10.1016/0022-3697(81)90104-9
10.1111/j.1151-2916.1991.tb07789.x
10.1007/BF00349882
10.1111/j.1151-2916.1992.tb05615.x
10.1007/BF00776344
{'key': 'e_1_2_1_19_2', 'first-page': '41', 'volume-title': 'Reactions in the Solid State', 'author': 'Brown W. E.', 'year': '1980'} / Reactions in the Solid State by Brown W. E. (1980)
10.1002/zaac.19271630102
{'issue': '12', 'key': 'e_1_2_1_21_2', 'first-page': '1327', 'article-title': 'Concerning the Diffusion Kinetics of Reactions in Spherical Particles', 'volume': '23', 'author': 'Ginstling A. M.', 'year': '1950', 'journal-title': 'J. Appl. Chem. USSR (Engl. Transl.)'} / J. Appl. Chem. USSR (Engl. Transl.) / Concerning the Diffusion Kinetics of Reactions in Spherical Particles by Ginstling A. M. (1950)
{'issue': '4', 'key': 'e_1_2_1_22_2', 'first-page': '309', 'article-title': 'Kinetics of the Oxidation of Metallic Spherules and Powders” (in Fr.)', 'volume': '202', 'author': 'Valensi G.', 'year': '1936', 'journal-title': 'C. R. Hebd. Seances Acad. Sci.'} / C. R. Hebd. Seances Acad. Sci. / Kinetics of the Oxidation of Metallic Spherules and Powders” (in Fr.) by Valensi G. (1936)
10.1063/1.1731812
10.1111/j.1151-2916.1995.tb08406.x
10.1179/cmq.1994.33.2.99
10.1016/0040-6031(80)87031-6
10.1111/j.1151-2916.1984.tb19605.x
10.1016/0040-6031(72)85004-4
{'key': 'e_1_2_1_29_2', 'article-title': 'Densification and Microstructural Development of Reaction Sintering of Strontium Barium and Barium Niobate', 'author': 'Lee W. J.', 'journal-title': 'J. Am. Ceram. Soc.'} / J. Am. Ceram. Soc. / Densification and Microstructural Development of Reaction Sintering of Strontium Barium and Barium Niobate by Lee W. J.
{'key': 'e_1_2_1_30_2', 'first-page': '203', 'article-title': 'Donor Dopant Diffusion into Barium Titanate Ceramics', 'volume': '1979', 'author': 'Fukami T.', 'journal-title': 'Proceedings of the 2nd Meeting on Ferroelectric Materials and Their Applications'} / Proceedings of the 2nd Meeting on Ferroelectric Materials and Their Applications / Donor Dopant Diffusion into Barium Titanate Ceramics by Fukami T.

Dates

Type	When
Created	15 years, 1 month ago (July 24, 2010, 10:42 a.m.)
Deposited	1 year, 9 months ago (Nov. 23, 2023, 9:02 a.m.)
Indexed	1 month, 3 weeks ago (July 7, 2025, 9:07 a.m.)
Issued	27 years, 7 months ago (Jan. 1, 1998)
Published	27 years, 7 months ago (Jan. 1, 1998)
Published Online	20 years, 7 months ago (Jan. 21, 2005)
Published Print	27 years, 7 months ago (Jan. 1, 1998)

Funders 0

None

BibTeX

@article{Lee_1998, title={Nonisothermal Reaction Kinetics of SrNb2O6 and BaNb2O6 for the Formation of SrxBa1−xNb2O6}, volume={81}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1998.tb02313.x}, DOI={10.1111/j.1151-2916.1998.tb02313.x}, number={1}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Lee, Wen‐Jiung and Fang, Tsang‐Tse}, year={1998}, month=jan, pages={193–199} }

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