DOI: 10.1111/j.1151-2916.1994.tb05404.x. Effect of Dopants on Zirconia Stabilization—An X‐ray Absorption Study: III, Charge‐Compensating Dopants

Effect of Dopants on Zirconia Stabilization—An X‐ray Absorption Study: III, Charge‐Compensating Dopants

10.1111/j.1151-2916.1994.tb05404.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

X‐ray absorption spectra at the Zr‐, Y‐, and Nb‐K edges of ZrO2‐YNBO4 solid solutions have been measured at 10 K to determine the local atomic structures. Both Y and Nb cations substitute for Zr in the cation network but maintain rather different local oxygen coordination from Zr. In tetragonal zirconia solid solutions, Y adopts a YO8 structure with a bond length of 2.32 Å. This is the same as the structure found in ZrO2–Y2O3, solid solutions, confirming our previous conclusion that Y is not associated with oxygen vacancies. Nb has an NbO4 structure with a bond length of 1.90 Å. This is shorter than the Zr–O, distance of 2.10 Å. The strong Nb–O coordination increases the bonding disparity between Zr–O layers, thus increasing tetragonality. This is similar to the trend previously established for ZrO2‐GeO2 solid solutions. Severe distortion of neighboring cations around the undersized Nb, similar to that previously found for undersized Fe3+ and Ga3+, is also observed. At higher temperatures, local Y–Nb cation ordering occurs at a concentration below the solubility limit, similar to the Zr–Ge ordering reported previously. This cation ordering mechanism allows the charge‐compensating Y‐Nb pair to stabilize the tetragonal structure but increase tetragonality.

Bibliography

Li, P., Chen, I., & PennerâHahn, J. E. (1994). Effect of Dopants on Zirconia StabilizationâAn Xâray Absorption Study: III, ChargeâCompensating Dopants. Journal of the American Ceramic Society, 77(5), 1289â1295. Portico.

Authors 3

Ping Li (first)
I‐Wei Chen (additional)
James E. Penner‐Hahn (additional)

References 30 Referenced 163

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Dates

Type	When
Created	20 years, 5 months ago (March 8, 2005, 11:06 a.m.)
Deposited	1 year, 9 months ago (Nov. 23, 2023, 12:13 p.m.)
Indexed	4 weeks, 2 days ago (Aug. 6, 2025, 8:22 a.m.)
Issued	31 years, 4 months ago (May 1, 1994)
Published	31 years, 4 months ago (May 1, 1994)
Published Online	20 years, 5 months ago (March 8, 2005)
Published Print	31 years, 4 months ago (May 1, 1994)

Funders 0

None

BibTeX

@article{Li_1994, title={Effect of Dopants on Zirconia Stabilization—An X‐ray Absorption Study: III, Charge‐Compensating Dopants}, volume={77}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1994.tb05404.x}, DOI={10.1111/j.1151-2916.1994.tb05404.x}, number={5}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Li, Ping and Chen, I‐Wei and Penner‐Hahn, James E.}, year={1994}, month=may, pages={1289–1295} }

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  "abstract": "<jats:p>X\u2010ray absorption spectra at the Zr\u2010, Y\u2010, and Nb\u2010<jats:italic>K</jats:italic> edges of ZrO<jats:sub>2</jats:sub>\u2010YNBO<jats:sub>4</jats:sub> solid solutions have been measured at 10 K to determine the local atomic structures. Both Y and Nb cations substitute for Zr in the cation network but maintain rather different local oxygen coordination from Zr. In tetragonal zirconia solid solutions, Y adopts a YO<jats:sub>8</jats:sub> structure with a bond length of 2.32 \u00c5. This is the same as the structure found in ZrO<jats:sub>2</jats:sub>\u2013Y<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, solid solutions, confirming our previous conclusion that Y is not associated with oxygen vacancies. Nb has an NbO<jats:sub>4</jats:sub> structure with a bond length of 1.90 \u00c5. This is shorter than the Zr\u2013O, distance of 2.10 \u00c5. The strong Nb\u2013O coordination increases the bonding disparity between Zr\u2013O layers, thus increasing tetragonality. This is similar to the trend previously established for ZrO<jats:sub>2</jats:sub>\u2010GeO<jats:sub>2</jats:sub> solid solutions. Severe distortion of neighboring cations around the undersized Nb, similar to that previously found for undersized Fe<jats:sup>3+</jats:sup> and Ga<jats:sup>3+</jats:sup>, is also observed. At higher temperatures, local Y\u2013Nb cation ordering occurs at a concentration below the solubility limit, similar to the Zr\u2013Ge ordering reported previously. This cation ordering mechanism allows the charge\u2010compensating Y\u2010Nb pair to stabilize the tetragonal structure but increase tetragonality.</jats:p>",
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