DOI: 10.1111/j.1151-2916.1992.tb05548.x. Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

10.1111/j.1151-2916.1992.tb05548.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

A pure, acicular lead titanate (PbTiO3) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO3 with I4 symmetry, cell parameters of a= 12.358 Å and b= 14.541 Å, and a density of 6.80 g.cm−3. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO3 under hydrothermal conditions have been investigated. The acicular PbTiO3 with I4 symmetry, referred to as the PX phase, can be converted to the perovskite‐type (PE phase) of PbTiO3 at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX‐phase PbTiO3 are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH2)3CH3]4) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.

Bibliography

Cheng, H., Ma, J., Zhao, Z., Qiang, D., Li, Y., & Yao, X. (1992). Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders. Journal of the American Ceramic Society, 75(5), 1123â1128. Portico.

Authors 6

Humin Cheng (first)
Jiming Ma (additional)
Zhenguo Zhao (additional)
Di Qiang (additional)
Yongxiang Li (additional)
Xi Yao (additional)

References 17 Referenced 47

{'issue': '4', 'key': 'e_1_2_1_2_2', 'first-page': '668', 'article-title': '0–3 Piezoelectric Composites Prepared by Coprecipitated PbTiO3 Powder', 'volume': '66', 'author': 'Safari A.', 'year': '1987', 'journal-title': 'Am. Ceram. Soc. Bull.'} / Am. Ceram. Soc. Bull. / 0–3 Piezoelectric Composites Prepared by Coprecipitated PbTiO3 Powder by Safari A. (1987)
{'key': 'e_1_2_1_3_2', 'first-page': '565', 'volume-title': 'Ceramic Powders', 'author': 'Jimenez C. M.', 'year': '1983'} / Ceramic Powders by Jimenez C. M. (1983)
10.1109/ISAF.1986.201150
10.1007/BF00575398
{'key': 'e_1_2_1_6_2', 'first-page': '15', 'volume-title': 'Ultrastructure Processing of Ceramics, Glasses, and Composites', 'author': 'Gurkovich S. R.', 'year': '1984'} / Ultrastructure Processing of Ceramics, Glasses, and Composites by Gurkovich S. R. (1984)
10.1007/BF00559337
{'key': 'e_1_2_1_8_2', 'first-page': '163', 'volume-title': 'Ceramic Transactions, Vol. 1, Ceramic Powder Science II', 'author': 'Suzuki M.', 'year': '1988'} / Ceramic Transactions, Vol. 1, Ceramic Powder Science II by Suzuki M. (1988)
S.Uedaira M.Suzuki H.Yamanoi andH.Tamura “Method for Manufacturing Fine Lead Titanate Powders ” Eur. Pat. Appl. No. EP 186 199 July 2 1986.
10.1246/bcsj.51.1739
{'key': 'e_1_2_1_11_2', 'first-page': '859', 'volume-title': 'Proceedings of 1st International Symposium on Hydrothermal Reactions', 'author': 'Takai K.', 'year': '1983'} / Proceedings of 1st International Symposium on Hydrothermal Reactions by Takai K. (1983)
{'key': 'e_1_2_1_12_2', 'first-page': '154', 'volume-title': 'Ceramic Transactions, Vol. 1, Ceramic Powder Science II', 'author': 'Watson D. J.', 'year': '1988'} / Ceramic Transactions, Vol. 1, Ceramic Powder Science II by Watson D. J. (1988)
{'key': 'e_1_2_1_13_2', 'first-page': '509', 'volume-title': "Proceedings of C‐MRS International '90", 'author': 'Cheng H.', 'year': '1990'} / Proceedings of C‐MRS International '90 by Cheng H. (1990)
10.1016/0025-5408(87)90156-5
{'key': 'e_1_2_1_15_2', 'volume-title': 'Atlas of Electrochemical Equilibria in Aqueous Solutions', 'author': 'Pourbaix M.', 'year': '1974'} / Atlas of Electrochemical Equilibria in Aqueous Solutions by Pourbaix M. (1974)
{'key': 'e_1_2_1_16_2', 'first-page': '323', 'volume-title': 'Applications of Complex Equilibria', 'author': 'Inczedy J.', 'year': '1976'} / Applications of Complex Equilibria by Inczedy J. (1976)
E. P.Stambaugh “Hydrothermal Precipitation of High‐Quality Oxides”; presented at SME‐AIME Fall Meeting St. Louis MO 1977.
{'key': 'e_1_2_1_18_2', 'first-page': '139', 'volume-title': 'Complexes and First‐Row Transition Elements;', 'author': 'Nicholls D.', 'year': '1975'} / Complexes and First‐Row Transition Elements; by Nicholls D. (1975)

Dates

Type	When
Created	20 years, 5 months ago (March 8, 2005, 11:48 a.m.)
Deposited	1 year, 9 months ago (Nov. 23, 2023, 3:52 p.m.)
Indexed	2 months, 1 week ago (June 16, 2025, 9:08 a.m.)
Issued	33 years, 3 months ago (May 1, 1992)
Published	33 years, 3 months ago (May 1, 1992)
Published Online	20 years, 5 months ago (March 8, 2005)
Published Print	33 years, 3 months ago (May 1, 1992)

Funders 0

None

BibTeX

@article{Cheng_1992, title={Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders}, volume={75}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1992.tb05548.x}, DOI={10.1111/j.1151-2916.1992.tb05548.x}, number={5}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Cheng, Humin and Ma, Jiming and Zhao, Zhenguo and Qiang, Di and Li, Yongxiang and Yao, Xi}, year={1992}, month=may, pages={1123–1128} }

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