DOI: 10.1111/j.1151-2916.1991.tb04302.x. Phase Stability and Physical Properties of Cubic and Tetragonal ZrO2 in the System ZrO2–Y2O3

Phase Stability and Physical Properties of Cubic and Tetragonal ZrO2 in the System ZrO2–Y2O3–Ta2O5

10.1111/j.1151-2916.1991.tb04302.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

The cubic (c‐ZrO2) and tetragonal zirconia (t‐ZrO2) phase stability regions in the system ZrO2–Y2O3–Ta2O5 were delineated. The c‐ZrO2 solid solutions are formed with the fluorite structure. The t‐ZrO2 solid solutions having a c/a axial ratio (tetragonality) smaller than 1.0203 display high fracture toughness (5 to 14 MPa · m1/2), and their instability/transformability to monoclinic zirconia (m‐ZrO2) increases with increasing tetragonality. On the other hand, the t‐ZrO2 solid solutions stabilized at room temperature with tetragonality greater than 1.0203 have low toughness values (2 to 5 MPa · m1/2), and their transformability is not related to the tetragonality.

Bibliography

Kim, D., & Tien, T. (1991). Phase Stability and Physical Properties of Cubic and Tetragonal ZrO2 in the System ZrO2âY2O3âTa2O5. Journal of the American Ceramic Society, 74(12), 3061â3065. Portico.

Authors 2

Dae‐Joon Kim (first)
Tseng‐Ying Tien (additional)

References 18 Referenced 98

{'key': 'e_1_2_1_2_2', 'first-page': '665', 'volume-title': 'Fast Ion Transport in Solids', 'author': 'Choudhary C. B.', 'year': '1979'} / Fast Ion Transport in Solids by Choudhary C. B. (1979)
{'key': 'e_1_2_1_3_2', 'first-page': '725', 'volume-title': 'Science of Ceramics', 'author': 'Prietzel S.', 'year': '1980'} / Science of Ceramics by Prietzel S. (1980)
10.1111/j.1151-2916.1990.tb05100.x
10.1016/0022-4596(85)90186-0
10.1111/j.1151-2916.1981.tb10320.x
10.1007/978-3-662-02357-0
{'key': 'e_1_2_1_8_2', 'article-title': 'Powder X‐ray Diffraction Data for Tetragonal Zirconia Solid Solutions in System ZrO2—YTaO4', 'author': 'Kim D.‐J.', 'journal-title': 'Powder Diffr.'} / Powder Diffr. / Powder X‐ray Diffraction Data for Tetragonal Zirconia Solid Solutions in System ZrO2—YTaO4 by Kim D.‐J.
10.1111/j.1151-2916.1989.tb07663.x
10.1107/S0567739476001551
{'key': 'e_1_2_1_11_2', 'first-page': '1649', 'article-title': 'Physicochemical Investigation of the System and Synthesis of Single Crystals of a Series of Niobates', 'volume': '8', 'author': 'Bondar I. A.', 'year': '1972', 'journal-title': 'Inorg. Mater. (Engl. Transl.)'} / Inorg. Mater. (Engl. Transl.) / Physicochemical Investigation of the System and Synthesis of Single Crystals of a Series of Niobates by Bondar I. A. (1972)
D.‐J.Kim “The Effect of Alloying on the Transformability of Y2O3Stabilized Tetragonal ZrO2”;Ph.D. Dissertation. University of Michigan Ann Arbor MI 1988.
10.1007/BF01026344
{'issue': '10', 'key': 'e_1_2_1_14_2', 'first-page': '1382', 'article-title': 'Transformation of Ceria‐Doped Tetragonal Zirconia Polycrystals by Annealing in Water', 'volume': '64', 'author': 'Sato T.', 'year': '1985', 'journal-title': 'Am. Ceram. Soc. Bull.'} / Am. Ceram. Soc. Bull. / Transformation of Ceria‐Doped Tetragonal Zirconia Polycrystals by Annealing in Water by Sato T. (1985)
10.1016/0001-6160(86)90052-0
{'key': 'e_1_2_1_16_2', 'first-page': '161', 'volume-title': 'Proceedings of the 1st European Ceramic Society Conference', 'author': 'Pandolfelli V. C.', 'year': '1820'} / Proceedings of the 1st European Ceramic Society Conference by Pandolfelli V. C. (1820)
10.1016/0584-8539(74)80096-6
10.1063/1.1680227
D.‐J.Kim P. F.Becher andC. R.Hubbard “Effect of Nb2O5Alloying on Aniosotropic Thermal Expansion of 2 mol% Y2O3Stabilized Tetragonal ZrO2”; unpublished work.

Dates

Type	When
Created	20 years, 5 months ago (March 8, 2005, 12:04 p.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 10:41 p.m.)
Indexed	1 month, 2 weeks ago (July 19, 2025, 11:51 p.m.)
Issued	33 years, 9 months ago (Dec. 1, 1991)
Published	33 years, 9 months ago (Dec. 1, 1991)
Published Online	20 years, 5 months ago (March 8, 2005)
Published Print	33 years, 9 months ago (Dec. 1, 1991)

Funders 0

None

BibTeX

@article{Kim_1991, title={Phase Stability and Physical Properties of Cubic and Tetragonal ZrO2 in the System ZrO2–Y2O3–Ta2O5}, volume={74}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1991.tb04302.x}, DOI={10.1111/j.1151-2916.1991.tb04302.x}, number={12}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Kim, Dae‐Joon and Tien, Tseng‐Ying}, year={1991}, month=dec, pages={3061–3065} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        20
      ]
    ],
    "date-time": "2025-07-20T03:51:00Z",
    "timestamp": 1752983460506
  },
  "reference-count": 18,
  "publisher": "Wiley",
  "issue": "12",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2005,
            3,
            8
          ]
        ],
        "date-time": "2005-03-08T00:00:00Z",
        "timestamp": 1110240000000
      },
      "content-version": "vor",
      "delay-in-days": 4846,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1991,
        12
      ]
    ]
  },
  "abstract": "<jats:p>The cubic (<jats:italic>c</jats:italic>\u2010ZrO<jats:sub>2</jats:sub>) and tetragonal zirconia (<jats:italic>t</jats:italic>\u2010ZrO<jats:sub>2</jats:sub>) phase stability regions in the system ZrO<jats:sub>2</jats:sub>\u2013Y<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>\u2013Ta<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> were delineated. The <jats:italic>c</jats:italic>\u2010ZrO<jats:sub>2</jats:sub> solid solutions are formed with the fluorite structure. The <jats:italic>t</jats:italic>\u2010ZrO<jats:sub>2</jats:sub> solid solutions having a <jats:italic>c/a</jats:italic> axial ratio (tetragonality) smaller than 1.0203 display high fracture toughness (5 to 14 MPa \u00b7 m<jats:sup>1/2</jats:sup>), and their instability/transformability to monoclinic zirconia (<jats:italic>m</jats:italic>\u2010ZrO<jats:sub>2</jats:sub>) increases with increasing tetragonality. On the other hand, the <jats:italic>t</jats:italic>\u2010ZrO<jats:sub>2</jats:sub> solid solutions stabilized at room temperature with tetragonality greater than 1.0203 have low toughness values (2 to 5 MPa \u00b7 m<jats:sup>1/2</jats:sup>), and their transformability is not related to the tetragonality.</jats:p>",
  "DOI": "10.1111/j.1151-2916.1991.tb04302.x",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        3,
        8
      ]
    ],
    "date-time": "2005-03-08T17:04:14Z",
    "timestamp": 1110301454000
  },
  "page": "3061-3065",
  "source": "Crossref",
  "is-referenced-by-count": 98,
  "title": "Phase Stability and Physical Properties of Cubic and Tetragonal ZrO<sub>2</sub> in the System ZrO<sub>2</sub>\u2013Y<sub>2</sub>O<sub>3</sub>\u2013Ta<sub>2</sub>O<sub>5</sub>",
  "prefix": "10.1111",
  "volume": "74",
  "author": [
    {
      "given": "Dae\u2010Joon",
      "family": "Kim",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Tseng\u2010Ying",
      "family": "Tien",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2005,
        3,
        8
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "first-page": "665",
      "volume-title": "Fast Ion Transport in Solids",
      "author": "Choudhary C. B.",
      "year": "1979"
    },
    {
      "key": "e_1_2_1_3_2",
      "first-page": "725",
      "volume-title": "Science of Ceramics",
      "author": "Prietzel S.",
      "year": "1980"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1111/j.1151-2916.1990.tb05100.x"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-4596(85)90186-0"
    },
    {
      "key": "e_1_2_1_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1111/j.1151-2916.1981.tb10320.x"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/978-3-662-02357-0"
    },
    {
      "key": "e_1_2_1_8_2",
      "article-title": "Powder X\u2010ray Diffraction Data for Tetragonal Zirconia Solid Solutions in System ZrO2\u2014YTaO4",
      "author": "Kim D.\u2010J.",
      "journal-title": "Powder Diffr."
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1111/j.1151-2916.1989.tb07663.x"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1107/S0567739476001551"
    },
    {
      "key": "e_1_2_1_11_2",
      "first-page": "1649",
      "article-title": "Physicochemical Investigation of the System and Synthesis of Single Crystals of a Series of Niobates",
      "volume": "8",
      "author": "Bondar I. A.",
      "year": "1972",
      "journal-title": "Inorg. Mater. (Engl. Transl.)"
    },
    {
      "key": "e_1_2_1_12_2",
      "unstructured": "D.\u2010J.Kim \u201cThe Effect of Alloying on the Transformability of Y2O3Stabilized Tetragonal ZrO2\u201d;Ph.D. Dissertation. University of Michigan Ann Arbor MI 1988."
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF01026344"
    },
    {
      "issue": "10",
      "key": "e_1_2_1_14_2",
      "first-page": "1382",
      "article-title": "Transformation of Ceria\u2010Doped Tetragonal Zirconia Polycrystals by Annealing in Water",
      "volume": "64",
      "author": "Sato T.",
      "year": "1985",
      "journal-title": "Am. Ceram. Soc. Bull."
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0001-6160(86)90052-0"
    },
    {
      "key": "e_1_2_1_16_2",
      "first-page": "161",
      "volume-title": "Proceedings of the 1st European Ceramic Society Conference",
      "author": "Pandolfelli V. C.",
      "year": "1820"
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0584-8539(74)80096-6"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1680227"
    },
    {
      "key": "e_1_2_1_19_2",
      "unstructured": "D.\u2010J.Kim P. F.Becher andC. R.Hubbard \u201cEffect of Nb2O5Alloying on Aniosotropic Thermal Expansion of 2 mol% Y2O3Stabilized Tetragonal ZrO2\u201d; unpublished work."
    }
  ],
  "container-title": "Journal of the American Ceramic Society",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1111%2Fj.1151-2916.1991.tb04302.x",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "http://onlinelibrary.wiley.com/wol1/doi/10.1111/j.1151-2916.1991.tb04302.x/fullpdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        11,
        23
      ]
    ],
    "date-time": "2023-11-23T03:41:23Z",
    "timestamp": 1700710883000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://ceramics.onlinelibrary.wiley.com/doi/10.1111/j.1151-2916.1991.tb04302.x"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1991,
        12
      ]
    ]
  },
  "references-count": 18,
  "journal-issue": {
    "issue": "12",
    "published-print": {
      "date-parts": [
        [
          1991,
          12
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1111/j.1151-2916.1991.tb04302.x"
  ],
  "URL": "http://dx.doi.org/10.1111/j.1151-2916.1991.tb04302.x",
  "relation": {},
  "ISSN": [
    "0002-7820",
    "1551-2916"
  ],
  "subject": [],
  "container-title-short": "Journal of the American Ceramic Society",
  "published": {
    "date-parts": [
      [
        1991,
        12
      ]
    ]
  }
}