DOI: 10.1111/j.1151-2916.1991.tb04293.x. Thin‐Layer Dielectrics in the Pb[(Mg1/3Nb2/3)1‐xTix]O3 System

Thin‐Layer Dielectrics in the Pb[(Mg1/3Nb2/3)1‐xTix]O3 System

10.1111/j.1151-2916.1991.tb04293.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

Thin layers of Pb[(Mg1/3Nb2/3)1–xTix]O3 (PMNT) were prepared by spin casting alkoxide‐based solutions on platinized Si. The effects of additives, heat treatment, and composition (x= 0 to 0.9) on perovskite phase development, ceramic microstructure, and dielectric properties are reported. Depending upon the processing conditions, ceramic thin layers could be formed in a nonferroelectric pyrochlore phase (A2B2O6) or in a ferroelectric perovskite phase (ABO3). The dimensions of the pyrochlore and perovskite units cells were related and increased with Mg and Nb contents. To minmize pyrochlore formation, the most effective processing method involved rapid heat treatment between successive solution depositions. Phase development and microstructure were also affected by solution additives. Additions of benzoic acid were found to affect the structure in solution and the later organic pyrolysis behavior from thin layers. The effect of composition on the dielectric and ferroelectric properties is also reported.

Bibliography

Francis, L. F., & Payne, D. A. (1991). ThinâLayer Dielectrics in the Pb[(Mg1/3Nb2/3)1âxTix]O3 System. Journal of the American Ceramic Society, 74(12), 3000â3010. Portico.

Authors 2

Lorraine Falter Francis (first)
David A. Payne (additional)

References 30 Referenced 103

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{'key': 'e_1_2_1_14_2', 'first-page': '107', 'article-title': 'Sol—Gel Processing of PbTiO3, PbZrO3, PZT and PLZT', 'volume': '36', 'author': 'Budd K. D.', 'year': '1985', 'journal-title': 'Br. Ceram. Proc.'} / Br. Ceram. Proc. / Sol—Gel Processing of PbTiO3, PbZrO3, PZT and PLZT by Budd K. D. (1985)
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10.1143/JJAP.18.897

Dates

Type	When
Created	20 years, 5 months ago (March 8, 2005, 12:04 p.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 10:40 p.m.)
Indexed	2 months ago (June 24, 2025, 7:28 a.m.)
Issued	33 years, 8 months ago (Dec. 1, 1991)
Published	33 years, 8 months ago (Dec. 1, 1991)
Published Online	20 years, 5 months ago (March 8, 2005)
Published Print	33 years, 8 months ago (Dec. 1, 1991)

Funders 0

None

BibTeX

@article{Francis_1991, title={Thin‐Layer Dielectrics in the Pb[(Mg1/3Nb2/3)1‐xTix]O3 System}, volume={74}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1991.tb04293.x}, DOI={10.1111/j.1151-2916.1991.tb04293.x}, number={12}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Francis, Lorraine Falter and Payne, David A.}, year={1991}, month=dec, pages={3000–3010} }

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