DOI: 10.1111/j.1151-2916.1990.tb06498.x. Polymorphic Phase Transformation of Lead Monoxide and Its Influence on Lead Zirconate Titanate Formation

Polymorphic Phase Transformation of Lead Monoxide and Its Influence on Lead Zirconate Titanate Formation

10.1111/j.1151-2916.1990.tb06498.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

The polymorphic phase transformation of PbO from massicot to litharge phase is easily produced by mechanical force. The transformation is relatively quick by wet ball‐milling. The additions of TiO2 and ZrO2 tend to retard it. A second‐order exponential relation is observed between the fractional conversion and the milling time for pure PbO, PbO‐TiO2, and PbO‐ZrO2‐TiO2 systems with a rutile constituent. This exponential relation is changed into a first‐order logarithmic relation when anatase instead of rutile is used. Although the PbOss phase is observed irrespective of the phase of the PbO in the raw materials, this PbOss peak is more obvious when massicot PbO or anatase TiO2 is used. The formation of PbOss phase is also dependent on the reactivity of the ZrO2, and its presence can affect the formation and piezoelectric properties of PZT ceramics.

Bibliography

Chen, S., Cheng, S., & Wang, C. (1990). Polymorphic Phase Transformation of Lead Monoxide and Its Influence on Lead Zirconate Titanate Formation. Journal of the American Ceramic Society, 73(2), 232â236. Portico.

Authors 3

San‐Yuan Chen (first)
Syh‐Yuh Cheng (additional)
Chien‐Min Wang (additional)

References 22 Referenced 16

10.1080/00150197608241960
G. G.Palmer “Stable Lead Zirconate Titanate ”Rept. No. DA‐121‐520 General Electric Co. Sept. 1974.
{'issue': '1', 'key': 'e_1_2_1_4_2', 'first-page': '32', 'article-title': '“Study of Formation Process of Pb(Ti, Zr)O3 Solid Solution with High Temperature X‐ray Diffractometry and Differential Thermal Analysis,”', 'volume': '10', 'author': 'Mori H.', 'year': '1964', 'journal-title': 'Natl. Tech. Rep.'} / Natl. Tech. Rep. / “Study of Formation Process of Pb(Ti, Zr)O3 Solid Solution with High Temperature X‐ray Diffractometry and Differential Thermal Analysis,” by Mori H. (1964)
10.1111/j.1151-2916.1965.tb14743.x
W. M.Speri “Thermal Analysis of Processes Which Occur During the Calcining of Adulterated and Unadulterated Lead Zirconate–Lead Titanate”;Ph.D. Thesis.Rutgers University New Brunswick NJ 1969.
{'issue': '4', 'key': 'e_1_2_1_7_2', 'first-page': '462', 'article-title': '“Reactivity of Zirconia in Calcining of Lead Zirconate–Lead Titanate Compositions Prepared from Mixed Oxdes,”', 'volume': '59', 'author': 'Venkataramani S.', 'year': '1980', 'journal-title': 'Am. Ceram. Soc. Bull.'} / Am. Ceram. Soc. Bull. / “Reactivity of Zirconia in Calcining of Lead Zirconate–Lead Titanate Compositions Prepared from Mixed Oxdes,” by Venkataramani S. (1980)
10.1111/j.1151-2916.1983.tb10564.x
{'key': 'e_1_2_1_9_2', 'volume-title': 'Lead Chemicals', 'author': 'Greninger D.', 'year': '1974'} / Lead Chemicals by Greninger D. (1974)
10.1016/0022-1902(65)80010-0
10.1016/0022-1902(65)80009-4
10.1111/j.1151-2916.1961.tb13739.x
10.1111/j.1151-2916.1971.tb12284.x
10.1107/S0021889869006856
10.1016/B978-1-4832-8313-5.50012-7
10.1103/RevModPhys.31.646
H. M.Sung; private communications.
10.1109/JRPROC.1961.287860
{'key': 'e_1_2_1_19_2', 'first-page': '37', 'article-title': '“Kinetics of the Thermal Decomposition of Solids,”', 'volume': '4', 'author': 'Jacobs P. W. M.', 'year': '1969', 'journal-title': 'Mater. Sci. Res.'} / Mater. Sci. Res. / “Kinetics of the Thermal Decomposition of Solids,” by Jacobs P. W. M. (1969)
10.1111/j.1151-2916.1965.tb14774.x
{'key': 'e_1_2_1_21_2', 'first-page': '1579', 'article-title': '“Mechanism of Crystal Structure Transformation,”', 'volume': '57', 'author': 'Yoganarasimham S. R.', 'year': '1961', 'journal-title': 'Trans. Faraday Soc.'} / Trans. Faraday Soc. / “Mechanism of Crystal Structure Transformation,” by Yoganarasimham S. R. (1961)
{'key': 'e_1_2_1_22_2', 'volume-title': 'Phase Transformation in Solids, Ch. 6', 'author': 'Buerger M. J.', 'year': '1957'} / Phase Transformation in Solids, Ch. 6 by Buerger M. J. (1957)
10.1111/j.1151-2916.1963.tb11764.x

Dates

Type	When
Created	20 years, 5 months ago (March 8, 2005, 12:50 p.m.)
Deposited	1 year, 8 months ago (Nov. 22, 2023, 5:37 p.m.)
Indexed	1 year, 6 months ago (Feb. 4, 2024, 10:26 a.m.)
Issued	35 years, 6 months ago (Feb. 1, 1990)
Published	35 years, 6 months ago (Feb. 1, 1990)
Published Online	20 years, 5 months ago (March 8, 2005)
Published Print	35 years, 6 months ago (Feb. 1, 1990)

Funders 0

None

BibTeX

@article{Chen_1990, title={Polymorphic Phase Transformation of Lead Monoxide and Its Influence on Lead Zirconate Titanate Formation}, volume={73}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1990.tb06498.x}, DOI={10.1111/j.1151-2916.1990.tb06498.x}, number={2}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Chen, San‐Yuan and Cheng, Syh‐Yuh and Wang, Chien‐Min}, year={1990}, month=feb, pages={232–236} }

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