DOI: 10.1111/j.1151-2916.1989.tb09707.x. Binder Distribution in Ceramic Greenware During Thermolysis

Binder Distribution in Ceramic Greenware During Thermolysis

10.1111/j.1151-2916.1989.tb09707.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

Capillary forces were shown to influence the distribution of polymer‐plasicizer mixtures within ceramic green bodies during binder thermolysis. Isothermal thermogravimetric analysis was performed on tape‐cast sheets of an aluminapoly(vinyl butyrall‐dibutyl phthalate composite and direct observations were made of the binder distribution and pore growth after partial pyrolysis. This led to the investigation of a model system, an alumina‐eicosane composite, by similar experimental techniques. The early stage of binder removal was found to be similar to the drying of particle beds in which capillary forces draw liquid into the smaller pores at the surface. The morphology of the binder distribution produced by these processes dictates which mass‐transfer resistances may be controlling in binder burnout. A model is described that determines the length scale over which capillarity acts based on measurable physical parameters of the binder system and the packing of the ceramic particles.

Bibliography

Cima, M. J., Lewis, J. A., & Devoe, A. D. (1989). Binder Distribution in Ceramic Greenware During Thermolysis. Journal of the American Ceramic Society, 72(7), 1192â1199. Portico.

Authors 3

Michael J Cima (first)
Jennifer Alan Lewis (additional)
Alan D. Devoe (additional)

References 11 Referenced 132

{'key': 'e_1_2_1_2_2', 'first-page': '411', 'volume-title': 'Ceramic Processing Before Firing', 'author': 'Mistler R. E.', 'year': '1978'} / Ceramic Processing Before Firing by Mistler R. E. (1978)
10.1016/0021-9797(81)90132-6
{'key': 'e_1_2_1_4_2', 'first-page': '1', 'article-title': 'The Mechanism of the Drying of Solids', 'volume': '27', 'author': 'Pearse J. F.', 'year': '1949', 'journal-title': 'Trans. Inst. Chem. Eng.'} / Trans. Inst. Chem. Eng. / The Mechanism of the Drying of Solids by Pearse J. F. (1949)
10.1021/ie50298a017
{'key': 'e_1_2_1_6_2', 'first-page': '283', 'article-title': 'The Drying of Granular Solids', 'volume': '33', 'author': 'Ceaglske N. H.', 'year': '1937', 'journal-title': 'Trans. Am. Inst. Chem. Eng.'} / Trans. Am. Inst. Chem. Eng. / The Drying of Granular Solids by Ceaglske N. H. (1937)
10.1111/j.1151-2916.1986.tb04688.x
10.1111/j.1151-2916.1989.tb06280.x
10.1017/S0021859600018499
{'key': 'e_1_2_1_10_2', 'first-page': '54', 'volume-title': 'Flow of Fluids Through Porous Materials', 'author': 'Collins R. E.', 'year': '1961'} / Flow of Fluids Through Porous Materials by Collins R. E. (1961)
{'key': 'e_1_2_1_11_2', 'first-page': '99', 'article-title': 'Experimental Investigation of Factors Affecting Laboratory Relative Permeability Measurements.', 'volume': '192', 'author': 'Geffen T. M.', 'year': '1951', 'journal-title': 'Petroleum Trans., AIME'} / Petroleum Trans., AIME / Experimental Investigation of Factors Affecting Laboratory Relative Permeability Measurements. by Geffen T. M. (1951)
B. C.Mutsuddy.A Review of Binder Removal Processes for Ceramic Injection Molded Parts ”AIChE Conference on Emerging Technologies in Materials Minneapolis MN Aug. 1820 1987.

Dates

Type	When
Created	19 years, 10 months ago (Oct. 10, 2005, 6:14 a.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 11:35 p.m.)
Indexed	1 month, 4 weeks ago (June 26, 2025, 8:47 a.m.)
Issued	36 years, 1 month ago (July 1, 1989)
Published	36 years, 1 month ago (July 1, 1989)
Published Online	19 years, 10 months ago (Oct. 10, 2005)
Published Print	36 years, 1 month ago (July 1, 1989)

Funders 0

None

BibTeX

@article{Cima_1989, title={Binder Distribution in Ceramic Greenware During Thermolysis}, volume={72}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1989.tb09707.x}, DOI={10.1111/j.1151-2916.1989.tb09707.x}, number={7}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={Cima, Michael J and Lewis, Jennifer Alan and Devoe, Alan D.}, year={1989}, month=jul, pages={1192–1199} }

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