DOI: 10.1111/j.1151-2916.1988.tb05793.x. Reactions of Silicon‐Based Ceramics in Mixed Oxidation Chlorination Environments

Reactions of Silicon‐Based Ceramics in Mixed Oxidation Chlorination Environments

10.1111/j.1151-2916.1988.tb05793.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

The reaction of silicon‐based ceramics with 2% Cl2/Ar and 1% Cl2/1% to 20% O2/Ar at 950 °C was studied with thermogravimetric analysis and high‐pressure mass spectrometry. Pure Si, SiO2, several types of SiC, and Si3N4 were examined. The primary corrosion products were SiCl4(g) and SiO2(s) with smaller amounts of volatile silicon oxychlorides. The reactions appear to occur by chlorine penetration of the SiO2 layer, and gas‐phase diffusion of the silicon chlorides away from the sample appears to be rate limiting. Pure SiO2 shows very little reaction with Cl2. SiC with excess Si is more reactive than the other materials with Cl2, whereas SiC with excess carbon is more reactive than the other materials with Cl2/O2. Si3N4 shows very little reaction with Cl2. These diferences are explained on the basis of thermodynamic and microstructural factors.

Bibliography

MARRA, J. E., KREIDLER, E. R., JACOBSON, N. S., & FOX, D. S. (1988). Reactions of SiliconâBased Ceramics in Mixed Oxidation Chlorination Environments. Journal of the American Ceramic Society, 71(12), 1067â1073. Portico.

Authors 4

JOHN E. MARRA (first)
ERIC R. KREIDLER (additional)
NATHAN S. JACOBSON (additional)
DENNIS S. FOX (additional)

References 35 Referenced 35

{'issue': '7', 'key': 'e_1_2_1_2_2', 'first-page': '20', 'article-title': 'High Temperature Alloy Corrosion by Halogens', 'volume': '37', 'author': 'Elliot P.', 'year': '1985', 'journal-title': 'J. Met.'} / J. Met. / High Temperature Alloy Corrosion by Halogens by Elliot P. (1985)
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Dates

Type	When
Created	20 years, 5 months ago (March 8, 2005, 1:33 p.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 4:56 p.m.)
Indexed	2 months, 1 week ago (June 17, 2025, 10:45 p.m.)
Issued	36 years, 8 months ago (Dec. 1, 1988)
Published	36 years, 8 months ago (Dec. 1, 1988)
Published Online	20 years, 5 months ago (March 8, 2005)
Published Print	36 years, 8 months ago (Dec. 1, 1988)

Funders 0

None

BibTeX

@article{MARRA_1988, title={Reactions of Silicon‐Based Ceramics in Mixed Oxidation Chlorination Environments}, volume={71}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1988.tb05793.x}, DOI={10.1111/j.1151-2916.1988.tb05793.x}, number={12}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={MARRA, JOHN E. and KREIDLER, ERIC R. and JACOBSON, NATHAN S. and FOX, DENNIS S.}, year={1988}, month=dec, pages={1067–1073} }

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  "abstract": "<jats:p>The reaction of silicon\u2010based ceramics with 2% Cl<jats:sub>2</jats:sub>/Ar and 1% Cl<jats:sub>2</jats:sub>/1% to 20% O<jats:sub>2</jats:sub>/Ar at 950 \u00b0C was studied with thermogravimetric analysis and high\u2010pressure mass spectrometry. Pure Si, SiO<jats:sub>2</jats:sub>, several types of SiC, and Si<jats:sub>3</jats:sub>N<jats:sub>4</jats:sub> were examined. The primary corrosion products were SiCl<jats:sub>4</jats:sub>(<jats:italic>g</jats:italic>) and SiO<jats:sub>2</jats:sub>(<jats:italic>s</jats:italic>) with smaller amounts of volatile silicon oxychlorides. The reactions appear to occur by chlorine penetration of the SiO<jats:sub>2</jats:sub> layer, and gas\u2010phase diffusion of the silicon chlorides away from the sample appears to be rate limiting. Pure SiO<jats:sub>2</jats:sub> shows very little reaction with Cl<jats:sub>2</jats:sub>. SiC with excess Si is more reactive than the other materials with Cl<jats:sub>2</jats:sub>, whereas SiC with excess carbon is more reactive than the other materials with Cl<jats:sub>2</jats:sub>/O<jats:sub>2</jats:sub>. Si<jats:sub>3</jats:sub>N<jats:sub>4</jats:sub> shows very little reaction with Cl<jats:sub>2</jats:sub>. These diferences are explained on the basis of thermodynamic and microstructural factors.</jats:p>",
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