DOI: 10.1111/j.1151-2916.1984.tb19643.x. Use of the Adam‐Gibbs Equation in the Analysis of Structural Relaxation

Use of the Adam‐Gibbs Equation in the Analysis of Structural Relaxation

10.1111/j.1151-2916.1984.tb19643.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

Narayanaswamy's model of structural relaxation has been shown to provide an excellent description of the behavior of a variety of glasses. In the standard formulation, the relaxation time, τ is represented by the Arrhenius equation, with the activation energy partitioned between the temperature and Active temperature. That form for τ is successful, but lacks theoretical justification. In this paper, the Adam‐Gibbs equation is shown to describe accurately both τ and the viscosity of NBS 710 (alkali lime silicate) glass. This equation is expected to be accurate over a wider range of temperature and Active temperature than the Arrhenius equation.

Bibliography

SCHERER, G. W. (1984). Use of the AdamâGibbs Equation in the Analysis of Structural Relaxation. Journal of the American Ceramic Society, 67(7), 504â511. Portico.

Authors 1

GEORGE W. SCHERER (first)

References 31 Referenced 382

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10.1111/j.1151-2916.1976.tb09377.x
10.1111/j.1151-2916.1974.tb10912.x
{'issue': '12', 'key': 'e_1_2_1_8_2', 'first-page': '427', 'article-title': '“Glass Transition as a Function of Cooling Rate,”', 'volume': '43', 'author': 'Rekhson S. M.', 'year': '1982', 'journal-title': 'J. Phys.'} / J. Phys. / “Glass Transition as a Function of Cooling Rate,” by Rekhson S. M. (1982)
{'issue': '12', 'key': 'e_1_2_1_9_2', 'first-page': '369', 'article-title': '“Transport Processes in Glass,”', 'volume': '43', 'author': 'Cooper A. R.', 'year': '1982', 'journal-title': 'J. Phys.'} / J. Phys. / “Transport Processes in Glass,” by Cooper A. R. (1982)
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{'key': 'e_1_2_1_12_2', 'first-page': '463', 'volume-title': 'Proceedings of the 4th International Conference on Rapidly Quenched Metals', 'author': 'Tsao S. S.', 'year': '1981'} / Proceedings of the 4th International Conference on Rapidly Quenched Metals by Tsao S. S. (1981)
{'issue': '1', 'key': 'e_1_2_1_13_2', 'first-page': '68', 'article-title': '“Temperature Dependence of the Viscosity of Some Glasses at a Constant Structural Temperature” (Engl. Transl.),', 'volume': '5', 'author': 'Mazurin O. V.', 'year': '1979', 'journal-title': 'Sov. J. Phys. Chem. Glass'} / Sov. J. Phys. Chem. Glass / “Temperature Dependence of the Viscosity of Some Glasses at a Constant Structural Temperature” (Engl. Transl.), by Mazurin O. V. (1979)
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{'issue': '2', 'key': 'e_1_2_1_16_2', 'first-page': '1148', 'article-title': '“Temperature Dependences of Structural Relaxation Times at Constant Fictive Temperatures in Oxide Glasses,”', 'volume': '56', 'author': 'Mazurin O.V.', 'year': '1983', 'journal-title': 'Glastech. Ber.'} / Glastech. Ber. / “Temperature Dependences of Structural Relaxation Times at Constant Fictive Temperatures in Oxide Glasses,” by Mazurin O.V. (1983)
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{'issue': '3', 'key': 'e_1_2_1_22_2', 'first-page': '217', 'article-title': '“An Experimental Check on Two Variants of the Narayanaswamy Relaxation Model” (Engl. Transl.),', 'volume': '7', 'author': 'Gonchukova N.O.', 'year': '1981', 'journal-title': 'Sov. J. Phys. Chem. Glass'} / Sov. J. Phys. Chem. Glass / “An Experimental Check on Two Variants of the Narayanaswamy Relaxation Model” (Engl. Transl.), by Gonchukova N.O. (1981)
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{'key': 'e_1_2_1_24_2', 'first-page': '339', 'volume-title': 'Proc. XI Int. Cong. Glass', 'author': 'Sasabe H.', 'year': '1977'} / Proc. XI Int. Cong. Glass by Sasabe H. (1977)
C.T.Moynihan Rensselaer Polytechnic Institute; private communication.
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M. A.DeBolt “Structural Relaxation in Glass Forming Liquids: Application to Dynamic Viscoelasticity at High Pressures”;Ph. D. Thesis Catholic University of America Washington D.C. 1976.
10.1111/j.1151-2916.1956.tb15613.x
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10.1111/j.1151-2916.1976.tb09376.x
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{'issue': '6', 'key': 'e_1_2_1_32_2', 'first-page': '122', 'article-title': '“Decay Function for the Electrical Field Relaxation in Vitreous Ionic Conductors,”', 'volume': '14', 'author': 'Moynihan C.T.', 'year': '1973', 'journal-title': 'Phys. Chem. Glasses'} / Phys. Chem. Glasses / “Decay Function for the Electrical Field Relaxation in Vitreous Ionic Conductors,” by Moynihan C.T. (1973)

Dates

Type	When
Created	15 years, 1 month ago (July 24, 2010, 2:19 p.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 10:56 p.m.)
Indexed	2 weeks, 4 days ago (Aug. 6, 2025, 9:08 a.m.)
Issued	41 years, 1 month ago (July 1, 1984)
Published	41 years, 1 month ago (July 1, 1984)
Published Online	18 years, 10 months ago (Oct. 4, 2006)
Published Print	41 years, 1 month ago (July 1, 1984)

Funders 0

None

BibTeX

@article{SCHERER_1984, title={Use of the Adam‐Gibbs Equation in the Analysis of Structural Relaxation}, volume={67}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1984.tb19643.x}, DOI={10.1111/j.1151-2916.1984.tb19643.x}, number={7}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={SCHERER, GEORGE W.}, year={1984}, month=jul, pages={504–511} }

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