DOI: 10.1111/j.1151-2916.1982.tb10344.x. Sluggish Pansition Between Tetragonal and Rhombohedral Phases of Pb(Zr,Ti)0<sub>3</sub> Prepared by Application of Electric Field

Sluggish Pansition Between Tetragonal and Rhombohedral Phases of Pb(Zr,Ti)03 Prepared by Application of Electric Field

10.1111/j.1151-2916.1982.tb10344.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

Tetragonal and rhombohedral phases always coexist in Pb(ZrxTil1−x)03 near the morphotropic phase boundary compositions (0.52≤x≤0.55) when prepared by solid‐solid reaction among the constituent oxides. A special technique was developed to obtain perovskite ceramics exhibiting no co‐existence in the boundary compositions, in which no compositional fluctuation occurred in the B site of the perovskite structure. Even these monophasic perovskite ceramics of the morphotropic phase boundary compositions were two‐phase with the lapse of time after poling. This phenomenon is interpreted in terms of thermodynamics. It is suggested that this phenomenon may closely relate to the origin of aging in piezoelectrics.

Bibliography

KAKEGAWA, K., MOHRI, J., SHIRASAKI, S., & TAKAHASHI, K. (1982). Sluggish Pansition Between Tetragonal and Rhombohedral Phases of Pb(Zr,Ti)03 Prepared by Application of Electric Field. Journal of the American Ceramic Society, 65(10), 515â519. Portico.

Authors 4

K. KAKEGAWA (first)
J. MOHRI (additional)
S. SHIRASAKI (additional)
K. TAKAHASHI (additional)

References 21 Referenced 107

10.1063/1.1721741
{'issue': '11', 'key': 'e_1_2_1_3_2', 'first-page': '18', 'article-title': 'History of the Application of Piezoelectric Ceramic,', 'volume': '2', 'author': 'Tanaka T.', 'year': '1971', 'journal-title': 'Electron. Ceram. Contin. Educ. Symp.'} / Electron. Ceram. Contin. Educ. Symp. / History of the Application of Piezoelectric Ceramic, by Tanaka T. (1971)
10.1111/j.1151-2916.1965.tb14743.x
10.1246/nikkashi.1976.717
10.1016/0038-1098(77)91186-3
10.1143/JPSJ.8.615
10.1143/JPSJ.7.333
{'key': 'e_1_2_1_9_2', 'article-title': 'High Temperature Phase Equilibria in the Lead Titanate‐Zirconate System,', 'volume': '85', 'author': 'Moon R. L.', 'year': '1967', 'journal-title': 'Tech. Kept.'} / Tech. Kept. / High Temperature Phase Equilibria in the Lead Titanate‐Zirconate System, by Moon R. L. (1967)
{'key': 'e_1_2_1_10_2', 'first-page': '500', 'volume-title': 'in X‐Ray Diffraction Procedures', 'author': 'Klug H. P.', 'year': '1954'} / in X‐Ray Diffraction Procedures by Klug H. P. (1954)
10.6028/jres.055.028
10.1080/00150197208235319
{'key': 'e_1_2_1_13_2', 'first-page': '121', 'article-title': 'Some Ceramic and Electrical Properties of Bodies Fabricated from Coprecipitated Lead‐Zirconium‐Titanium Hydroxide,', 'volume': '34', 'author': 'Webster A. H.', 'year': '1965', 'journal-title': 'J. Can. Ceram. Soc.'} / J. Can. Ceram. Soc. / Some Ceramic and Electrical Properties of Bodies Fabricated from Coprecipitated Lead‐Zirconium‐Titanium Hydroxide, by Webster A. H. (1965)
{'key': 'e_1_2_1_14_2', 'first-page': '413', 'volume-title': 'in X‐Ray Diffraction by Polycrystalline Materials', 'author': 'Stokes A. R.', 'year': '1960'} / in X‐Ray Diffraction by Polycrystalline Materials by Stokes A. R. (1960)
10.1246/nikkashi.1975.413
{'key': 'e_1_2_1_16_2', 'first-page': '41', 'article-title': 'Analysis of X‐ray Powder Diffraction Profile,', 'volume': '44', 'author': 'Kasai N.', 'year': '1980', 'journal-title': 'Bull. Electrotech. lab.'} / Bull. Electrotech. lab. / Analysis of X‐ray Powder Diffraction Profile, by Kasai N. (1980)
{'key': 'e_1_2_1_17_2', 'first-page': '297', 'volume-title': 'in X‐Ray Diffraction Procedures', 'author': 'Klug H. P.', 'year': '1954'} / in X‐Ray Diffraction Procedures by Klug H. P. (1954)
{'issue': '10', 'key': 'e_1_2_1_18_2', 'first-page': '894', 'article-title': 'The Origin of Excellent Piezoelectric Properties in PZT‐Especially at Morphotropic Phase Boundary,', 'volume': '14', 'author': 'Nakamura T.', 'year': '1979', 'journal-title': 'Seramikkusu'} / Seramikkusu / The Origin of Excellent Piezoelectric Properties in PZT‐Especially at Morphotropic Phase Boundary, by Nakamura T. (1979)
10.1143/JJAP.7.1219
10.1111/j.1151-2916.1959.tb14321.x
10.1016/B978-0-12-379550-2.50009-0
10.1103/PhysRev.98.549

Dates

Type	When
Created	19 years, 2 months ago (June 6, 2006, 11:12 a.m.)
Deposited	1 year, 9 months ago (Nov. 23, 2023, 2:59 a.m.)
Indexed	2 months, 1 week ago (June 26, 2025, 6:45 a.m.)
Issued	42 years, 11 months ago (Oct. 1, 1982)
Published	42 years, 11 months ago (Oct. 1, 1982)
Published Online	19 years, 3 months ago (June 2, 2006)
Published Print	42 years, 11 months ago (Oct. 1, 1982)

Funders 0

None

BibTeX

@article{KAKEGAWA_1982, title={Sluggish Pansition Between Tetragonal and Rhombohedral Phases of Pb(Zr,Ti)03 Prepared by Application of Electric Field}, volume={65}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1982.tb10344.x}, DOI={10.1111/j.1151-2916.1982.tb10344.x}, number={10}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={KAKEGAWA, K. and MOHRI, J. and SHIRASAKI, S. and TAKAHASHI, K.}, year={1982}, month=oct, pages={515–519} }

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