DOI: 10.1111/j.1151-2916.1981.tb10223.x. Reversible Weight Change of Acceptor‐Doped BaTiO<sub>3</sub>

Reversible Weight Change of Acceptor‐Doped BaTiO3

10.1111/j.1151-2916.1981.tb10223.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

The oxygen vacancy concentration of BaTiO3 doped with acceptors (Cr to Ni) is determined gravimetrically as a function of the O2 partial pressure during and after annealing at 700° to 1300°C. The oxygen vacancy concentration of these materials is larger than that of undoped and donor‐doped BaTiO3. The oxygen vacancies are doubly ionized and they compensate the acceptors of lower valence. Both the vacancy concentration and the valence of the acceptor dopants depend on the annealing conditions. The electronic energy levels of the acceptors within the BaTiO3 band gap are derived from the gravimetric measurements. The electrical properties of the acceptor‐doped ceramics are favorable for base‐metal‐electrode multilayer capacitors, which require sintering in reducing atmospheres.

Bibliography

HAGEMANN, H. âJ., & HENNINGS, D. (1981). Reversible Weight Change of AcceptorâDoped BaTiO3. Journal of the American Ceramic Society, 64(10), 590â594. Portico.

Authors 2

H.‐J. HAGEMANN (first)
D. HENNINGS (additional)

References 13 Referenced 175

10.1002/pssa.2210130113
10.1007/BF00566571
10.1103/PhysRevB.20.3871
{'issue': '6', 'key': 'e_1_2_1_5_2', 'first-page': '516', 'article-title': 'Defect Chemistry and Electrical Conductivity of Doped Barium Titanate Ceramics: Part II, Thermogravimetric Investigations', 'volume': '31', 'author': 'Hennings D.', 'year': '1976', 'journal-title': 'Philips Res. Repl.'} / Philips Res. Repl. / Defect Chemistry and Electrical Conductivity of Doped Barium Titanate Ceramics: Part II, Thermogravimetric Investigations by Hennings D. (1976)
R.Wemicke “The Kinetics of Equilibrium Restoration in Barium Titanate Ceramics ”ibid. pp.526–43.
10.1149/1.2132644
10.1016/0022-4596(78)90015-4
10.1111/j.1151-2916.1971.tb12191.x
H.‐J.Hagemann “Acceptor Ions in BaTiO3and SrTiO3and Their Consequences on the Properties of Titanate Ceramics;”Ph. D. Thesis Rheinisch‐Westfälische Technische Hochschule Aachen Federal Republic of Germany 1980;145pp.
{'issue': '3', 'key': 'e_1_2_1_11_2', 'first-page': '1', 'article-title': 'Defect Chemistry and Electrical Transport Properties of Barium Titanate', 'author': 'Seuter A. M. J. H.', 'year': '1974', 'journal-title': 'Philips Res. Repl'} / Philips Res. Repl / Defect Chemistry and Electrical Transport Properties of Barium Titanate by Seuter A. M. J. H. (1974)
10.1002/pssa.2210350109
10.1063/1.325579
10.1088/0022-3719/9/18/013

Dates

Type	When
Created	19 years, 2 months ago (June 6, 2006, 9:08 p.m.)
Deposited	1 year, 11 months ago (Sept. 26, 2023, 12:58 a.m.)
Indexed	2 weeks, 6 days ago (Aug. 6, 2025, 7:58 a.m.)
Issued	43 years, 10 months ago (Oct. 1, 1981)
Published	43 years, 10 months ago (Oct. 1, 1981)
Published Online	19 years, 2 months ago (June 2, 2006)
Published Print	43 years, 10 months ago (Oct. 1, 1981)

Funders 0

None

BibTeX

@article{HAGEMANN_1981, title={Reversible Weight Change of Acceptor‐Doped BaTiO3}, volume={64}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1981.tb10223.x}, DOI={10.1111/j.1151-2916.1981.tb10223.x}, number={10}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={HAGEMANN, H.‐J. and HENNINGS, D.}, year={1981}, month=oct, pages={590–594} }

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