DOI: 10.1111/j.1151-2916.1981.tb09608.x. Mass‐Spectrometric and Electrochemical Studies of Thermodynamic Properties of Liquid and Solid Phases in the System CaO‐Al<sub>2</sub>O<sub>3</sub>

Mass‐Spectrometric and Electrochemical Studies of Thermodynamic Properties of Liquid and Solid Phases in the System CaO‐Al2O3

10.1111/j.1151-2916.1981.tb09608.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

The activities of CaO and Al2O3 in lime‐alumina melts were studied by Knudsen cell‐mass spectrometry at 2060 K. Emf of solid state cells, with CaF2 as the electrolyte, was measured from 923 to 1223 K to obtain the free energies of formation of the interoxide compounds. The results are critically evaluated in the light of data reported in the literature on phase equilibria, activities in melts, and stabilities of compounds. A coherent set of data is presented, including the previously unknown free energy of formation of CaO.6Al2O3 and the temperature dependence of activities in the liquid phase.

Bibliography

ALLIBERT, M., CHATILLON, C., JACOB, K. T., & LOURTAU, R. (1981). MassâSpectrometric and Electrochemical Studies of Thermodynamic Properties of Liquid and Solid Phases in the System CaOâAl2O3. Journal of the American Ceramic Society, 64(5), 307â314. Portico.

Authors 4

MICHEL ALLIBERT (first)
CHRISTIAN CHATILLON (additional)
K. T. JACOB (additional)
ROGER LOURTAU (additional)

References 22 Referenced 82

J.Chipman Proceedings of the Symposium on Physical Chemistry of Process Metallurgy Part I.Interscience Publishers New York 1961; p.27.
{'issue': '2', 'key': 'e_1_2_1_3_2', 'first-page': '415', 'article-title': 'Activities in the Liquid Solution SiO2‐CaO‐MgO‐Al2O3 at 1600°C', 'volume': '233', 'author': 'Rein R. H.', 'year': '1965', 'journal-title': 'Trans. A1ME'} / Trans. A1ME / Activities in the Liquid Solution SiO2‐CaO‐MgO‐Al2O3 at 1600°C by Rein R. H. (1965)
{'key': 'e_1_2_1_4_2', 'first-page': '231', 'volume-title': 'Phase Diagrams for Ceramists', 'author': 'Levin E. M.'} / Phase Diagrams for Ceramists by Levin E. M.
{'key': 'e_1_2_1_5_2', 'first-page': '14', 'volume-title': 'Heats and Free Energies of Formation of Ferrites and Aluminates of Calcium, Magnesium, Sodium, and Lithium', 'author': 'Koehler M. F.', 'year': '1961'} / Heats and Free Energies of Formation of Ferrites and Aluminates of Calcium, Magnesium, Sodium, and Lithium by Koehler M. F. (1961)
{'key': 'e_1_2_1_6_2', 'first-page': '386', 'article-title': 'Activities in Lime‐Alumina Melts', 'volume': '198', 'author': 'Sharma R. A.', 'year': '1961', 'journal-title': 'J. Iron Steel Inst.'} / J. Iron Steel Inst. / Activities in Lime‐Alumina Melts by Sharma R. A. (1961)
{'key': 'e_1_2_1_7_2', 'first-page': '700', 'article-title': 'Sulfur in Lime‐Alumina Mixtures', 'volume': '206', 'author': 'Kor G. J. W.', 'year': '1968', 'journal-title': 'J. Iron Steel Inst.'} / J. Iron Steel Inst. / Sulfur in Lime‐Alumina Mixtures by Kor G. J. W. (1968)
{'issue': '1', 'key': 'e_1_2_1_8_2', 'first-page': '54', 'article-title': 'Thermodynamics of Slag Systems: I', 'volume': '185', 'author': 'Carter P. T.', 'year': '1957', 'journal-title': 'J. Iron Steel Inst.'} / J. Iron Steel Inst. / Thermodynamics of Slag Systems: I by Carter P. T. (1957)
{'issue': '12', 'key': 'e_1_2_1_9_2', 'first-page': '1223', 'article-title': 'Calcium Sulfide Solubilities and Lime Activities in the Lime‐Alumina‐Silica System', 'volume': '204', 'author': 'Cameron J.', 'year': '1966', 'journal-title': 'J. Iron Steel Inst.'} / J. Iron Steel Inst. / Calcium Sulfide Solubilities and Lime Activities in the Lime‐Alumina‐Silica System by Cameron J. (1966)
{'issue': '9', 'key': 'e_1_2_1_10_2', 'first-page': '409', 'article-title': 'The CaO‐Al2O3 System in a Moisture‐Free Atmosphere', 'volume': '64', 'author': 'Nurse R. W.', 'year': '1965', 'journal-title': 'Trans. Br. Ceram. Soc.'} / Trans. Br. Ceram. Soc. / The CaO‐Al2O3 System in a Moisture‐Free Atmosphere by Nurse R. W. (1965)
10.1016/0022-0248(79)90031-9
10.1063/1.1134618
{'key': 'e_1_2_1_13_2', 'first-page': '615', 'volume-title': 'Advances in Mass Spectrometry, Vol. 7A', 'author': 'Chatillon C.', 'year': '1977'} / Advances in Mass Spectrometry, Vol. 7A by Chatillon C. (1977)
10.1063/1.1727229
10.1021/j100826a007
10.1149/1.2131542
{'issue': '11', 'key': 'e_1_2_1_17_2', 'first-page': '1304', 'article-title': 'Decomposition of Monocalcium Aluminate in Presence of Chlorides and Solid State Equilibria in theSystem CaO‐Al2O3‐CaF2', 'volume': '57', 'author': 'Brisi C.', 'year': '1968', 'journal-title': 'Ann. Chim.'} / Ann. Chim. / Decomposition of Monocalcium Aluminate in Presence of Chlorides and Solid State Equilibria in theSystem CaO‐Al2O3‐CaF2 by Brisi C. (1968)
10.1039/jr9630004297
{'issue': '6', 'key': 'e_1_2_1_19_2', 'first-page': '414', 'article-title': 'The System CaF2‐CaO‐Al2O3 Under One‐Third Atmosphere of Helium', 'volume': '5', 'author': 'Nafziger R. H.', 'year': '1973', 'journal-title': 'High Temp. Sci.'} / High Temp. Sci. / The System CaF2‐CaO‐Al2O3 Under One‐Third Atmosphere of Helium by Nafziger R. H. (1973)
10.1007/BF00549555
{'key': 'e_1_2_1_21_2', 'volume-title': 'Metallurgical Thermochemistry', 'author': 'Kubaschewski O.', 'year': '1979'} / Metallurgical Thermochemistry by Kubaschewski O. (1979)
{'issue': '7', 'key': 'e_1_2_1_22_2', 'first-page': '1237', 'article-title': 'A Study of the Thermodynamic Properties of Calcium Hexa‐Aluminate and Its Interaction with Oxides of Ti, Cr, and Zr', 'volume': '15', 'author': 'Popov S. G.', 'year': '1979', 'journal-title': 'Neorg. Mater.'} / Neorg. Mater. / A Study of the Thermodynamic Properties of Calcium Hexa‐Aluminate and Its Interaction with Oxides of Ti, Cr, and Zr by Popov S. G. (1979)
10.1016/0022-4596(77)90058-5

Dates

Type	When
Created	19 years, 2 months ago (June 6, 2006, 11:21 a.m.)
Deposited	1 year, 9 months ago (Nov. 23, 2023, 1:23 p.m.)
Indexed	4 weeks, 1 day ago (Aug. 7, 2025, 4:55 a.m.)
Issued	44 years, 4 months ago (May 1, 1981)
Published	44 years, 4 months ago (May 1, 1981)
Published Online	19 years, 3 months ago (June 2, 2006)
Published Print	44 years, 4 months ago (May 1, 1981)

Funders 0

None

BibTeX

@article{ALLIBERT_1981, title={Mass‐Spectrometric and Electrochemical Studies of Thermodynamic Properties of Liquid and Solid Phases in the System CaO‐Al2O3}, volume={64}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1981.tb09608.x}, DOI={10.1111/j.1151-2916.1981.tb09608.x}, number={5}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={ALLIBERT, MICHEL and CHATILLON, CHRISTIAN and JACOB, K. T. and LOURTAU, ROGER}, year={1981}, month=may, pages={307–314} }

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