Abstract
There is a range of compositions and temperatures below the monotectic where the equilibrium solid cannot form directly from an undercooled single‐phase liquid. Thermodynamics requires either a prior liquid‐liquid Phase separation or a simultaneous formation of the second liquid if the solid is to form. The implications for controlled crystallization of glass are discussed.
References
8
Referenced
79
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10.1016/0001-6160(68)90132-6
- Rustum Roy; pp.39–45in Ref.4.
Dates
Type | When |
---|---|
Created | 19 years, 2 months ago (June 6, 2006, 11:38 p.m.) |
Deposited | 1 year, 9 months ago (Nov. 22, 2023, 5:59 p.m.) |
Indexed | 4 months, 2 weeks ago (April 8, 2025, 12:26 p.m.) |
Issued | 56 years, 5 months ago (March 1, 1969) |
Published | 56 years, 5 months ago (March 1, 1969) |
Published Online | 19 years, 2 months ago (June 2, 2006) |
Published Print | 56 years, 5 months ago (March 1, 1969) |
@article{CAHN_1969, title={The Metastable Liquidus and Its Effect on the Crystallization of Glass}, volume={52}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1969.tb11194.x}, DOI={10.1111/j.1151-2916.1969.tb11194.x}, number={3}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={CAHN, JOHN W.}, year={1969}, month=mar, pages={118–121} }