DOI: 10.1111/j.1151-2916.1962.tb11145.x. Observations on Normal Grain Growth of Magnesia and Calcia

Observations on Normal Grain Growth of Magnesia and Calcia

10.1111/j.1151-2916.1962.tb11145.x

Crossref journal-article

Wiley

Journal of the American Ceramic Society (311)

Abstract

It is generally agreed that the rate of grain growth in metallic systems may be expressed by an equation that describes the square of the average diameter as being proportional to the time of annealing at constant temperature. The proportionality constant is exponentially dependent on temperature as normally expected in a rate expression according to the theory of reaction kinetics. The purpose of this study was to check the applicability of these equations to metallic oxide systems. Reagent‐grade MgO and CaO prepared from reagent‐grade CaCl2 obeyed the grain‐growth expressions reasonably well. Strong temperature dependence of the growth rate of both materials was attributed to impurities. Activation energies of 110 and 60 kcal per mole were calculated for CaO and MgO, respectively. Both values are higher than would be anticipated for grain‐boundary diffusion in high‐purity materials. Although porosity varied considerably for various isotherms, no effect of porosity on grain growth was detected. The data, however, were considered to be insufficient to warrant strong conclusions concerning this variable.

Bibliography

DANIELS, A. U., LOWRIE, R. C., GIBBY, R. L., & CUTLER, I. B. (1962). Observations on Normal Grain Growth of Magnesia and Calcia. Journal of the American Ceramic Society, 45(6), 282â285. Portico.

Authors 4

A. U. DANIELS (first)
R. C. LOWRIE (additional)
R. L. GIBBY (additional)
IVAN B. CUTLER (additional)

References 6 Referenced 48

10.1016/0502-8205(52)90009-9
{'key': 'e_1_2_1_2_2', 'first-page': '120', 'volume-title': 'Ceramic Fabrication Processes', 'author': 'Burke J. E.', 'year': '1958'} / Ceramic Fabrication Processes by Burke J. E. (1958)
{'key': 'e_1_2_1_3_2', 'first-page': '109', 'volume-title': 'Kinetics of High‐Temperature Processes–Report of Endicott House Conference on Kinetics of High‐Temperature Processes', 'author': 'Burke J. E.', 'year': '1958'} / Kinetics of High‐Temperature Processes–Report of Endicott House Conference on Kinetics of High‐Temperature Processes by Burke J. E. (1958)
{'key': 'e_1_2_1_4_2', 'first-page': '23', 'article-title': 'Grain Growth in High‐Purity Aluminum and in an Aluminum‐Magnesium Alloy', 'volume': '14', 'author': 'Beck P. A.', 'year': '1947', 'journal-title': 'Metals Technol.'} / Metals Technol. / Grain Growth in High‐Purity Aluminum and in an Aluminum‐Magnesium Alloy by Beck P. A. (1947)
{'key': 'e_1_2_1_5_2', 'first-page': '661', 'article-title': 'Theory of Grain‐Boundary Migration Rates', 'volume': '191', 'author': 'Turnbull David', 'year': '1951', 'journal-title': 'J. Metals, 3; Trans. Am. Inst. Mining Met. Engrs.'} / J. Metals, 3; Trans. Am. Inst. Mining Met. Engrs. / Theory of Grain‐Boundary Migration Rates by Turnbull David (1951)
10.1111/j.1151-2916.1957.tb12580.x

Dates

Type	When
Created	19 years, 2 months ago (June 6, 2006, 3:27 p.m.)
Deposited	1 year, 9 months ago (Nov. 22, 2023, 11:49 p.m.)
Indexed	1 year, 6 months ago (Feb. 4, 2024, 1:06 p.m.)
Issued	63 years, 2 months ago (June 1, 1962)
Published	63 years, 2 months ago (June 1, 1962)
Published Online	19 years, 2 months ago (June 2, 2006)
Published Print	63 years, 2 months ago (June 1, 1962)

Funders 0

None

BibTeX

@article{DANIELS_1962, title={Observations on Normal Grain Growth of Magnesia and Calcia}, volume={45}, ISSN={1551-2916}, url={http://dx.doi.org/10.1111/j.1151-2916.1962.tb11145.x}, DOI={10.1111/j.1151-2916.1962.tb11145.x}, number={6}, journal={Journal of the American Ceramic Society}, publisher={Wiley}, author={DANIELS, A. U. and LOWRIE, R. C. and GIBBY, R. L. and CUTLER, IVAN B.}, year={1962}, month=jun, pages={282–285} }

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