A Preliminary Investigation of the ISG Glass Vapor Hydration
10.1111/ijag.12055
Crossref journal-article
Wiley
International Journal of Applied Glass Science (311)
Abstract

During the geological disposal of high‐level waste, the nuclear glass is expected to be first hydrated in water vapor prior to liquid alteration. In the present work, we investigated the vapor hydration of the International simple glass (ISG) at 175°C and different relative humidities (60%, 80% and 98%). The glass hydration was investigated by nuclear reaction analysis (NRA) and Fourier transform infra‐red spectroscopy. The chemical and mineralogical compositions of the alteration products were studied using scanning electron microscopy/energy dispersive X‐ray spectroscopy (SEM‐EDS) and μ‐Raman spectroscopy, respectively. The NRA results gave water diffusion coefficients of 2.31–7.34 × 10−21 m2/s, in good agreement with the literature data on borosilicate glasses altered in aqueous media. The glass hydration increased with relative humidity percentage and the SEM‐EDS analysis showed a slight enrichment in Si and loss of Na in the hydrated glass layer compared with the pristine glass. The hydration rate of the ISG glass was little higher than that of the French SON68 glass hydrated using water vapor. The corrosion products were analcime, tobermorite, and calcite, which were typical of the SON68 glass hydrated in similar conditions.

Bibliography

Abdelouas, A., El Mendili, Y., Aït Chaou, A., Karakurt, G., Hartnack, C., Bardeau, J., Saito, T., & Matsuzaki, H. (2013). A Preliminary Investigation of the ISG Glass Vapor Hydration. International Journal of Applied Glass Science, 4(4), 307–316. Portico.

Authors 8
  1. Abdesselam Abdelouas (first)
  2. Yassine El Mendili (additional)
  3. Abdelouahed Aït Chaou (additional)
  4. Gokhan Karakurt (additional)
  5. Christoph Hartnack (additional)
  6. Jean‐François Bardeau (additional)
  7. Takumi Saito (additional)
  8. Hiroyuki Matsuzaki (additional)
References 49 Referenced 37
  1. 10.1533/9780857097194.1.70
  2. {'issue': '4', 'key': 'e_1_2_6_3_1', 'first-page': '133', 'article-title': 'The Sorption of Water on Obsidian and a Nuclear Waste Glass', 'volume': '32', 'author': 'Ebert W. L.', 'year': '1991', 'journal-title': 'Phys. Chem. Glasses'} / Phys. Chem. Glasses / The Sorption of Water on Obsidian and a Nuclear Waste Glass by Ebert W. L. (1991)
  3. {'issue': '24', 'key': 'e_1_2_6_4_1', 'first-page': '9', 'article-title': 'Analytical Electron Microscopy Study of Surface Layers Formed on the French SON68 Nuclear Waste Glass During Vapor Hydration at 200°C', 'volume': '254', 'author': 'Gong W. L.', 'year': '1998', 'journal-title': 'J. Nucl. Mater.'} / J. Nucl. Mater. / Analytical Electron Microscopy Study of Surface Layers Formed on the French SON68 Nuclear Waste Glass During Vapor Hydration at 200°C by Gong W. L. (1998)
  4. {'issue': '289', 'key': 'e_1_2_6_5_1', 'first-page': '4', 'article-title': 'Vapor Hydration of SON68 Glass from 90 °C to 200 °C: A Kinetic Study and Corrosion Products Investigation', 'volume': '358', 'author': 'Neeway J.', 'year': '2012', 'journal-title': 'J. Non‐Cryst. Solids'} / J. Non‐Cryst. Solids / Vapor Hydration of SON68 Glass from 90 °C to 200 °C: A Kinetic Study and Corrosion Products Investigation by Neeway J. (2012)
  5. {'issue': '26', 'key': 'e_1_2_6_6_1', 'first-page': '9', 'article-title': 'Aqueous Corrosion of Natural and Nuclear Wastes Glasses', 'volume': '108', 'author': 'Abrajano T. A.', 'year': '1989', 'journal-title': 'J. Non‐Cryst. Solids'} / J. Non‐Cryst. Solids / Aqueous Corrosion of Natural and Nuclear Wastes Glasses by Abrajano T. A. (1989)
  6. 10.1016/0022-3093(86)90783-0
  7. {'issue': '6', 'key': 'e_1_2_6_8_1', 'first-page': '3', 'article-title': 'The Relevance of Vapor Phase Hydration Aging to Nuclear Waste Isolation', 'volume': '5', 'author': 'Bates J. K.', 'year': '1984', 'journal-title': 'Waste Manag.'} / Waste Manag. / The Relevance of Vapor Phase Hydration Aging to Nuclear Waste Isolation by Bates J. K. (1984)
  8. {'issue': '7', 'key': 'e_1_2_6_9_1', 'first-page': '9', 'article-title': 'The Hydration Alteration of a Commercial Nuclear Waste Glass', 'volume': '51', 'author': 'Bates J. K.', 'year': '1985', 'journal-title': 'Chem. Geol.'} / Chem. Geol. / The Hydration Alteration of a Commercial Nuclear Waste Glass by Bates J. K. (1985)
  9. {'issue': '25', 'key': 'e_1_2_6_10_1', 'first-page': '5', 'article-title': 'Comparison of the Layer Structure of Vapor Phase and Leached SRL Glass by Use of AEM', 'volume': '176', 'author': 'Biwer B. M.', 'year': '1990', 'journal-title': 'Mat. Res. Soc. Symp. Proc'} / Mat. Res. Soc. Symp. Proc / Comparison of the Layer Structure of Vapor Phase and Leached SRL Glass by Use of AEM by Biwer B. M. (1990)
  10. 10.1016/j.mattod.2013.06.008
  11. K. S.Pitzer D. J.Bradley P. S. Z.Rogers andJ. C.Peiper Thermodynamics of High Temperature Brines Report LBL‐8973 Lawrence Berkeley Laboratory April1979.
  12. {'issue': '3', 'key': 'e_1_2_6_13_1', 'first-page': '6', 'article-title': 'Multi‐Nuclide AMS Performances at MALT', 'volume': '259', 'author': 'Matsuzaki H.', 'year': '2007', 'journal-title': 'Nucl. Instr. Meth. B.'} / Nucl. Instr. Meth. B. / Multi‐Nuclide AMS Performances at MALT by Matsuzaki H. (2007)
  13. {'issue': '62', 'key': 'e_1_2_6_14_1', 'first-page': '7', 'article-title': 'Development of Site‐Specific NRA for Hydrogen Mapping: Observation of Fatigue‐Fractured Surface of Glassy Alloys', 'volume': '269', 'author': 'Sekiba D.', 'year': '2011', 'journal-title': 'Nucl. Instr. Meth. B.'} / Nucl. Instr. Meth. B. / Development of Site‐Specific NRA for Hydrogen Mapping: Observation of Fatigue‐Fractured Surface of Glassy Alloys by Sekiba D. (2011)
  14. 10.1016/S1359-0286(02)00039-6
  15. {'issue': '919', 'key': 'e_1_2_6_16_1', 'first-page': '7', 'article-title': 'Insight Into the Mechanism of Carbon Steel Corrosion Under Aerobic and Anaerobic Conditions', 'volume': '15', 'author': 'El Mendili Y.', 'year': '2013', 'journal-title': 'Phys. Chem. Chem. Phys.'} / Phys. Chem. Chem. Phys. / Insight Into the Mechanism of Carbon Steel Corrosion Under Aerobic and Anaerobic Conditions by El Mendili Y. (2013)
  16. {'issue': '113', 'key': 'e_1_2_6_17_1', 'first-page': '7', 'article-title': 'Raman Microscopy in Archaeological Science', 'volume': '31', 'author': 'Smith G. D.', 'year': '2004', 'journal-title': 'J. Archaeol. Sci'} / J. Archaeol. Sci / Raman Microscopy in Archaeological Science by Smith G. D. (2004)
  17. {'issue': '55', 'key': 'e_1_2_6_18_1', 'first-page': '1', 'article-title': 'Understanding Otolith Biomineralization Processes: New Insights Into Microscale Spatial Distribution of Organic and Mineral Fractions from Raman Microspectrometry', 'volume': '392', 'author': 'Jolivet A.', 'year': '2008', 'journal-title': 'Anal. Bioanal. Chem.'} / Anal. Bioanal. Chem. / Understanding Otolith Biomineralization Processes: New Insights Into Microscale Spatial Distribution of Organic and Mineral Fractions from Raman Microspectrometry by Jolivet A. (2008)
  18. 10.1016/0022-3093(95)00638-9
  19. {'key': 'e_1_2_6_20_1', 'first-page': '5', 'article-title': 'Water Diffusion in the Simulated French Nuclear Waste Glass SON 68 Contacting Silica Rich Solutions: Experimental and Modeling', 'volume': '35', 'author': 'Ferrand K.', 'year': '2006', 'journal-title': 'J. Nucl. Mater.'} / J. Nucl. Mater. / Water Diffusion in the Simulated French Nuclear Waste Glass SON 68 Contacting Silica Rich Solutions: Experimental and Modeling by Ferrand K. (2006)
  20. {'issue': '10', 'key': 'e_1_2_6_21_1', 'first-page': '6', 'article-title': 'Composition Effects on Synthetic Glass Alteration Mechanisms: part 1. Experiments', 'volume': '279', 'author': 'Rajmohan N.', 'year': '2010', 'journal-title': 'Chem. Geol.'} / Chem. Geol. / Composition Effects on Synthetic Glass Alteration Mechanisms: part 1. Experiments by Rajmohan N. (2010)
  21. 10.1016/j.chemgeo.2013.04.001
  22. 10.1016/j.jnucmat.2006.06.016
  23. 10.1016/j.gca.2010.01.001
  24. J.Neeway “The alteration of the SON68 reference waste glass in silica saturated conditions and in presence of water vapor”. Ph.D Thesis Université de Nantes 2010.
  25. {'issue': '9', 'key': 'e_1_2_6_26_1', 'first-page': '3', 'article-title': 'Water‐Related Bands in the IR Absorption Spectra of Silicate Glasses', 'volume': '332', 'author': 'Efimov A. M.', 'year': '2003', 'journal-title': 'J. Non‐Cryst. Solids'} / J. Non‐Cryst. Solids / Water‐Related Bands in the IR Absorption Spectra of Silicate Glasses by Efimov A. M. (2003)
  26. {'issue': '179', 'key': 'e_1_2_6_27_1', 'first-page': '6', 'article-title': 'OH‐Related Infrared Absorption Bands in Oxide Glasses', 'volume': '351', 'author': 'Navarra G.', 'year': '2005', 'journal-title': 'J. Non‐Cryst. Solids'} / J. Non‐Cryst. Solids / OH‐Related Infrared Absorption Bands in Oxide Glasses by Navarra G. (2005)
  27. {'issue': '255', 'key': 'e_1_2_6_28_1', 'first-page': '9', 'article-title': 'Effect of Composition on the Short‐Term and Long‐Term Dissolution Rates of Ten Borosilicate Glasses of Increasing Complexity from 3 to 30 Oxides', 'volume': '358', 'author': 'Gin S.', 'year': '2012', 'journal-title': 'J. Non‐Cryst. Solids'} / J. Non‐Cryst. Solids / Effect of Composition on the Short‐Term and Long‐Term Dissolution Rates of Ten Borosilicate Glasses of Increasing Complexity from 3 to 30 Oxides by Gin S. (2012)
  28. 10.1016/0022-3093(83)90032-7
  29. {'issue': '5', 'key': 'e_1_2_6_30_1', 'first-page': '3', 'article-title': 'Planar Rings in Vitreous Silica', 'volume': '49', 'author': 'Galeener F. L.', 'year': '1982', 'journal-title': 'J. Non‐Cryst. Solids'} / J. Non‐Cryst. Solids / Planar Rings in Vitreous Silica by Galeener F. L. (1982)
  30. {'issue': '62', 'key': 'e_1_2_6_31_1', 'first-page': '2', 'article-title': 'Structural Studies of Silicate Glasses and Melts‐Applications and Limitations of Raman Spectroscopy', 'volume': '69', 'author': 'McMillan P.', 'year': '1984', 'journal-title': 'Am. Mineral.'} / Am. Mineral. / Structural Studies of Silicate Glasses and Melts‐Applications and Limitations of Raman Spectroscopy by McMillan P. (1984)
  31. N.Ollier “Verres de confinement de déchets nucléaires de type SON68 et leurs produits d'altération: spectroscopie optique des terres rares et de l'uranium ” Ph.D Thesis Université Lyon 1.2002.
  32. {'issue': '3', 'key': 'e_1_2_6_33_1', 'first-page': '0', 'article-title': 'Multinuclear Nuclear Magnetic Resonance and Raman Investigation of Sodium Borosilicate Glass Structures', 'volume': '31', 'author': 'Bunker B. C.', 'year': '1990', 'journal-title': 'Phys. Chem. Glasses'} / Phys. Chem. Glasses / Multinuclear Nuclear Magnetic Resonance and Raman Investigation of Sodium Borosilicate Glass Structures by Bunker B. C. (1990)
  33. 10.1016/S0022-3093(02)01594-6
  34. 10.1016/S0022-3093(01)00878-X
  35. 10.1111/j.1151-2916.1981.tb09893.x
  36. 10.1127/ejm/9/5/0935
  37. {'issue': '107', 'key': 'e_1_2_6_38_1', 'first-page': '3', 'article-title': 'Vibrational Spectra of Magnesium‐Sodium‐Borate Glasses: 2. Raman and Mid‐Infrared Investigation of the Network Structure', 'volume': '91', 'author': 'Kamitsos E. I.', 'year': '1987', 'journal-title': 'J. Phys. Chem.'} / J. Phys. Chem. / Vibrational Spectra of Magnesium‐Sodium‐Borate Glasses: 2. Raman and Mid‐Infrared Investigation of the Network Structure by Kamitsos E. I. (1987)
  38. 10.1016/j.jnoncrysol.2003.08.082
  39. 10.1103/PhysRevB.45.12797
  40. {'key': 'e_1_2_6_41_1', 'first-page': '690', 'article-title': 'Relations Between the Anionic Structure and Viscosity of Silicate Melts ‐ a Raman Spectroscopic Study', 'volume': '65', 'author': 'Mysen B. O.', 'year': '1980', 'journal-title': 'Am. Mineral.'} / Am. Mineral. / Relations Between the Anionic Structure and Viscosity of Silicate Melts ‐ a Raman Spectroscopic Study by Mysen B. O. (1980)
  41. {'issue': '310', 'key': 'e_1_2_6_42_1', 'first-page': '5', 'article-title': 'Ageing of Oilfield Cement at High Humidity: a Combined FEG‐ESEM and Raman Microscopic Investigation', 'volume': '11', 'author': 'Deng C.‐S.', 'year': '2002', 'journal-title': 'J. Mat. Chem'} / J. Mat. Chem / Ageing of Oilfield Cement at High Humidity: a Combined FEG‐ESEM and Raman Microscopic Investigation by Deng C.‐S. (2002)
  42. {'issue': '55', 'key': 'e_1_2_6_43_1', 'first-page': '5', 'article-title': 'Micro‐Raman Spectroscopy in White Portland Cement Hydration: Long‐Term Study at Room Temperature', 'volume': '37', 'author': 'Martinez‐Ramirez S.', 'year': '2006', 'journal-title': 'J. Raman Spectrosc.'} / J. Raman Spectrosc. / Micro‐Raman Spectroscopy in White Portland Cement Hydration: Long‐Term Study at Room Temperature by Martinez‐Ramirez S. (2006)
  43. 10.1016/S1065-7355(97)00001-1
  44. {'issue': '5', 'key': 'e_1_2_6_45_1', 'first-page': '7', 'article-title': 'Raman Spectroscopic Studies of Silicate and related Glass Structure ‐ A Review', 'volume': '106', 'author': 'McMillan P.', 'year': '1983', 'journal-title': 'Bull. Mineral'} / Bull. Mineral / Raman Spectroscopic Studies of Silicate and related Glass Structure ‐ A Review by McMillan P. (1983)
  45. {'issue': '68', 'key': 'e_1_2_6_46_1', 'first-page': '6', 'article-title': 'Curve‐Fitting of Raman Spectra of Silicate Glasses', 'volume': '67', 'author': 'Mysen B.', 'year': '1982', 'journal-title': 'Amer. Mineral'} / Amer. Mineral / Curve‐Fitting of Raman Spectra of Silicate Glasses by Mysen B. (1982)
  46. 10.1366/0003702864508322
  47. {'issue': '1', 'key': 'e_1_2_6_48_1', 'first-page': '45', 'article-title': 'Raman Polarization Spectra of the Natural Zeolite Analcime', 'volume': '35', 'author': 'Pechar F.', 'year': '1981', 'journal-title': 'Chem. Zvesti'} / Chem. Zvesti / Raman Polarization Spectra of the Natural Zeolite Analcime by Pechar F. (1981)
  48. {'issue': '227', 'key': 'e_1_2_6_49_1', 'first-page': '3', 'article-title': 'FT‐Raman Spectroscopic Study of Calcium‐Rich and Magnesium‐Rich Carbonate Minerals', 'volume': '61', 'author': 'Edwards H. G. M.', 'year': '2005', 'journal-title': 'Spectrochim. Acta. A'} / Spectrochim. Acta. A / FT‐Raman Spectroscopic Study of Calcium‐Rich and Magnesium‐Rich Carbonate Minerals by Edwards H. G. M. (2005)
  49. 10.1016/j.jnucmat.2011.05.027
Dates
Type When
Created 11 years, 10 months ago (Oct. 30, 2013, 3:37 a.m.)
Deposited 1 year, 11 months ago (Sept. 12, 2023, 6:43 p.m.)
Indexed 2 months ago (June 30, 2025, 1:28 a.m.)
Issued 11 years, 10 months ago (Oct. 30, 2013)
Published 11 years, 10 months ago (Oct. 30, 2013)
Published Online 11 years, 10 months ago (Oct. 30, 2013)
Published Print 11 years, 8 months ago (Dec. 1, 2013)
Funders 0

None

@article{Abdelouas_2013, title={A Preliminary Investigation of the <scp>ISG</scp> Glass Vapor Hydration}, volume={4}, ISSN={2041-1294}, url={http://dx.doi.org/10.1111/ijag.12055}, DOI={10.1111/ijag.12055}, number={4}, journal={International Journal of Applied Glass Science}, publisher={Wiley}, author={Abdelouas, Abdesselam and El Mendili, Yassine and Aït Chaou, Abdelouahed and Karakurt, Gokhan and Hartnack, Christoph and Bardeau, Jean‐François and Saito, Takumi and Matsuzaki, Hiroyuki}, year={2013}, month=oct, pages={307–316} }