DOI: 10.1111/ijag.12043. Initial Dissolution Rate of the International Simple Glass as a Function of <scp>pH</scp> and Temperature Measured Using Microchannel Flow‐Through Test Method

Initial Dissolution Rate of the International Simple Glass as a Function of pH and Temperature Measured Using Microchannel Flow‐Through Test Method

10.1111/ijag.12043

Crossref journal-article

Wiley

International Journal of Applied Glass Science (311)

Abstract

International simple glass (ISG) is a six‐component alumino‐borosilicate glass developed as a reference benchmark glass for six nations collaborating study on high‐level nuclear waste glass dissolution/corrosion mechanism. In this study, aqueous dissolution tests were performed for the ISG using microchannel flow‐through (MCFT) method to evaluate the initial dissolution rate of glass matrix, r0, precisely and systematically as a function of solution pH and temperature. The test results indicated that the r0 shows a “V‐shaped” pH dependence with a bottom at around pH4 at each temperature. Compared with Japanese reference glass of P0798, for which the r0 showed a “U‐shaped” pH dependence with a bottom at around pH6 in our previous study, the ISG shows the higher dissolution rate at basic pH, and lower dissolution rate at neutral to acidic pH. The results also indicated that the r0 increases with temperature according to an Arrhenius law, and the apparent activation energy evaluated from Arrhenius relation is 62–77 [kJ/mol] at any pH from 3 to 10, which suggests the initial dissolution of ISG proceeds controlled by a surface‐reaction mechanism in this pH range.

Bibliography

Inagaki, Y., Kikunaga, T., Idemitsu, K., & Arima, T. (2013). Initial Dissolution Rate of the International Simple Glass as a Function of pH and Temperature Measured Using Microchannel FlowâThrough Test Method. International Journal of Applied Glass Science, 4(4), 317â327. Portico.

Authors 4

Yaohiro Inagaki (first)
Taiki Kikunaga (additional)
Kazuya Idemitsu (additional)
Tatsumi Arima (additional)

References 24 Referenced 85

{'key': 'e_1_2_6_2_1', 'volume-title': 'Nuclear Waste Materials Handbook', 'author': 'Material Characterization Center (MCC)', 'year': '1981'} / Nuclear Waste Materials Handbook by Material Characterization Center (MCC) (1981)
{'key': 'e_1_2_6_3_1', 'volume-title': 'Standard Test Methods for Determining the Chemical Durability of Nuclear Waste Glasses: The Product Consistency Test (PCT)', 'author': 'ASTM', 'year': '1994'} / Standard Test Methods for Determining the Chemical Durability of Nuclear Waste Glasses: The Product Consistency Test (PCT) by ASTM (1994)
{'key': 'e_1_2_6_4_1', 'volume-title': 'Evaluation of the Single‐Pass Flow‐Through Test to Support a Low‐Activity Waste Specification', 'author': 'McGrail B. P.', 'year': '1981'} / Evaluation of the Single‐Pass Flow‐Through Test to Support a Low‐Activity Waste Specification by McGrail B. P. (1981)
10.1016/S0022-3115(97)00213-4
10.1016/S0022-3115(00)00041-6
{'key': 'e_1_2_6_7_1', 'volume-title': 'Testing and Modeling of the Corrosion of Simulated Nuclear Waste Glass Powders in a Waste Package Environment', 'year': '1988'} / Testing and Modeling of the Corrosion of Simulated Nuclear Waste Glass Powders in a Waste Package Environment (1988)
{'key': 'e_1_2_6_8_1', 'series-title': 'Mat. Res. Soc. Symp. Proc', 'first-page': '219', 'volume-title': 'Scientific Basis for Nuclear Waste Management III', 'author': 'Inagaki Y.', 'year': '2010'} / Scientific Basis for Nuclear Waste Management III / Mat. Res. Soc. Symp. Proc by Inagaki Y. (2010)
{'key': 'e_1_2_6_9_1', 'series-title': 'Mat. Res. Soc. Symp. Proc', 'first-page': '307', 'volume-title': 'Scientific Basis for Nuclear Waste Management III', 'author': 'Makigaki H.', 'year': '2010'} / Scientific Basis for Nuclear Waste Management III / Mat. Res. Soc. Symp. Proc by Makigaki H. (2010)
10.1080/00223131.2012.669246
10.1016/j.mattod.2013.06.008
10.1016/j.pce.2005.12.007
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D. L.Parkhurst Water‐Resources Investigations Report 95‐4227 US Geological Survey 1995.
{'key': 'e_1_2_6_15_1', 'series-title': 'Mat. Res. Soc. Symp. Proc', 'first-page': '15', 'volume-title': 'Scientific Basis for Nuclear Waste Management VIII', 'author': 'Grambow B.', 'year': '1985'} / Scientific Basis for Nuclear Waste Management VIII / Mat. Res. Soc. Symp. Proc by Grambow B. (1985)
10.1016/j.chemgeo.2012.09.012
10.1016/j.jnoncrysol.2012.05.024
10.1016/j.jnucmat.2013.04.008
{'key': 'e_1_2_6_19_1', 'series-title': 'Mat. Res. Soc. Symp. Proc', 'first-page': '41', 'volume-title': 'Scientific Basis for Nuclear Waste Management XIV', 'author': 'Delage F.', 'year': '1991'} / Scientific Basis for Nuclear Waste Management XIV / Mat. Res. Soc. Symp. Proc by Delage F. (1991)
10.1016/0016-7037(94)90487-1
10.1016/0016-7037(94)00232-B
10.1021/jp044360a
{'key': 'e_1_2_6_23_1', 'series-title': 'Mat. Res. Soc. Symp. Proc', 'first-page': '327', 'volume-title': 'Scientific Basis for Nuclear Waste Management XXVIII', 'author': 'Gin S.', 'year': '2004'} / Scientific Basis for Nuclear Waste Management XXVIII / Mat. Res. Soc. Symp. Proc by Gin S. (2004)
{'key': 'e_1_2_6_24_1', 'series-title': 'Mat. Res. Soc. Symp. Proc', 'first-page': '321', 'volume-title': 'Scientific Basis for Nuclear Waste Management XXIX', 'author': 'Inagaki Y.', 'year': '2006'} / Scientific Basis for Nuclear Waste Management XXIX / Mat. Res. Soc. Symp. Proc by Inagaki Y. (2006)
10.1016/S0022-3093(01)00890-0

Dates

Type	When
Created	11 years, 10 months ago (Oct. 25, 2013, 7:17 a.m.)
Deposited	1 year, 11 months ago (Sept. 12, 2023, 6:44 p.m.)
Indexed	1 month, 1 week ago (July 20, 2025, 12:24 a.m.)
Issued	11 years, 10 months ago (Oct. 25, 2013)
Published	11 years, 10 months ago (Oct. 25, 2013)
Published Online	11 years, 10 months ago (Oct. 25, 2013)
Published Print	11 years, 8 months ago (Dec. 1, 2013)

Funders 0

None

BibTeX

@article{Inagaki_2013, title={Initial Dissolution Rate of the International Simple Glass as a Function of <scp>pH</scp> and Temperature Measured Using Microchannel Flow‐Through Test Method}, volume={4}, ISSN={2041-1294}, url={http://dx.doi.org/10.1111/ijag.12043}, DOI={10.1111/ijag.12043}, number={4}, journal={International Journal of Applied Glass Science}, publisher={Wiley}, author={Inagaki, Yaohiro and Kikunaga, Taiki and Idemitsu, Kazuya and Arima, Tatsumi}, year={2013}, month=oct, pages={317–327} }

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